The types, contents and morphologies of crystalline Fe oxides and their relations to phosphate adsorptionon the clay fractions in soils with variable charge in southern China were investigated by means of XRD, TEM,EMA...The types, contents and morphologies of crystalline Fe oxides and their relations to phosphate adsorptionon the clay fractions in soils with variable charge in southern China were investigated by means of XRD, TEM,EMA and chemical analysis methods.Results indicated that the types and contents of crystalline Fe oxidesvaried with the soils examined. The dominant crystalline Fe oxide was hematite in the latosols and goethitesin the red soils.In yellow-brown soils, the only crystalline Fe oxide was goethite.The difference between Aldand Alo came mainly from the Al substituting for Fe in the pe oxides. The crystal morphology of goethiteappeared mainly as subrounded flat or iso-dimensional rather than acicular particles. Hematites occurredin plates of various thickness. Their MCDa/MCDc ratios in the latosols and red soils were generally above1.5 and below 1.5, respectively. The MCD values of goethites and hematites were 15-25nm and 20-35nm,and their specific surface areas were 80-120m￣2/g and 35-75m￣2/g, respectively.The goethite crystals weregenerally smaller. Variations of the total amounts of crystalline Fe oxi es in clay fractions were not related tophosphate adsorption. The types, contents and morphologies of crystalline Fe oxides in the soils remarkablyaffected phosphate adsorption characteristics of the soils. The phosphate adsorption of goethite was muchgreater than that of hematite. The higher the MCD /MCDc rotio of hematite, the lower the phosphateadsorption.展开更多
This paper is a review of some advances in the studies on 1.4-nm intergrade mineral of soils in sub-tropical China. 1) 1.4-nm intergrade mineral occurs ubiquitously in soils of subtropical China. The 1.4-nmrnineral in...This paper is a review of some advances in the studies on 1.4-nm intergrade mineral of soils in sub-tropical China. 1) 1.4-nm intergrade mineral occurs ubiquitously in soils of subtropical China. The 1.4-nmrnineral in red soil and yellow soil is mainly 1.4-nm intergrade mineral, and in acidic yellow-brown soil (pH< 5.5) is verniiculite alone or 1.4-nm intergrade mineral together with vermiculite. The distribution and thecontent of 1 .4-nm intergrade mineral in the mountain soils are more widespread and higher than those of thecorresponding soils in horizontal zone. 2) The interlayer material of 1.4-nin intergrade mineral ui these soilsappears to be hydroxy-Al polymers instead of hydroxy-Fe, proto-imogolite or kaolin-like material. There isa significant positive correlation between Al amount extracted from the soil with sodium citrate after DCBextraction and pH value of the citrate solution after the extraction. The citrate can also extract a certainamount of silicon from the soil, but the silicon may not come from interlayer of 1.4-nm intergrade mineral.3) It was seldom studied that either vermiculite or smectite did the natural 1.4-nm intergrade mineral comefrom in soil, or it was commonly thought to come from vermiculite. A recent report has revealed that itcan come from smectite. There are some different behaviors between the 1.4-nm intergrade mineral derivedfrom vermiculite and that from smectite. For example, they exert different influences on the formation ofgibbsite. The 1.4-nm intergrade mineral derived from smectite may promote the formation of gibbsite in theyellow soil. 4) The type of 1.4-nm minerals in soils. i.e., vermiculite or 1.4-nm intergrade mineral, may besignificant to soil properties, such as soil acidity, exchangeable Al, electric charge aiiiount and specific surfacearea. Therefore, the management for the soil in which 1.4-nm mineral is mainly 1.4-nm intergrade mineralor vermiculite should be dealt with differently.展开更多
X-ray photoelectron spectroscopy (XPS) and automatic titrimeter were nsed to study the relation be-tween pH and the transformation of the coordinate forms of P on goethite surfaces. The results showed thatfor a given ...X-ray photoelectron spectroscopy (XPS) and automatic titrimeter were nsed to study the relation be-tween pH and the transformation of the coordinate forms of P on goethite surfaces. The results showed thatfor a given P concentration, increasing the pH of suspension could cause a fast transformation of monodentatecomplexes of phosphate ions on goethite surfaces to binuclear ones. When lowering the PH, additional adsorp-tion of P occurred and the binuclear complexes reverted slowly to the monodentate ones. The dissociationand association of protons of the sorbed P caused by PH changes was considered to be a major reason lewtingto the transformation of the coordinate forms of P on the surfaces. The stability of binuclear surface complexof P was greater than that of monodentate complex. The possible reactions on the interface of goethite andsolutions with pH changes, and the reasons causing the different stabilities of the two coordinate P complexesare discussed in the paper.展开更多
