The reactive surface area, an important parameter controlling mineral reactions, affects the amount of mineralization trapping of CO2 which affects the long-term CO2 storage. The effect of the reactive surface area on...The reactive surface area, an important parameter controlling mineral reactions, affects the amount of mineralization trapping of CO2 which affects the long-term CO2 storage. The effect of the reactive surface area on the mineralization trapping of CO2 was numerically simulated for CO2 storage in saline aquifers. Three kinds of minerals, including anorthite, calcite and kaolinite, are involved in the mineral reactions. This paper models the relationship between the specific surface area and the grain diameter of anorthite based on experimental data from literature （Brantley and Mellott, 2000）. When the reactive surface areas of anorthite and calcite decrease from 838 to 83.8 m^2/m^3, the percentage of mineralization trapping of CO： after 500 years decreases from 11.8% to 0.65%. The amount of dissolved anorthite and the amounts of precipitated kaolinite and calcite decrease significantly when the reactive surface areas ofanorthite and calcite decrease from 838 to 83.8 m2/m3. Calcite is initially dissolved in the brine and then precipitates during the geochemical reactions between CO2-H20 and the minerals. Different reactive surface areas of anorthite and calcite lead to different times from dissolution to precipitation. The pH of the brine decreases with decreasing reactive surface areas of anorthite and calcite which influences the acidity of the saline aquifer. The gas saturation between the upper and lower parts of the saline aquifer increases with decreasing reactive surface areas of anorthite and calcite. The mass density distribution of brine solution shows that the CO2^＋brine solution region increases with decreasing reactive surface areas ofanorthite and calcite.展开更多
A geothermal demonstration exploitation area will be established in the Enhanced Geothermal System of the Qiabuqia field, Gonghe Basin, Qinghai–Xizang Plateau in China. Selection of operational parameters for geother...A geothermal demonstration exploitation area will be established in the Enhanced Geothermal System of the Qiabuqia field, Gonghe Basin, Qinghai–Xizang Plateau in China. Selection of operational parameters for geothermal field extraction is thus of great significance to realize the best production performance. A novel integrated method of finite element and multi-objective optimization has been employed to obtain the optimal scheme for thermal extraction from the Gonghe Basin. A thermal-hydraulic-mechanical coupling model(THM) is established to analyze the thermal performance. From this it has been found that there exists a contraction among different heat extraction indexes. Parametric study indicates that injection mass rate(Q_(in)) is the most sensitive parameter to the heat extraction, followed by well spacing(WS) and injection temperature(T_(in)). The least sensitive parameter is production pressure(p_(out)). The optimal combination of operational parameters acquired is such that(T_(in), p_(out), Q_(in), WS) equals(72.72°C, 30.56 MPa, 18.32 kg/s, 327.82 m). Results indicate that the maximum electrical power is 1.41 MW for the optimal case over 20 years. The thermal break has been relieved and the pressure difference reduced by 8 MPa compared with the base case. The optimal case would extract 50% more energy than that of a previous case and the outcome will provide a remarkable reference for the construction of Gonghe project.展开更多
碳捕集、利用与封存技术(carbon capture,utilization and storage,CCUS)是指将CO_(2)从能源利用、工业生产或大气中分离出来,经过提纯运送到可利用或封存场地,以实现被捕集的CO_(2)与大气长期分离的技术。联合国政府间气候变化专门委员...碳捕集、利用与封存技术(carbon capture,utilization and storage,CCUS)是指将CO_(2)从能源利用、工业生产或大气中分离出来,经过提纯运送到可利用或封存场地,以实现被捕集的CO_(2)与大气长期分离的技术。联合国政府间气候变化专门委员会(IPCC)近期在报告中指出:CCUS技术是碳减排与碳中和的“foundation”技术。在我国碳达峰碳中和的“双碳”目标大背景下,CCUS技术被认为是我国实现碳中和目标不可或缺的关键性技术之一。该文对国际、国内主要研究团队和作者研究团队近年来在CO_(2)地质封存、增产致密油/页岩气/深层地热开采过程中的关键热质传递问题研究进行了综述,通过理论分析,利用分子动力学、格子Boltzmann、计算流体力学等模拟方法,和微观孔隙尺度可视化实验、岩心尺度核磁共振实验、超临界压力流体对流换热实验等实验手段,从不同尺度阐述了储层条件下超临界CO_(2)在微纳多孔结构中多相多组分流动与热质传递机理,分析了矿物反应、降压析出、流体变物性、尺度效应等对CO_(2)地质封存和驱油、驱气、采热过程中的影响规律,从而为CO_(2)地质封存和利用的应用提供理论和技术支撑。展开更多
