3D anchoring structured for LiFe_(0.5)Mn_(0.5)PO_(4)@cornstalk-C cathode materials

The organic carbon source coating LiFe_(x)Mn_(1-x)PO_(4)suffers from the problem of non-uniform carbon cladding.Too thick carbon cladding layer instead hinders the de-embedding of lithium ions.In this paper,we choose cornstalk as the carbon source,then LiFe_(0.5)Mn_(0.5)PO_(4)@cornstalk-C(LFMP@C-C)with 3D anchoring structure is prepared by the solvothermal method.The results show that the LFMP with cornstalk as the carbon source has better performance compared to the sucrose-coated LFMP material(LFMP@C).The discharge capacity of LFMP@C-C is 116 mAh/g for the first cycle at 1 C and the capacity retention rate is 94.0%after 500 cycles,and the discharge capacity of LFMP@C-C is more than 17.17%higher than that of LFMP@C.

Surface modification of Li_(3)InCl_(6)provides superior electrochemical performance for LiMn_(2)O_(4)cathode materials

Li Mn_(2)O_(4)(LMO)is the substance of choice for small and medium-sized energy storage materials in daily life.In this work,Li3InCl6(LIC)is prepared on the surface of LiMn_(2)O_(4)by hydrothermal method using InCl_(3)and LiCl as raw materials.This method stabilizes the LMO crystal structure by uniformly coating the LIC on the LMO surface and effectively maintains the morphology of LMO crystals during the cycling process.SEM and EDS analysis confirm the morphology and homogeneity of the synthesized material LIC on the LMO surface.The prepared material is put into a battery,and the charge-discharge test is carried out at 0.5 C and 1 C.The results show that the LIC surface-modified samples exhibit more than 6%higher cycling performance than the unmodified samples after long cycling.