(Bal-xSrx)4(Sm0.4Nd0.6)28/3Ti18O54 (x=0.02,0.04,0.06,0.08,0.1) solid solutions were prepared by the conventional solid-state reaction process.It was found that (Ba1-xSrx)4(Sm0.4Nd0.6)28/3 Ti18O54 ceramics are fully co...(Bal-xSrx)4(Sm0.4Nd0.6)28/3Ti18O54 (x=0.02,0.04,0.06,0.08,0.1) solid solutions were prepared by the conventional solid-state reaction process.It was found that (Ba1-xSrx)4(Sm0.4Nd0.6)28/3 Ti18O54 ceramics are fully composed of BaSm2Ti4O12 and BaNd2TisO14 phases for all the compositions.The increasing x value (0.02 ≤ x ≤ 0.1) in (Ba1-xSrx)4(Sm0.4Nd0.6)28/3Ti18O54 ceramics can not only obtain high Q ×f value but also effectively enhance the permittivity (εr).The (Ba1-xSrx)4(Sm0.4Nd0.6)28/3Ti18O54 ceramic with x=0.08,sintered at 1440 ℃ for 4 h,shows excellent microwave dielectric properties of permittivity (εr) ≈ 93.19,quality factor (Q × f) ≈ 9770.14 GHz (at 3.415 GHz),and almost near-zero temperature coefficient of resonant frequency (rf)≈ +4.56 ppm/℃.展开更多
基金Financial supports of the National Natural Science Foundation of China，the Middle-aged and Young Teachers in Colleges and/or Universities in Guangxi Basic Ability Promotion Project of China (Grant No.KY2016YB534) are gratefully acknowledged by the authors
文摘(Bal-xSrx)4(Sm0.4Nd0.6)28/3Ti18O54 (x=0.02,0.04,0.06,0.08,0.1) solid solutions were prepared by the conventional solid-state reaction process.It was found that (Ba1-xSrx)4(Sm0.4Nd0.6)28/3 Ti18O54 ceramics are fully composed of BaSm2Ti4O12 and BaNd2TisO14 phases for all the compositions.The increasing x value (0.02 ≤ x ≤ 0.1) in (Ba1-xSrx)4(Sm0.4Nd0.6)28/3Ti18O54 ceramics can not only obtain high Q ×f value but also effectively enhance the permittivity (εr).The (Ba1-xSrx)4(Sm0.4Nd0.6)28/3Ti18O54 ceramic with x=0.08,sintered at 1440 ℃ for 4 h,shows excellent microwave dielectric properties of permittivity (εr) ≈ 93.19,quality factor (Q × f) ≈ 9770.14 GHz (at 3.415 GHz),and almost near-zero temperature coefficient of resonant frequency (rf)≈ +4.56 ppm/℃.