The nanoparticle thermal conductivity and nanoscale thermal contact resistance were investigated by molecular dynamics(MD) simulations to further understand nanoscale porous media thermal conductivity.Macroscale porou...The nanoparticle thermal conductivity and nanoscale thermal contact resistance were investigated by molecular dynamics(MD) simulations to further understand nanoscale porous media thermal conductivity.Macroscale porous media thermal conductivity models were then revised for nanoporous media.The effective thermal conductivities of two packed beds with nanoscale nickel particles and a packed bed with microscale nickel particles were then measured using the Hot Disk.The measured results show that the nano/microscale porous media thermal conductivities were much less than the thermal conductivities of the solid particles.Comparison of the measured and calculated results shows that the revised combined parallel-series model and the revised Hsu-Cheng model can accurately predict the effective thermal conductivities of micro-and nanoparticle packed beds.展开更多
The internal heat transfer of different gases in microporous media was investigated experimentally and numerically.The experimental test section had a sintered bronze porous media with average particle diameters from ...The internal heat transfer of different gases in microporous media was investigated experimentally and numerically.The experimental test section had a sintered bronze porous media with average particle diameters from 11 μm to 225 μm.The Knudsen numbers at the average inlet and outlet pressures of each test section varied from 0.0006 to 0.13 with porosities from 0.16 to 0.38.The particle-to-fluid heat transfer coefficients of air,CO 2 and helium in the microporous media were determined experimentally.The results show that the Nusselt numbers for the internal heat transfer in the microporous media decrease with decreasing the particle diameter,d p,and increasing Knudsen number for the same Reynolds number.For Kn>0.01,the rarefaction affects the internal heat transfer in the microporous media.A Nusselt number correlation was developed that includes the influence of rarefaction.The computational fluid dynamics(CFD) numerical simulation was carried out to do the pore scale simulation of internal heat transfer in the microporous media considering the rarefaction effect.Pore scale three-dimensional numerical simulations were also used to predict the particle-to-fluid heat transfer coefficients.The numerical results without slip-flow and temperature jump effects for Kn<0.01 corresponded well with the experimental data.The numerical results with slip-flow and temperature jump effects for 0.01<Kn<0.13 are lower than the numerical results without rarefaction effects,but closer to the experimental data.The numerical results with rarefaction effects can accurately simulate the unsteady heat transfer in the microporous media.展开更多
基金supported by the National Natural Science Foundation of China (Grant No. 50906043)the Tsinghua University Initiative Scientific Research Program(2009THZ02232)The first author did this study while at Geoscience Australia sponsored by CAGS (China-Australia Geological Storage of CO2Project)
文摘The reactive surface area, an important parameter controlling mineral reactions, affects the amount of mineralization trapping of CO2 which affects the long-term CO2 storage. The effect of the reactive surface area on the mineralization trapping of CO2 was numerically simulated for CO2 storage in saline aquifers. Three kinds of minerals, including anorthite, calcite and kaolinite, are involved in the mineral reactions. This paper models the relationship between the specific surface area and the grain diameter of anorthite based on experimental data from literature （Brantley and Mellott, 2000）. When the reactive surface areas of anorthite and calcite decrease from 838 to 83.8 m^2/m^3, the percentage of mineralization trapping of CO： after 500 years decreases from 11.8% to 0.65%. The amount of dissolved anorthite and the amounts of precipitated kaolinite and calcite decrease significantly when the reactive surface areas ofanorthite and calcite decrease from 838 to 83.8 m2/m3. Calcite is initially dissolved in the brine and then precipitates during the geochemical reactions between CO2-H20 and the minerals. Different reactive surface areas of anorthite and calcite lead to different times from dissolution to precipitation. The pH of the brine decreases with decreasing reactive surface areas of anorthite and calcite which influences the acidity of the saline aquifer. The gas saturation between the upper and lower parts of the saline aquifer increases with decreasing reactive surface areas of anorthite and calcite. The mass density distribution of brine solution shows that the CO2^＋brine solution region increases with decreasing reactive surface areas ofanorthite and calcite.
