Objective To investigate the photocatalytic degradation of gaseous ammonia in static state by using nano-TiO2 as photoeatalyst supported on latex paint film under UV-irradiation. Methods Experiments were conducted to ...Objective To investigate the photocatalytic degradation of gaseous ammonia in static state by using nano-TiO2 as photoeatalyst supported on latex paint film under UV-irradiation. Methods Experiments were conducted to study the relationship between the initial concentration of ammonia and the degradation products competing to be adsorbed on catalyst surface. Degradation of ammonia and its products were detected by spectrophotometry and catalytic kinetic spectrophotometry, respectively. Results On the one hand, TiO2 catalyst was excellent for degradation of ammonia, and the crystal phase of TiO2, anatase or ruffle, had little effect on degradation of ammonia, but the conversion of ammonia grew with the increase of catalyst content. On the other hand, apparent rate constant and conversion of ammonia decreased with the increase of initial concentration of ammonia, and the photocatalytic degradation reaction followed a pseudo-first-order expression due to-the evidence of linear correlation between -lnC/C0 vs. irradiation time t, but the relationship between initial concentration and the degradation products was not linear in low initial concentration. Conclusion Whether the photocatalytic degradation of ammonia in static state follows a first-order reaction depends on the initial ammonia concentration due to competition in adsorption between reactant and the degradation products.展开更多
： The“ ring-morphostructures” (RM) are the object of this study. They are one of the most significant element of lineament’s structure and unknown for the majority of investigations. RM are numerous to lineament’...： The“ ring-morphostructures” (RM) are the object of this study. They are one of the most significant element of lineament’s structure and unknown for the majority of investigations. RM are numerous to lineament’s zone: they have different size (from 10-20km to 500-800km in diameter), structure, age, geological history and have been divided into several classes on the most important signs. They have a spatial-genetic connection Amur-Songhua-Huanghe lineament (ASHL) and had been developed simultaneously with it. The RM exerted an essential influence on the geologic-geomorphological structure, evolution and geodynamics of lineament. The main factor of evolution of lineament is a long geological process of extension of the earth’s crust which is a result of the expanding earth.展开更多
基金This work has been supported by Shandong Provincial Scientific Council, People’s Republic of China (Grant No. Z2000B01)
文摘Objective To investigate the photocatalytic degradation of gaseous ammonia in static state by using nano-TiO2 as photoeatalyst supported on latex paint film under UV-irradiation. Methods Experiments were conducted to study the relationship between the initial concentration of ammonia and the degradation products competing to be adsorbed on catalyst surface. Degradation of ammonia and its products were detected by spectrophotometry and catalytic kinetic spectrophotometry, respectively. Results On the one hand, TiO2 catalyst was excellent for degradation of ammonia, and the crystal phase of TiO2, anatase or ruffle, had little effect on degradation of ammonia, but the conversion of ammonia grew with the increase of catalyst content. On the other hand, apparent rate constant and conversion of ammonia decreased with the increase of initial concentration of ammonia, and the photocatalytic degradation reaction followed a pseudo-first-order expression due to-the evidence of linear correlation between -lnC/C0 vs. irradiation time t, but the relationship between initial concentration and the degradation products was not linear in low initial concentration. Conclusion Whether the photocatalytic degradation of ammonia in static state follows a first-order reaction depends on the initial ammonia concentration due to competition in adsorption between reactant and the degradation products.
基金Supported by the National Natural Science Foundation of China! (No.49471013)Changchun Jingyuetan Remote Sensing Test Site, t
文摘： The“ ring-morphostructures” (RM) are the object of this study. They are one of the most significant element of lineament’s structure and unknown for the majority of investigations. RM are numerous to lineament’s zone: they have different size (from 10-20km to 500-800km in diameter), structure, age, geological history and have been divided into several classes on the most important signs. They have a spatial-genetic connection Amur-Songhua-Huanghe lineament (ASHL) and had been developed simultaneously with it. The RM exerted an essential influence on the geologic-geomorphological structure, evolution and geodynamics of lineament. The main factor of evolution of lineament is a long geological process of extension of the earth’s crust which is a result of the expanding earth.
