The power of the toroidal field （TF） coil in HL-2A is supplied with two 80 MVA motor generators （MGs） together through a diode rectifier. The TF system is designed to obtain the parameters as follows： the highest...The power of the toroidal field （TF） coil in HL-2A is supplied with two 80 MVA motor generators （MGs） together through a diode rectifier. The TF system is designed to obtain the parameters as follows： the highest toroidal filed of 2.8 T, the biggest coil current of 45 kA, the fiat top time of 3-5 s. So the released energy of each MG set for one pulse discharge mast be more than 500 MJ.展开更多
Rigid trigonal tris(3-pyridylduryl)borane L was synthesized through four steps in good overall yield from readily available 1,2,4,5-tetramethylbenzene and was used to construct two porous cadmium(II) complexes Cd(L)X2...Rigid trigonal tris(3-pyridylduryl)borane L was synthesized through four steps in good overall yield from readily available 1,2,4,5-tetramethylbenzene and was used to construct two porous cadmium(II) complexes Cd(L)X2.G(X = Cl,Br;G = guset molecules),1(Cd(L)Cl2.EtOH.iPrOH.3H2O) and 2(Cd(L)Br2.MeOH.C7H8.3H2O),under mild reaction conditions.1 and 2 are isostructural and featured with 3D porous metal-organoboron framewoks with rtl topology,in which L acts as a 3-connected node while a dicadmium motif serves as 6-connected node.In addition,1 and 2 exhibit strong photoluminescence in the visible region and 1 shows moderate adsorption ability of carbon dioxide at 273 K.展开更多
Eight-coordinate chiral lanthanide complexes [Eu(dbm)3LRR](1),[Eu(dbm)3LSS](2) and [Tb(dbm)3LRR](3)(LRR/LSS =(-)-/(+)-4,5-pineno-2,2'-bipyridine,Hdbm = dibenzoylmethane) were synthesized stereoselectively,which we...Eight-coordinate chiral lanthanide complexes [Eu(dbm)3LRR](1),[Eu(dbm)3LSS](2) and [Tb(dbm)3LRR](3)(LRR/LSS =(-)-/(+)-4,5-pineno-2,2'-bipyridine,Hdbm = dibenzoylmethane) were synthesized stereoselectively,which were characterized by UV-vis,CD spectra and X-ray single-crystal diffraction.The mirrorimage structure features of complexes 1 and 2 were obtained by combination of the solid-state CD spectra and the crystal structure analysis.After further comparison with the solid-state CD spectra of six-coordinate and seven-coordinate metal complexes containing β-diketone ligands,the CD spectraabsolute configuration correlation rule for the eight-coordinate β-diketonate lanthanide complexes was proposed through the exciton chirality method for the first time.The △ or Λ absolute configurations of complexes 1―3 with the distorted square antiprism geometry were confirmed by the X-ray single-crystal analysis.展开更多
文摘The power of the toroidal field （TF） coil in HL-2A is supplied with two 80 MVA motor generators （MGs） together through a diode rectifier. The TF system is designed to obtain the parameters as follows： the highest toroidal filed of 2.8 T, the biggest coil current of 45 kA, the fiat top time of 3-5 s. So the released energy of each MG set for one pulse discharge mast be more than 500 MJ.
基金supported by the National Natural Foundation of China (21025103 & 20971085)the National Basic Research Program of China (2007CB209701 & 2009CB930403)+1 种基金Shanghai Science and Technology Committee(10DJ1400100)the Key Project of State Education Ministry
文摘Rigid trigonal tris(3-pyridylduryl)borane L was synthesized through four steps in good overall yield from readily available 1,2,4,5-tetramethylbenzene and was used to construct two porous cadmium(II) complexes Cd(L)X2.G(X = Cl,Br;G = guset molecules),1(Cd(L)Cl2.EtOH.iPrOH.3H2O) and 2(Cd(L)Br2.MeOH.C7H8.3H2O),under mild reaction conditions.1 and 2 are isostructural and featured with 3D porous metal-organoboron framewoks with rtl topology,in which L acts as a 3-connected node while a dicadmium motif serves as 6-connected node.In addition,1 and 2 exhibit strong photoluminescence in the visible region and 1 shows moderate adsorption ability of carbon dioxide at 273 K.
基金Supported by the National Natural Science Foundation of China (Grant Nos. 20773098 & 20973136)the Innovation Foundation of Xiamen University (Series 2) (Grant No. XDKJCX20061027)
文摘Eight-coordinate chiral lanthanide complexes [Eu(dbm)3LRR](1),[Eu(dbm)3LSS](2) and [Tb(dbm)3LRR](3)(LRR/LSS =(-)-/(+)-4,5-pineno-2,2'-bipyridine,Hdbm = dibenzoylmethane) were synthesized stereoselectively,which were characterized by UV-vis,CD spectra and X-ray single-crystal diffraction.The mirrorimage structure features of complexes 1 and 2 were obtained by combination of the solid-state CD spectra and the crystal structure analysis.After further comparison with the solid-state CD spectra of six-coordinate and seven-coordinate metal complexes containing β-diketone ligands,the CD spectraabsolute configuration correlation rule for the eight-coordinate β-diketonate lanthanide complexes was proposed through the exciton chirality method for the first time.The △ or Λ absolute configurations of complexes 1―3 with the distorted square antiprism geometry were confirmed by the X-ray single-crystal analysis.
