Phase-Transfer-Catalyzed Intramolecular Hydroaryloxylation and Hydroamination of C≡C Triple Bonds: An Efficient Synthesis of Benzo[<i>b</i>]furan and 3-Methyleneisoindoline-1-one Derivatives

Phase-transfer-catalyzed intramolecular cyclization reaction of forming benzo[b]furan and 3-methyleneisoin- doline-1-one derivatives has been developed. The cyclization reaction of propargylic carbonates was also de- scribed under metal-free condition and the reaction was reported by Pd and Ni before. The reaction condi- tions and the scope of the process are examined. The catalysts are cheap and environmentally friendly and the substrates are readily available and the procedure is simple, rapid, and general. The development of C-O and C-N bond formation processes via an overall structural isomerization represents the most atom-eco- nomical approach.

Time-resolution enhanced multi-path OTD measurement using an adaptive filter based incoherent OFDR

High accuracy and time resolution optical transfer delay(OTD)measurement is highly desired in many multi-path applications,such as optical true-time-delay-based array systems and distributed optical sensors.However,the time resolution is usually limited by the frequency range of the probe signal in frequency-multiplexed OTD measurement techniques.Here,we proposed a time-resolution enhanced OTD measurement method based on incoherent optical frequency domain reflectometry(I-OFDR),where an adaptive filter is designed to suppress the spectral leakage from other paths to break the resolution limitation.A weighted least square(WLS)cost function is first established,and then an iteration approach is used to minimize the cost function.Finally,the appropriate filter parameter is obtained according to the convergence results.In a proof-of-concept experiment,the time-domain response of two optical links with a length difference of 900 ps is successfully estimated by applying a probe signal with a bandwidth of 400 MHz.The time resolution is improved by 2.78times compared to the theoretical resolution limit of the inverse discrete Fourier transform(iDFT)algorithm.In addition,the OTD measurement error is below±0.8 ps.The proposed algorithm provides a novel way to improve the measurement resolution without applying a probe signal with a large bandwidth,avoiding measurement errors induced by the dispersion effect.

High-accuracy optical time delay measurement in fiber link [Invited]

Optoelectronic components and subsystems such as optically controlled phased array antennas,distributed radar networks,interferometric optical fiber hydrophones,and high-speed optoelectronic chips demand highaccuracy optical time delay measurement with large measurement range and the capability for single-end and wavelength-dependent measurement.In this paper,the recent advances in the optical time delay measurement of a fiber link with high accuracy are reviewed.The general models of the typical time delay measurement technologies are established with the operational principle analyzed.The performance of these techniques is also discussed.

Ultra-high resolution microwave photonic radar with post-bandwidth synthesis

We demonstrate microwave photonic radar with post-bandwidth synthesis, which can realize target detection with ultra-high range resolution using relatively small-bandwidth radio frequency(RF) frontends. In the proposed radar, two temporal-overlapped linear frequency-modulated(LFM) signals with the same chirp rate and different center frequencies are transmitted. By post-processing the de-chirped echoes in the receiver, a signal equivalent to that de-chirped from an LFM signal with the combined bandwidth is achieved. In a proof-ofconcept experiment, two LFM signals with bandwidths of 8.4 GHz are exploited to achieve radar detection with an equivalent bandwidth of 16 GHz, and a range resolution of 1 cm is obtained.