Transparent afterglow crystals are keenly desired for three-dimensional information storage.Herein,CsCdCl3 perovskite crystals were grown by a programmable cool-ing procedure in a hydrothermal reactor.The pristine cry...Transparent afterglow crystals are keenly desired for three-dimensional information storage.Herein,CsCdCl3 perovskite crystals were grown by a programmable cool-ing procedure in a hydrothermal reactor.The pristine crystal showed an abnormal optical behavior where the absorption increased by 2.3 folds at high temperature,leading to a fourfold boost of photoluminescence(PL)intensity.After Mn2+dop-ing,the PL quantum yield was improved to nearly unity.Importantly,the doped crystals exhibited an ultralong afterglow up to 12 h after ceasing UV excitation and a high transmittance up to 75%in the visible region.This work brought a new mem-ber to the library of transparent afterglow crystal,opening up many possibilities to advanced applications such as volumetric display and three-dimensional information encryption.展开更多
BiOCl crystal shows potential as efficient optical host due to its special layered structure. Here,the luminescence properties of the Er^3＋/Sm^3＋ co-doped BiOCl phosphors as single-phase phosphors were reported. Upo...BiOCl crystal shows potential as efficient optical host due to its special layered structure. Here,the luminescence properties of the Er^3＋/Sm^3＋ co-doped BiOCl phosphors as single-phase phosphors were reported. Upon near ultraviolet excitation（NUV, 380 nm corresponding the ^4 I15/2→ ^4 G11/2 transition of Er^3＋ ions）, the phosphors exhibit the efficient characteristic emissions of Er^3＋ and Sm^3＋ ions simultaneously. The energy transfer（ET） from Er^3＋ to Sm^3＋ ions in the layered crystals has been validated by the variation of emission intensities and decay lifetimes respectively, which is ascribed to be a dipoledipole interaction. By virtue of the ET behavior and increasing Sm^3＋ ion concentration, the enhancing emission intensity of Sm^3＋ and the tunability of emission color from yellowish-green（0.318, 0.420） to white（0.343, 0.347） are realized. The results of our work indicate that the Er^3＋/Sm^3＋ co-doped BiOCI phosphor has a promising application serving as single component white emitting phosphors for NUV excited WLEDs.展开更多
基金Natural Science Foundation of Shandong Province,Grant/Award Number:ZR2020YQ12Young Taishan Scholars Program of Shandong Province,Grant/Award Number:tsqn201812082。
文摘Transparent afterglow crystals are keenly desired for three-dimensional information storage.Herein,CsCdCl3 perovskite crystals were grown by a programmable cool-ing procedure in a hydrothermal reactor.The pristine crystal showed an abnormal optical behavior where the absorption increased by 2.3 folds at high temperature,leading to a fourfold boost of photoluminescence(PL)intensity.After Mn2+dop-ing,the PL quantum yield was improved to nearly unity.Importantly,the doped crystals exhibited an ultralong afterglow up to 12 h after ceasing UV excitation and a high transmittance up to 75%in the visible region.This work brought a new mem-ber to the library of transparent afterglow crystal,opening up many possibilities to advanced applications such as volumetric display and three-dimensional information encryption.
基金Project supported by the National Natural Science Foundation of China(No.61465006)the Reserve talents project of Yunnan Province(2015HB013)
文摘BiOCl crystal shows potential as efficient optical host due to its special layered structure. Here,the luminescence properties of the Er^3＋/Sm^3＋ co-doped BiOCl phosphors as single-phase phosphors were reported. Upon near ultraviolet excitation（NUV, 380 nm corresponding the ^4 I15/2→ ^4 G11/2 transition of Er^3＋ ions）, the phosphors exhibit the efficient characteristic emissions of Er^3＋ and Sm^3＋ ions simultaneously. The energy transfer（ET） from Er^3＋ to Sm^3＋ ions in the layered crystals has been validated by the variation of emission intensities and decay lifetimes respectively, which is ascribed to be a dipoledipole interaction. By virtue of the ET behavior and increasing Sm^3＋ ion concentration, the enhancing emission intensity of Sm^3＋ and the tunability of emission color from yellowish-green（0.318, 0.420） to white（0.343, 0.347） are realized. The results of our work indicate that the Er^3＋/Sm^3＋ co-doped BiOCI phosphor has a promising application serving as single component white emitting phosphors for NUV excited WLEDs.