基金the National Key R&D Program of China(Grant No.2018YFB1501804)the National Natural Science Funds for Excellent Young Scholars of China(Grant No.51822406)+2 种基金the Sichuan Science and Technology Program(2021YJ0389)the Program of Introducing Talents of Discipline to Chinese Universities(111 Plan)(Grant No.B17045)the Beijing Outstanding Young Scientist Program(Grant No.BJJWZYJH01201911414038)。
文摘A geothermal demonstration exploitation area will be established in the Enhanced Geothermal System of the Qiabuqia field, Gonghe Basin, Qinghai–Xizang Plateau in China. Selection of operational parameters for geothermal field extraction is thus of great significance to realize the best production performance. A novel integrated method of finite element and multi-objective optimization has been employed to obtain the optimal scheme for thermal extraction from the Gonghe Basin. A thermal-hydraulic-mechanical coupling model(THM) is established to analyze the thermal performance. From this it has been found that there exists a contraction among different heat extraction indexes. Parametric study indicates that injection mass rate(Q_(in)) is the most sensitive parameter to the heat extraction, followed by well spacing(WS) and injection temperature(T_(in)). The least sensitive parameter is production pressure(p_(out)). The optimal combination of operational parameters acquired is such that(T_(in), p_(out), Q_(in), WS) equals(72.72°C, 30.56 MPa, 18.32 kg/s, 327.82 m). Results indicate that the maximum electrical power is 1.41 MW for the optimal case over 20 years. The thermal break has been relieved and the pressure difference reduced by 8 MPa compared with the base case. The optimal case would extract 50% more energy than that of a previous case and the outcome will provide a remarkable reference for the construction of Gonghe project.
文摘碳捕集、利用与封存技术(carbon capture,utilization and storage,CCUS)是指将CO_(2)从能源利用、工业生产或大气中分离出来,经过提纯运送到可利用或封存场地,以实现被捕集的CO_(2)与大气长期分离的技术。联合国政府间气候变化专门委员会(IPCC)近期在报告中指出:CCUS技术是碳减排与碳中和的“foundation”技术。在我国碳达峰碳中和的“双碳”目标大背景下,CCUS技术被认为是我国实现碳中和目标不可或缺的关键性技术之一。该文对国际、国内主要研究团队和作者研究团队近年来在CO_(2)地质封存、增产致密油/页岩气/深层地热开采过程中的关键热质传递问题研究进行了综述,通过理论分析,利用分子动力学、格子Boltzmann、计算流体力学等模拟方法,和微观孔隙尺度可视化实验、岩心尺度核磁共振实验、超临界压力流体对流换热实验等实验手段,从不同尺度阐述了储层条件下超临界CO_(2)在微纳多孔结构中多相多组分流动与热质传递机理,分析了矿物反应、降压析出、流体变物性、尺度效应等对CO_(2)地质封存和驱油、驱气、采热过程中的影响规律,从而为CO_(2)地质封存和利用的应用提供理论和技术支撑。
基金supported by the key project fund from the National Natural Science Foundation of China (Grant No. 50736003)the National Natural Science Foundation of China (Grant No. 50676047)
文摘The nanoparticle thermal conductivity and nanoscale thermal contact resistance were investigated by molecular dynamics(MD) simulations to further understand nanoscale porous media thermal conductivity.Macroscale porous media thermal conductivity models were then revised for nanoporous media.The effective thermal conductivities of two packed beds with nanoscale nickel particles and a packed bed with microscale nickel particles were then measured using the Hot Disk.The measured results show that the nano/microscale porous media thermal conductivities were much less than the thermal conductivities of the solid particles.Comparison of the measured and calculated results shows that the revised combined parallel-series model and the revised Hsu-Cheng model can accurately predict the effective thermal conductivities of micro-and nanoparticle packed beds.
基金supported by the Key Project Fund from the National Natural Science Foundation of China (Grant No. 50736003)the Major Project of Beijing Natural Science Foundation (Grant No. 3110001)+1 种基金the Industrial Technology Development Program (Grant No. B1420110113)the National High Technology R&D Program of China (GrantNo.2012AA052803)
文摘The internal heat transfer of different gases in microporous media was investigated experimentally and numerically.The experimental test section had a sintered bronze porous media with average particle diameters from 11 μm to 225 μm.The Knudsen numbers at the average inlet and outlet pressures of each test section varied from 0.0006 to 0.13 with porosities from 0.16 to 0.38.The particle-to-fluid heat transfer coefficients of air,CO 2 and helium in the microporous media were determined experimentally.The results show that the Nusselt numbers for the internal heat transfer in the microporous media decrease with decreasing the particle diameter,d p,and increasing Knudsen number for the same Reynolds number.For Kn>0.01,the rarefaction affects the internal heat transfer in the microporous media.A Nusselt number correlation was developed that includes the influence of rarefaction.The computational fluid dynamics(CFD) numerical simulation was carried out to do the pore scale simulation of internal heat transfer in the microporous media considering the rarefaction effect.Pore scale three-dimensional numerical simulations were also used to predict the particle-to-fluid heat transfer coefficients.The numerical results without slip-flow and temperature jump effects for Kn<0.01 corresponded well with the experimental data.The numerical results with slip-flow and temperature jump effects for 0.01<Kn<0.13 are lower than the numerical results without rarefaction effects,but closer to the experimental data.The numerical results with rarefaction effects can accurately simulate the unsteady heat transfer in the microporous media.
