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Atomically Precise Insights into Metal–Metal Bonds Using Comparable Endo-Units of Sc_(2) and Sc_(2)C_(2)
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作者 Yang-Rong Yao xiang-mei shi +4 位作者 Shan-Yu Zheng Zuo-Chang Chen Su-Yuan Xie Rong-Bin Huang Lan-Sun Zheng 《CCS Chemistry》 CAS 2021年第12期294-302,共9页
The precise identification of metal-metal bonds is critical to fully understanding the nature of metal-metal bonding but remains a fundamental challenge.Herein,we show the essence of Sc-Sc bonds with a metal-metal dis... The precise identification of metal-metal bonds is critical to fully understanding the nature of metal-metal bonding but remains a fundamental challenge.Herein,we show the essence of Sc-Sc bonds with a metal-metal distance of 3.36 Å in a C_(3v)(8)-C_(82) fullerene cage using crystallography. 展开更多
关键词 endohedral fullerenes metal–metal bond X-ray single-crystal diffraction metal carbide SCANDIUM
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