The effect of F,K,and Na on the solid phase reaction of the Baiyunebo iron ore was investigated by differential thermal analysis （DTA） and X-ray diffraction（XRD）.It has been identified that alkaline elements K and...The effect of F,K,and Na on the solid phase reaction of the Baiyunebo iron ore was investigated by differential thermal analysis （DTA） and X-ray diffraction（XRD）.It has been identified that alkaline elements K and Na in the Baiyunebo ore instigate the formation of low melting point compounds Na2SiO3 and Na2O·Fe2O3 and the generation of molten state in the solid phase sintering.Element F in the Baiyunebo ore facilitates the formation of cuspidine compound 3CaO·2SiO2·CaF2 in the solid phase reaction.The cuspidine compound is kept in solid as one of the final products through the entire sintering process due to its high melting point.In the sintering process,CaF2and SiO2 react with CaO first and form 3CaO·2SiO2·CaF2 and 3CaO·2SiO2,so the formation of ferrites,Na2O·Fe2O3,and 2CaO·Fe2O3 is inhibited.展开更多
基金supported by the National Natural Science Foundation of China(No.50664006)
文摘The effect of F,K,and Na on the solid phase reaction of the Baiyunebo iron ore was investigated by differential thermal analysis （DTA） and X-ray diffraction（XRD）.It has been identified that alkaline elements K and Na in the Baiyunebo ore instigate the formation of low melting point compounds Na2SiO3 and Na2O·Fe2O3 and the generation of molten state in the solid phase sintering.Element F in the Baiyunebo ore facilitates the formation of cuspidine compound 3CaO·2SiO2·CaF2 in the solid phase reaction.The cuspidine compound is kept in solid as one of the final products through the entire sintering process due to its high melting point.In the sintering process,CaF2and SiO2 react with CaO first and form 3CaO·2SiO2·CaF2 and 3CaO·2SiO2,so the formation of ferrites,Na2O·Fe2O3,and 2CaO·Fe2O3 is inhibited.
