Pyrolysis-Gas Chromatography-Mass Spectrometry(Py-GC/MS)was adopted to determine the changes in component of BG11-cultivated Desmodesmus sp.(BG11/8-10)pyrolyzed products at different temperatures(300℃-800℃).The resu...Pyrolysis-Gas Chromatography-Mass Spectrometry(Py-GC/MS)was adopted to determine the changes in component of BG11-cultivated Desmodesmus sp.(BG11/8-10)pyrolyzed products at different temperatures(300℃-800℃).The results of analysis on a series of total ions chromatogram(TIC)showed that pyrolyzed products of BG11/8-10 at different temperature mainly included aliphatic hydrocarbons,nitrogen compounds,aromatic hydrocarbons,fatty acids,ketones,alcohols,aldehydes and furan compounds.Compared to the bio-oil(42.36%)generated by pyrolysis at 700℃,the relative content of bio-oil generated at 800℃was the highest up to 56.96%.However,higher temperature could easily cause the generation of large quantities of such pollutants as nitrogen compounds and polycyclic aromatic hydrocarbons(PAHs).Therefore,based on lower pollutant discharge and higher bio-oil yield,the optimal pyrolysis temperature of BG11/8-10 was around 700℃.展开更多
Qualitative and quantitative analyses of thermal cracking products from Desmodesmus sp.were performed based on pyrolysis-gas chromatography-mass spectrometry(Py-GC/MS)at different temperature regimes(350℃-750℃).Afte...Qualitative and quantitative analyses of thermal cracking products from Desmodesmus sp.were performed based on pyrolysis-gas chromatography-mass spectrometry(Py-GC/MS)at different temperature regimes(350℃-750℃).After further analysis of a series of total ions chromatogram(TIC)and summarized,thermal cracking products of Desmodesmus sp.at different temperature regimes can be obtained,which mainly comprised of aliphatic hydrocarbons,nitrogen compounds,aromatic hydrocarbons,fatty acids,ketones,alcohols,aldehydes and furan compounds.Compared to bio-oil production at 650℃(32.07%),Desmodesmus sp.pyrolyzed at 750℃could produce the highest bio-oil content of 42.25%.However,higher temperature could lead to the formation of contaminants(nitrogen compounds and PAHs)more easily.Therefore,considering the higher content of bio-oil conversion and less pollutants generation,the optimum temperature for Desmodesmus sp.thermal cracking conversion was about 650℃.展开更多
基金Beijing Municipal Science and Technology Plan Projects(No.D161100006016001)。
文摘Pyrolysis-Gas Chromatography-Mass Spectrometry(Py-GC/MS)was adopted to determine the changes in component of BG11-cultivated Desmodesmus sp.(BG11/8-10)pyrolyzed products at different temperatures(300℃-800℃).The results of analysis on a series of total ions chromatogram(TIC)showed that pyrolyzed products of BG11/8-10 at different temperature mainly included aliphatic hydrocarbons,nitrogen compounds,aromatic hydrocarbons,fatty acids,ketones,alcohols,aldehydes and furan compounds.Compared to the bio-oil(42.36%)generated by pyrolysis at 700℃,the relative content of bio-oil generated at 800℃was the highest up to 56.96%.However,higher temperature could easily cause the generation of large quantities of such pollutants as nitrogen compounds and polycyclic aromatic hydrocarbons(PAHs).Therefore,based on lower pollutant discharge and higher bio-oil yield,the optimal pyrolysis temperature of BG11/8-10 was around 700℃.
基金supported by the Beijing Municipal Science and Technology Plan Projects(No.D161100006016001)Beijing Municipal Key Discipline of Biomass Engineering.
文摘Qualitative and quantitative analyses of thermal cracking products from Desmodesmus sp.were performed based on pyrolysis-gas chromatography-mass spectrometry(Py-GC/MS)at different temperature regimes(350℃-750℃).After further analysis of a series of total ions chromatogram(TIC)and summarized,thermal cracking products of Desmodesmus sp.at different temperature regimes can be obtained,which mainly comprised of aliphatic hydrocarbons,nitrogen compounds,aromatic hydrocarbons,fatty acids,ketones,alcohols,aldehydes and furan compounds.Compared to bio-oil production at 650℃(32.07%),Desmodesmus sp.pyrolyzed at 750℃could produce the highest bio-oil content of 42.25%.However,higher temperature could lead to the formation of contaminants(nitrogen compounds and PAHs)more easily.Therefore,considering the higher content of bio-oil conversion and less pollutants generation,the optimum temperature for Desmodesmus sp.thermal cracking conversion was about 650℃.