All-inorganic perovskites CsPbX_(3)(X=Cl,Br,I)have attracted worldwide interest due to their excellent lumi-nescent performances.Meanwhile,Cs_(4)PbBr_(6) have been studied because they can enhance the luminescent effi...All-inorganic perovskites CsPbX_(3)(X=Cl,Br,I)have attracted worldwide interest due to their excellent lumi-nescent performances.Meanwhile,Cs_(4)PbBr_(6) have been studied because they can enhance the luminescent efficiency and stability of CsPbBr_(3).Herein,we introduced a microfluidic method based on room-temperature supersat-urated recrystallization to synthesize blue-emitting CsPbBr_(3)nanocrystals(NCs)and green-emitting CsPbBr_(3)/Cs_(4)PbBr_(6)NCs.The ultrasmall CsPbBr_(3)NCs emitted at a deep blue wavelength of 461 nm with the full width at half maximum(FWHM)of 15 nm.transmission electron microscopy(TEM)results demonstrated that ultrasmall CsPbBr_(3)NCs with the average particle size of 3.8 nm were synthesized and the CsPbBr_(3)NCs were crystallized as monoclinic structure.展开更多
A series of hexagonal phase NaBiF_(4):x Yb^(3+),y Er^(3+) were successfully synthesized by solvothermal method.The morphology,phase structure,up-conversion luminescence and down-conversion luminescence properties of Y...A series of hexagonal phase NaBiF_(4):x Yb^(3+),y Er^(3+) were successfully synthesized by solvothermal method.The morphology,phase structure,up-conversion luminescence and down-conversion luminescence properties of Yb^(3+) and Er^(3+) doping concentration and the energy transfer mechanism were studied.It shows that the doping of Yb^(3+) and Er^(3+) does not cause the phase transition of NaBiF_(4),but influences its morphology.In the NaBiF_(4):Yb^(3+),Er^(3+),Yb^(3+) can transfer energy with Er^(3+),enhancing up-conversion green emission.With Yb^(3+) doping concentration increasing,the up-conversion red-green ratio will increase while the down-conversion intensity of the green emission decreases and that of the red emission increases.Considering the potential application of Na BiF4:x Yb^(3+),y Er^(3+) phosphors in optical illumination,the thermal stability was carried out.展开更多
基金Project(2016YFC0600706) supported by the State Key Research Development Program of ChinaProjects(41630642,51774325) supported by the National Natural Science Foundation of China+1 种基金Project(2017JJ3389) supported by the Natural Science Foundation of Hunan Province,ChinaProjects(2017CX006,2018zzts212) supported by the Innovation-Driven Program of Central South University,China
基金The authors are grateful for the financial supports from the National Natural Science Foundation of China(Nos.51904335,11972378,41630642)the Fundamental Research Funds for the Central Universities of Central South University,China(No.2019zzts310).
基金Project(51304241)supported by the Youth Project of National Natural Science Foundation of ChinaProject(2014M552164)supported by Chinese Postdoctoral Science FoundationProject(20130162120015)supported by the Specialized Research Fund for the Doctoral Program of Higher Education of China
基金Projects(2016YFC0600706,2016YFC0600802) supported by the National Key Research and Development Program of ChinaProject(2017zzts186) supported by Cultivating Excellent Doctors of Central South University,China
基金Project(41630642)supported by the Key Project of National Natural Science Foundation of ChinaProjects(51674288,11402311)supported by the National Natural Science Foundation of China
基金the National Natural Science Foundation of China(Nos.41972283,11972378)the National Key Scientific Instrument and Equipment Development,China(No.51927808)the Hunan Provincial Innovation Foundation for Postgraduate,China(No.CX2018B066).
基金Projects(41630642,11472311)supported by the National Natural Science Foundation of ChinaProject(2017zzts181)supported by the Cultivating Excellent Ph Ds of Central South University,ChinaProject(201806370062)supported by the China Scholarship Council
基金supported by the National Natural Science Foundation of China (Nos. 52174099, 51904333)the Natural Science Foundation of Hunan Province, China (No. 2021JJ30842)
基金the National Natural Science Foundation of China(Nos.11972378,51904335,51927808)the Fundamental Research Funds for the Central Universities of Central South University,China(No.2021zzts0282).
基金the National Frontier Technology Key R&D Project(Nos.XXX-125 and JXXX-2019-058)the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)the Collaborative Innovation Center of Advanced Inorganic Functional Composites of Jiangsu Province。
文摘All-inorganic perovskites CsPbX_(3)(X=Cl,Br,I)have attracted worldwide interest due to their excellent lumi-nescent performances.Meanwhile,Cs_(4)PbBr_(6) have been studied because they can enhance the luminescent efficiency and stability of CsPbBr_(3).Herein,we introduced a microfluidic method based on room-temperature supersat-urated recrystallization to synthesize blue-emitting CsPbBr_(3)nanocrystals(NCs)and green-emitting CsPbBr_(3)/Cs_(4)PbBr_(6)NCs.The ultrasmall CsPbBr_(3)NCs emitted at a deep blue wavelength of 461 nm with the full width at half maximum(FWHM)of 15 nm.transmission electron microscopy(TEM)results demonstrated that ultrasmall CsPbBr_(3)NCs with the average particle size of 3.8 nm were synthesized and the CsPbBr_(3)NCs were crystallized as monoclinic structure.
基金financially supported by the National Pre-research Foundation of China(Nos.6140208010201 and 61402080104)the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD),the Research and Innovation Program for College Graduates of Jiangsu Province(No.KYCX170970)+1 种基金Jiangsu Students Innovation and Entrepreneurship Training Program(No.201910291240Y)the Top-notch Academic Programs Project of Jiangsu Higher Education Institutions(No.PPZY2015B128)。
文摘A series of hexagonal phase NaBiF_(4):x Yb^(3+),y Er^(3+) were successfully synthesized by solvothermal method.The morphology,phase structure,up-conversion luminescence and down-conversion luminescence properties of Yb^(3+) and Er^(3+) doping concentration and the energy transfer mechanism were studied.It shows that the doping of Yb^(3+) and Er^(3+) does not cause the phase transition of NaBiF_(4),but influences its morphology.In the NaBiF_(4):Yb^(3+),Er^(3+),Yb^(3+) can transfer energy with Er^(3+),enhancing up-conversion green emission.With Yb^(3+) doping concentration increasing,the up-conversion red-green ratio will increase while the down-conversion intensity of the green emission decreases and that of the red emission increases.Considering the potential application of Na BiF4:x Yb^(3+),y Er^(3+) phosphors in optical illumination,the thermal stability was carried out.