Zeolite-confined Fe-site catalysts(ZFCs)have emerged as superior materials for sustainably producing high-value chemicals through CO_(2) hydrogenation,owing to their adaptable framework,customizable composition,and th...Zeolite-confined Fe-site catalysts(ZFCs)have emerged as superior materials for sustainably producing high-value chemicals through CO_(2) hydrogenation,owing to their adaptable framework,customizable composition,and thermal robustness.They excel in activating,adsorbing,and converting CO_(2) with remarkable efficiency and consistency in performance.This has sparked a surge in research interest in recent years.The review delves into the latest advancements in CO_(2) catalytic hydrogenation to olefins,alcohols,aromatics,and other liquid hydrocarbons,examining the synthesis,modification tactics,and the correlation between structure and performance across various ZFCs.Additionally,it underscores the pivotal factors affecting performance and sheds light on the mechanisms behind selectivity control in the CO_(2) hydrogenation process facilitated by ZFCs.To conclude,it presents pressing challenges and strategic recommendations to inspire the development of high-performance,durable ZFCs for CO_(2) hydrogenation applications.展开更多
基金the National Natural Science Foundation of China(Nos.U22A20107,U1967215,22078307,22208314,22278379,22238003,and 22002008)the Science and Technology R&D Program Joint Fund Project of Henan Provincial,China(No.222301420001)+3 种基金the Distinguished Young Scholars Innovation Team of Zhengzhou University,China(No.32320275)the Postgraduate Education Reform Project of Henan Province,China(No.2021SJGLX093Y)the National Funded Postdoctoral Researcher Program,China(No.GZC20232382)the Key Research Projects of University in Henan Province,China(No.24A150041).
文摘Zeolite-confined Fe-site catalysts(ZFCs)have emerged as superior materials for sustainably producing high-value chemicals through CO_(2) hydrogenation,owing to their adaptable framework,customizable composition,and thermal robustness.They excel in activating,adsorbing,and converting CO_(2) with remarkable efficiency and consistency in performance.This has sparked a surge in research interest in recent years.The review delves into the latest advancements in CO_(2) catalytic hydrogenation to olefins,alcohols,aromatics,and other liquid hydrocarbons,examining the synthesis,modification tactics,and the correlation between structure and performance across various ZFCs.Additionally,it underscores the pivotal factors affecting performance and sheds light on the mechanisms behind selectivity control in the CO_(2) hydrogenation process facilitated by ZFCs.To conclude,it presents pressing challenges and strategic recommendations to inspire the development of high-performance,durable ZFCs for CO_(2) hydrogenation applications.
