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Effect of V and Nb additions on microstructure,properties,and deformability of Ti-45Al-9 (V,Nb,Y) alloy 被引量:3
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作者 Yang Fei Kong Fantao +1 位作者 Chen Yuyong xiao shulong 《China Foundry》 SCIE CAS 2010年第4期357-361,共5页
Ti-45Al-9(V, Nb, Y) alloys with four different x=V/Nb (atomic ratio x = 1, 1.5, 2 and 3.5) have been prepared, and the microstructures, properties and hot deformation behaviors were investigated. SEM, XRD and TEM resu... Ti-45Al-9(V, Nb, Y) alloys with four different x=V/Nb (atomic ratio x = 1, 1.5, 2 and 3.5) have been prepared, and the microstructures, properties and hot deformation behaviors were investigated. SEM, XRD and TEM results showed that Ti-45Al-9(V, Nb, Y) alloys were mainly composed of γ, α 2 , and β phase, and the volume fraction of β phase increased with the increase of the atomic ratio of V/Nb. The alloys were featured with lamellar microstructure with β and γ phases locating at the colony boundaries, and some β precipitates appearing at γ/γ interfaces. It was found that the colony size decreased with the increase of x. The alloys exhibited moderate mechanical properties at room temperature, with a yield strength of over 600 MPa, and fractures showed mainly translamellar character. The alloy with x=3.5 exhibited the best deformability at elevated temperature and that with x=1 had superior oxidation resistance at 800 ℃. 展开更多
关键词 TiAl 合金 微观结构和性质 热变丑行为 氧化
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Effect of yttrium on microstructure and mold filling capacity of a near-α high temperature titanium alloy 被引量:1
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作者 Zhao Ertuan Chen Yuyong +2 位作者 Kong Fantao Zhang Changjiang xiao shulong 《China Foundry》 SCIE CAS 2012年第4期344-348,共5页
The addition of rare earth yttrium(Y) can improve the performances of high temperature titanium alloys,such as the tensile ductility,thermal stability and creep property,etc.However,few studies on the effect of Y on t... The addition of rare earth yttrium(Y) can improve the performances of high temperature titanium alloys,such as the tensile ductility,thermal stability and creep property,etc.However,few studies on the effect of Y on the castability of titanium alloys have been carried out,which is significant to fabrication of thin-walled complex titanium castings by investment casting.In this study,the microstructure and mold filling capacity of a Ti-1100 alloy with different Y additions(0,0.1wt.%,0.3wt.%,0.5wt.% and 1.0wt.%) were investigated systematically through investment casting experiments,and the casting experiments were carried out in a centrifugal titanium casting machine.The microstructures of the alloy were observed via the optical microscopy,scanning electron microscopy and transmission electron microscopy.The mold filling capacity was tested by using of a grid pattern and was evaluated by the number of segments completely filled by the cast alloy.The results indicate that the grain size is decreased and the mold filling capacity is improved significantly with increasing the addition of Y from 0 to 1.0wt.%.The average primary grain size of Ti-1100 alloy is reduced from 250 μm to 50 μm and the mold filling capacity is increased from 61.5% to 100%.Considering the potential harmful effect on tensile properties of titanium alloys due to high concentrations of Y,it is suggested that Y addition should be about 0.3wt.%. 展开更多
