Mg2Sn(100)surfaces were investigated using ab-initio method based on density functional theory in order to explore the surface properties.It is found that both the eleven-layers for Mg-termination surfaces and the nin...Mg2Sn(100)surfaces were investigated using ab-initio method based on density functional theory in order to explore the surface properties.It is found that both the eleven-layers for Mg-termination surfaces and the nine-layers for Sn-termination surfaces are all converged very well.The effects of relaxation mainly occurred within the three outermost atomic layers for both Mg and Sn terminations during the surface relaxation.Mg-termination surfaces are more stable than Sn-termination surfaces according to the analysis of surface energy.The density of states reveals the metallic property of both Mg-termination and Sn-termination surfaces.Covalent bonding exists in Mg2Sn(100)surfaces according to the analysis of partial density of states.展开更多
The as-cast Ti_(48)Zr_(27)Cu_(6)Nb_(5)Be_(14)bulk metallic glass matrix composites(BMGMCs)were fabricated using a copper mold suction casting method.Then,the semi-solid BMGMC samples were obtained following an isother...The as-cast Ti_(48)Zr_(27)Cu_(6)Nb_(5)Be_(14)bulk metallic glass matrix composites(BMGMCs)were fabricated using a copper mold suction casting method.Then,the semi-solid BMGMC samples were obtained following an isothermal treatment(heating at 900°C for 10 min,then cooling with water).The microstructure and compression property were investigated by scanning electronic microscopy(SEM)and universal mechanical tester.As a result of the isothermal treatment,the crystal shapes change from fine,granular,and dendritic to spherical or vermicular,and the average crystal size of the as-cast and semi-solid samples is 2.2μm and 18.1μm,respectively.The plasticity increases from 5.31%in the as-cast to 10.23%in the semi-solid samples,with an increase of 92.66%.The shear bands from different areas of the side surfaces of as-cast and semisolid compression fracture samples were observed.The characteristic changes of multiplicity,bend,branch and intersection of shear bands in different areas indicate that the deformation of as-cast and semi-solid samples is non-uniform during compression.It is found that poor plasticity of the as-cast samples or good plasticity of the semi-solid samples are reflected by characteristics of the shear bands.The semi-solid isothermal treatment improves the plasticity by forming large crystals which can block the expansion of shear bands and promote the multiplicity of shear bands.展开更多
A nanocrystalline layer （NL） was fabricated on the surface of AZ31 magnesium （Mg） alloy sheet by surface mechanical attrition treatment （SMAT）. The microstructure of the Mg alloy was characterized by optical mic...A nanocrystalline layer （NL） was fabricated on the surface of AZ31 magnesium （Mg） alloy sheet by surface mechanical attrition treatment （SMAT）. The microstructure of the Mg alloy was characterized by optical microscopy, X-ray diffraction and microhardness test. The results showed that both the microstructure and microhardness of AZ31 Mg alloy sheet after SMAT revealed a gradient distribution along depth from surface to center. The thermal stability of the NL was investigated through characterizing the microstructure evolution during the post-isothermal annealing treatment within the temperature range from 150 to 250℃. The NL exhibits a certain degree of thermal stability below 150 ℃, while it disappears quickly when annealing at the temperature range of 200-250 ℃. The grain growth kinetics of the nanocrystalline of AZ31 Mg alloy induced by SMAT was investigated. The activation energy of nanocrystalline AZ31 Mg alloy was obtained with a value of 92.8 kJ/mol.展开更多
The microstructure and mechanical properties of Mg–6Zn–1Y and Mg–6Zn–3Y（wt%） alloys under different cooling rates were investigated. The results show that the second dendrite arm spacing（SDAS） of Mg–6Zn–1Y a...The microstructure and mechanical properties of Mg–6Zn–1Y and Mg–6Zn–3Y（wt%） alloys under different cooling rates were investigated. The results show that the second dendrite arm spacing（SDAS） of Mg–6Zn–1Y and Mg–6Zn–3Y is reduced by 32 and 30% with increasing cooling rates（Rc） from 10.2 to 23 K/s, which can be predicted using a empirical model of SDAS=68 R 0：45：45cand SDAS=73 R 0c, respectively. The compressive strength of both alloys increases with increasing the cooling rate, which is attributed to the increase of volume fraction（Vf） of secondary phases under high cooling rate. The interaction of the cooling rate and component with SDAS has been theoretically analyzed using interdependence theory.展开更多
基金Project(51674144)supported by the National Natural Science Foundation of ChinaProject(KJLD14016)supported by the Luodi Research Plan of Jiangxi Educational Department,China+1 种基金Projects(20122BAB206021,20133ACB21003)supported by the Natural Science Foundation of Jiangxi Province,ChinaProject(20122BCB23001)supported by the Young Scientists Cultivating Program of Jiangxi Province,China
基金This work was supported by the National Natural Science Foundation of China(Nos.51464034 and 51301107).