文摘The types, contents and morphologies of crystalline Fe oxides and their relations to phosphate adsorptionon the clay fractions in soils with variable charge in southern China were investigated by means of XRD, TEM,EMA and chemical analysis methods.Results indicated that the types and contents of crystalline Fe oxidesvaried with the soils examined. The dominant crystalline Fe oxide was hematite in the latosols and goethitesin the red soils.In yellow-brown soils, the only crystalline Fe oxide was goethite.The difference between Aldand Alo came mainly from the Al substituting for Fe in the pe oxides. The crystal morphology of goethiteappeared mainly as subrounded flat or iso-dimensional rather than acicular particles. Hematites occurredin plates of various thickness. Their MCDa/MCDc ratios in the latosols and red soils were generally above1.5 and below 1.5, respectively. The MCD values of goethites and hematites were 15-25nm and 20-35nm,and their specific surface areas were 80-120m￣2/g and 35-75m￣2/g, respectively.The goethite crystals weregenerally smaller. Variations of the total amounts of crystalline Fe oxi es in clay fractions were not related tophosphate adsorption. The types, contents and morphologies of crystalline Fe oxides in the soils remarkablyaffected phosphate adsorption characteristics of the soils. The phosphate adsorption of goethite was muchgreater than that of hematite. The higher the MCD /MCDc rotio of hematite, the lower the phosphateadsorption.
文摘This paper is a review of some advances in the studies on 1.4-nm intergrade mineral of soils in sub-tropical China. 1) 1.4-nm intergrade mineral occurs ubiquitously in soils of subtropical China. The 1.4-nmrnineral in red soil and yellow soil is mainly 1.4-nm intergrade mineral, and in acidic yellow-brown soil (pH< 5.5) is verniiculite alone or 1.4-nm intergrade mineral together with vermiculite. The distribution and thecontent of 1 .4-nm intergrade mineral in the mountain soils are more widespread and higher than those of thecorresponding soils in horizontal zone. 2) The interlayer material of 1.4-nin intergrade mineral ui these soilsappears to be hydroxy-Al polymers instead of hydroxy-Fe, proto-imogolite or kaolin-like material. There isa significant positive correlation between Al amount extracted from the soil with sodium citrate after DCBextraction and pH value of the citrate solution after the extraction. The citrate can also extract a certainamount of silicon from the soil, but the silicon may not come from interlayer of 1.4-nm intergrade mineral.3) It was seldom studied that either vermiculite or smectite did the natural 1.4-nm intergrade mineral comefrom in soil, or it was commonly thought to come from vermiculite. A recent report has revealed that itcan come from smectite. There are some different behaviors between the 1.4-nm intergrade mineral derivedfrom vermiculite and that from smectite. For example, they exert different influences on the formation ofgibbsite. The 1.4-nm intergrade mineral derived from smectite may promote the formation of gibbsite in theyellow soil. 4) The type of 1.4-nm minerals in soils. i.e., vermiculite or 1.4-nm intergrade mineral, may besignificant to soil properties, such as soil acidity, exchangeable Al, electric charge aiiiount and specific surfacearea. Therefore, the management for the soil in which 1.4-nm mineral is mainly 1.4-nm intergrade mineralor vermiculite should be dealt with differently.
文摘X-ray photoelectron spectroscopy (XPS) and automatic titrimeter were nsed to study the relation be-tween pH and the transformation of the coordinate forms of P on goethite surfaces. The results showed thatfor a given P concentration, increasing the pH of suspension could cause a fast transformation of monodentatecomplexes of phosphate ions on goethite surfaces to binuclear ones. When lowering the PH, additional adsorp-tion of P occurred and the binuclear complexes reverted slowly to the monodentate ones. The dissociationand association of protons of the sorbed P caused by PH changes was considered to be a major reason lewtingto the transformation of the coordinate forms of P on the surfaces. The stability of binuclear surface complexof P was greater than that of monodentate complex. The possible reactions on the interface of goethite andsolutions with pH changes, and the reasons causing the different stabilities of the two coordinate P complexesare discussed in the paper.