关键词 金属材料 钛材料 钛合金 组织结构
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铸态Ti-43Al-6Nb-1Mo-1Cr-0.2TiB_(2)合金高温蠕变行为研究
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作者 邵意 徐丽娟 +2 位作者 肖树龙 田竟 陈玉勇 《特种铸造及有色合金》 CAS 北大核心 2024年第2期203-211,共9页
通过XRD与SEM分析铸态Ti-43Al-6Nb-1Mo-1Cr-0.2TiB_(2)合金组织,并进行760~840℃、240~300 MPa范围内的蠕变测试,利用SEM、EBSD和TEM方法观察蠕变变形后的显微组织及断口形貌,以探究温度和应力对试验合金高温蠕变变形与断裂行为的影响... 通过XRD与SEM分析铸态Ti-43Al-6Nb-1Mo-1Cr-0.2TiB_(2)合金组织,并进行760~840℃、240~300 MPa范围内的蠕变测试,利用SEM、EBSD和TEM方法观察蠕变变形后的显微组织及断口形貌,以探究温度和应力对试验合金高温蠕变变形与断裂行为的影响。结果表明,该铸态合金为近片层组织,硼化物弥散分布在基体中。根据蠕变数据计算可得合金在测试范围内的应力指数n和蠕变激活能Q_(c)分别为6.64和388.37 kJ/mol。结合TEM观察可推知,合金的变形速率主要由位错攀移控制。结合蠕变变形后的显微组织及断口形貌可知,该合金的蠕变断裂模式主要为韧脆混合型断裂。随着温度升高,局部韧断区域增加;随着应力增大,萌生裂纹数量增多。根据EBSD和TEM分析可知,晶界处的B2相和γ相的界面存在较大的应力集中,容易萌生裂纹。此外,在蠕变过程中,硼化物不仅可以阻碍位错运动,还可促进动态再结晶。 展开更多
关键词 高Nb-TiAl合金 显微组织 蠕变 变形行为 硼化物
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纳米Y_(2)O_(3)对高Nb-TiAl合金高温抗蠕变性能的影响
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作者 肖树龙 梁振泉 +3 位作者 王鑫 郭应飞 徐丽娟 陈玉勇 《稀有金属材料与工程》 SCIE EI CAS CSCD 北大核心 2021年第6期2177-2185,共9页
在不同温度、不同应力条件下对高Nb-TiAl合金进行蠕变测试,结合扫描电子显微镜(SEM)、透射电子显微镜(TEM)等分析手段探究纳米Y_(2)O_(3)对Ti-45Al-6Nb-2.5V合金高温抗蠕变性能的影响。铸态高Nb-TiAl合金组织为α2/γ层片结构,纳米Y_(2)... 在不同温度、不同应力条件下对高Nb-TiAl合金进行蠕变测试,结合扫描电子显微镜(SEM)、透射电子显微镜(TEM)等分析手段探究纳米Y_(2)O_(3)对Ti-45Al-6Nb-2.5V合金高温抗蠕变性能的影响。铸态高Nb-TiAl合金组织为α2/γ层片结构,纳米Y_(2)O_(3)的添加可显著细化合金组织并改善合金的高温拉伸性能。蠕变分析结果得出,添加0.15%(原子分数)纳米Y_(2)O_(3)会显著改善Ti-45Al-6Nb-2.5V合金的抗蠕变性能,在800℃/300MPa条件下,合金稳态蠕变速率由2.389×10^(-7) s^(-1)降至1.500×10^(-7) s^(-1);在850℃/250 MPa条件下,合金的蠕变寿命由14.10 h延长至61.50 h。添加纳米Y_(2)O_(3)提高合金蠕变抗力的机制是Y_(2)O_(3)与基体具有较高的结合强度,可以有效阻碍位错运动,减弱孔洞萌生的倾向。经分析,2种合金在800℃/300 MPa下的蠕变行为主要受位错攀移与孪晶控制,蠕变损伤断裂机理为孔洞萌生与裂纹扩展。 展开更多
关键词 高Nb-TiAl合金 纳米Y_(2)O_(3) 抗蠕变性能 损伤断裂机理
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Ti-48Al-2Cr-2Nb-(Ni,TiB_(2))合金凝固组织演变规律及力学性能研究
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作者 王昊 谢广明 +5 位作者 贾燚 姚昊明 王涛 肖树龙 陈玉勇 韩建超 《稀有金属材料与工程》 SCIE EI CAS CSCD 北大核心 2022年第6期2316-2322,共7页
TiAl合金作为轻质耐高温材料,在一定温度范围内成为替代镍基高温合金的重要材料,但其铸态室温塑性和强度低,限制其进一步工程应用。采用真空感应凝壳熔炼工艺系制备铸锭,研究TiB_(2)和Ni元素共同添加对Ti-48Al-2Cr-2Nb合金凝固组织和力... TiAl合金作为轻质耐高温材料,在一定温度范围内成为替代镍基高温合金的重要材料,但其铸态室温塑性和强度低,限制其进一步工程应用。采用真空感应凝壳熔炼工艺系制备铸锭,研究TiB_(2)和Ni元素共同添加对Ti-48Al-2Cr-2Nb合金凝固组织和力学性能的影响。结果表明,TiB_(2)及Ni合金化后,合金的凝固路径和初生相并未改变,晶粒尺寸从700μm细化至100μm,生成片状TiB_(2)和富镍τ_(3)相,τ_(3)相的纳米硬度达到8.3 GPa,远高于片层团和块状γ相。T4822-(Ni,TiB_(2))合金的室温拉强度与基体合金相近,断裂伸长率提高30%。700~900℃时,T4822-(Ni,TiB_(2))合金的抗拉强度始终高于基体合金,在900℃时抗拉强度达到365 MPa,较基体合金提高9%。800和900℃时T4822-(Ni,TiB_(2))合金的断裂伸长率分别达到25.3%和36.1%,远高于基体合金。晶粒细化和晶界处的块状γ相是T4822-(Ni,TiB_(2))合金塑性提升的主要原因,其良好的高温强度则可以归因于片层团内部和界面处硬质硼化物和富镍τ_(3)相。 展开更多
关键词 TIAL合金 合金化 显微组织 增强相 力学性能
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