GaSb is an attractive candidate for future high-performance Ⅲ-Ⅴ p-channel metal-oxide-semiconductor-field-effect-transistors(pMOSFETs)because of its high hole mobility.The effect of HCl based-chemical cleaning on re...GaSb is an attractive candidate for future high-performance Ⅲ-Ⅴ p-channel metal-oxide-semiconductor-field-effect-transistors(pMOSFETs)because of its high hole mobility.The effect of HCl based-chemical cleaning on removing the non-self limiting and instable native oxide layer of GaSb to obtain a clean and smooth surface has been studied.It is observed that the rms roughness of a GaSb surface is significantly reduced from 2.731 nm to 0.693 nm by using HCl:H_(2)O(1:3)solution.The Ni/Pt/Au ohmic contact exhibits an optimal specific contact resistivity of about 6.89×10^(-7)Ω·cm^(2) with a 60 s rapid thermal anneal(RTA)at 250℃.Based on the chemical cleaning and ohmic contact experimental results,inversion-channel enhancement GaSb pMOSFETs are demonstrated.For a 6μm gate length GaSb pMOSFET,a maximum drain current of about 4.0 mA/mm,a drain current on-off(ION/IOFF)ratio of>10^(3),and a subthreshold swing of~250 mV/decade are achieved.Combined with the split C-V method,a peak hole mobility of about 160 cm^(2)/V·s is obtained for a 24μm gate length GaSb pMOSFET.展开更多
Surface treatment for Ge substrates using hydrogen chlorine cleaning and chemical passivation are investigated on AuTi/Al2O3/Ge metal-oxide-semiconductor capacitors.After hydrogen chlorine cleaning,a smooth Ge surface...Surface treatment for Ge substrates using hydrogen chlorine cleaning and chemical passivation are investigated on AuTi/Al2O3/Ge metal-oxide-semiconductor capacitors.After hydrogen chlorine cleaning,a smooth Ge surface almost free from native oxide is demonstrated by atomic force microscopy and x-ray photoelectron spectroscopy observations.Passivation using a hydrogen chlorine solution is found to form a chlorine-terminated surface,while aqueous ammonium sulfide pretreatment results in a surface terminated by Ge-S bonding.Compared with chlorine-passivated samples,the sulfur-passivated ones show less frequency dispersion and better thermal stability based on capacitance-voltage characterizations.The samples with HCl pre-cleaning and (NH4 )2S passivation show less frequency dispersion than the HF pre-cleaning and (NH4)2S passivated ones.The surface treatment process using hydrogen chlorine cleaning followed by aqueous ammonium sulfide passivation demonstrates a promising way to improve gate dielectric/Ge interface quality.展开更多
The solid phase reactions of Ni with GaAs substrates are investigated.The experimental results reveal that the Ni-GaAs solid phase reaction forms a ternary phase of Ni2GaAs when annealing temperatures are in the range...The solid phase reactions of Ni with GaAs substrates are investigated.The experimental results reveal that the Ni-GaAs solid phase reaction forms a ternary phase of Ni2GaAs when annealing temperatures are in the range 250 300℃.As the annealing temperature increases to 400℃,the Ni2GaAs phase starts to decompose due to NiAs phase precipitation.Ni-GaAs alloys processed at 400℃ with a 3min annealing time demonstrate a sheet resistance of 30Ω/square after unreacted Ni removal in hot diluted-HCl solutions.Therefore,Ni-GaAs alloys formed by solid phase reaction could be promising metallic source/drain structures with significant low series resistance for high mobility Ⅲ-Ⅴ metal-oxide-semiconductor field effect transistor (MOSFET) applications.展开更多
基金Supported by the National Basic Research Program of China under Grant Nos 2011CBA00605,2010CB327501the National Natural Science Foundation of China under Grant No 61106095+1 种基金the National Science&Technology Major Project of China under Grant No 2011ZX02708-003One Hundred Talents Program of Chinese Academy of Sciences,and the Scientific Research Foundation for the Returned Overseas Chinese Scholars,the Ministry of Education of China.
文摘GaSb is an attractive candidate for future high-performance Ⅲ-Ⅴ p-channel metal-oxide-semiconductor-field-effect-transistors(pMOSFETs)because of its high hole mobility.The effect of HCl based-chemical cleaning on removing the non-self limiting and instable native oxide layer of GaSb to obtain a clean and smooth surface has been studied.It is observed that the rms roughness of a GaSb surface is significantly reduced from 2.731 nm to 0.693 nm by using HCl:H_(2)O(1:3)solution.The Ni/Pt/Au ohmic contact exhibits an optimal specific contact resistivity of about 6.89×10^(-7)Ω·cm^(2) with a 60 s rapid thermal anneal(RTA)at 250℃.Based on the chemical cleaning and ohmic contact experimental results,inversion-channel enhancement GaSb pMOSFETs are demonstrated.For a 6μm gate length GaSb pMOSFET,a maximum drain current of about 4.0 mA/mm,a drain current on-off(ION/IOFF)ratio of>10^(3),and a subthreshold swing of~250 mV/decade are achieved.Combined with the split C-V method,a peak hole mobility of about 160 cm^(2)/V·s is obtained for a 24μm gate length GaSb pMOSFET.
基金Supported by the National Basic Research Program of China under Grant NoS 2011CBA00605 and 2010CB327501the National Science&Technology Major Project of China under Grant No 2011ZX02708-003,One Hundred Talents Program of Chinese Academy of Sciencesthe Scientific Research Foundation for the Returned Overseas Chinese Scholars,State Education Ministry.
文摘Surface treatment for Ge substrates using hydrogen chlorine cleaning and chemical passivation are investigated on AuTi/Al2O3/Ge metal-oxide-semiconductor capacitors.After hydrogen chlorine cleaning,a smooth Ge surface almost free from native oxide is demonstrated by atomic force microscopy and x-ray photoelectron spectroscopy observations.Passivation using a hydrogen chlorine solution is found to form a chlorine-terminated surface,while aqueous ammonium sulfide pretreatment results in a surface terminated by Ge-S bonding.Compared with chlorine-passivated samples,the sulfur-passivated ones show less frequency dispersion and better thermal stability based on capacitance-voltage characterizations.The samples with HCl pre-cleaning and (NH4 )2S passivation show less frequency dispersion than the HF pre-cleaning and (NH4)2S passivated ones.The surface treatment process using hydrogen chlorine cleaning followed by aqueous ammonium sulfide passivation demonstrates a promising way to improve gate dielectric/Ge interface quality.
基金Supported by the National Basic Research Program of China under Grant Nos 2011CBA00605 and 2010CB327501the National Science&Technology Major Project of China under Grant No 2011ZX02708-003+1 种基金One-Hundred Talent Program of Chinese Academy of Sciencesthe Scientific Research Foundation for the Returned Overseas Chinese Scholars,Ministry of Education of China.
文摘The solid phase reactions of Ni with GaAs substrates are investigated.The experimental results reveal that the Ni-GaAs solid phase reaction forms a ternary phase of Ni2GaAs when annealing temperatures are in the range 250 300℃.As the annealing temperature increases to 400℃,the Ni2GaAs phase starts to decompose due to NiAs phase precipitation.Ni-GaAs alloys processed at 400℃ with a 3min annealing time demonstrate a sheet resistance of 30Ω/square after unreacted Ni removal in hot diluted-HCl solutions.Therefore,Ni-GaAs alloys formed by solid phase reaction could be promising metallic source/drain structures with significant low series resistance for high mobility Ⅲ-Ⅴ metal-oxide-semiconductor field effect transistor (MOSFET) applications.