文摘Mg2Sn(100)surfaces were investigated using ab-initio method based on density functional theory in order to explore the surface properties.It is found that both the eleven-layers for Mg-termination surfaces and the nine-layers for Sn-termination surfaces are all converged very well.The effects of relaxation mainly occurred within the three outermost atomic layers for both Mg and Sn terminations during the surface relaxation.Mg-termination surfaces are more stable than Sn-termination surfaces according to the analysis of surface energy.The density of states reveals the metallic property of both Mg-termination and Sn-termination surfaces.Covalent bonding exists in Mg2Sn(100)surfaces according to the analysis of partial density of states.
基金supported by the National Natural Science Foundation of China(Nos.:51674144,11364031)the Luodi Research Plan of Jiangxi Educational Department(No.:KJLD14016)+1 种基金the Nature Science Foundation of Jiangxi Province(Nos.:20122BAB206021,20133ACB21003)the Jiangxi Province Young Scientists Cultivating Programs(No.:20122BCB23001)。
文摘The as-cast Ti_(48)Zr_(27)Cu_(6)Nb_(5)Be_(14)bulk metallic glass matrix composites(BMGMCs)were fabricated using a copper mold suction casting method.Then,the semi-solid BMGMC samples were obtained following an isothermal treatment(heating at 900°C for 10 min,then cooling with water).The microstructure and compression property were investigated by scanning electronic microscopy(SEM)and universal mechanical tester.As a result of the isothermal treatment,the crystal shapes change from fine,granular,and dendritic to spherical or vermicular,and the average crystal size of the as-cast and semi-solid samples is 2.2μm and 18.1μm,respectively.The plasticity increases from 5.31%in the as-cast to 10.23%in the semi-solid samples,with an increase of 92.66%.The shear bands from different areas of the side surfaces of as-cast and semisolid compression fracture samples were observed.The characteristic changes of multiplicity,bend,branch and intersection of shear bands in different areas indicate that the deformation of as-cast and semi-solid samples is non-uniform during compression.It is found that poor plasticity of the as-cast samples or good plasticity of the semi-solid samples are reflected by characteristics of the shear bands.The semi-solid isothermal treatment improves the plasticity by forming large crystals which can block the expansion of shear bands and promote the multiplicity of shear bands.
基金provided by the Grant 2012CB932203 of the National Key Basic Research Program of the Chinese Ministry of Science and Technology and Technologythe Croucher Foundation (No. 9500006)+4 种基金Hong Kong Collaborative Research Fund (CRF) Scheme (No. C402814G)the National Natural Science Foundation of China (No. 51464034)the Hong Kong Scholars Program (No. XJ2012025)the China Postdoctoral Science Foundation funded project (Nos. 2012T50594, 2014M551866)the Jiangxi Postdoctoral Science Foundation (No. 2014KY11)
文摘A nanocrystalline layer （NL） was fabricated on the surface of AZ31 magnesium （Mg） alloy sheet by surface mechanical attrition treatment （SMAT）. The microstructure of the Mg alloy was characterized by optical microscopy, X-ray diffraction and microhardness test. The results showed that both the microstructure and microhardness of AZ31 Mg alloy sheet after SMAT revealed a gradient distribution along depth from surface to center. The thermal stability of the NL was investigated through characterizing the microstructure evolution during the post-isothermal annealing treatment within the temperature range from 150 to 250℃. The NL exhibits a certain degree of thermal stability below 150 ℃, while it disappears quickly when annealing at the temperature range of 200-250 ℃. The grain growth kinetics of the nanocrystalline of AZ31 Mg alloy induced by SMAT was investigated. The activation energy of nanocrystalline AZ31 Mg alloy was obtained with a value of 92.8 kJ/mol.
基金financially supported by the National Natural Science Foundation of China (NO. 51464034)the Cooperation and Exchanges of Nanchang City (2012DWHZXCL@JDYTH-001)+5 种基金the Educational Commission of Jiangxi Province (No. GJJ13069)the Innovation Fund Designated for Graduate Students of Jiangxi Province (No. YC2013-S027)the Hong Kong Scholars Program (No. XJ2012025)the China Post-doctoral Science Foundation funded project (No. 2012T50594, 2014M551866)the Jiangxi Post-doctoral Science Foundation (No. 2014KY11)Doctoral Fund of Ministry of Education of China (No. 20113601110008)
文摘The microstructure and mechanical properties of Mg–6Zn–1Y and Mg–6Zn–3Y（wt%） alloys under different cooling rates were investigated. The results show that the second dendrite arm spacing（SDAS） of Mg–6Zn–1Y and Mg–6Zn–3Y is reduced by 32 and 30% with increasing cooling rates（Rc） from 10.2 to 23 K/s, which can be predicted using a empirical model of SDAS=68 R 0：45：45cand SDAS=73 R 0c, respectively. The compressive strength of both alloys increases with increasing the cooling rate, which is attributed to the increase of volume fraction（Vf） of secondary phases under high cooling rate. The interaction of the cooling rate and component with SDAS has been theoretically analyzed using interdependence theory.
