4-（2-Ferrocenylethenyl）-phenyl-POSS Fc-CH=CH-C6H6-（C5H9）7Si8O12 （FEPS, Fc： ferrocene）, containing metal and C=C double bond, was firstly synthesized as a mixture of E/Z isomers by the Wittig reaction. The chemi...4-（2-Ferrocenylethenyl）-phenyl-POSS Fc-CH=CH-C6H6-（C5H9）7Si8O12 （FEPS, Fc： ferrocene）, containing metal and C=C double bond, was firstly synthesized as a mixture of E/Z isomers by the Wittig reaction. The chemical structure of FEPS was characterized by FTIR, ^1H-, ^13C and ^29Si- NMR.展开更多
基金We gratefully acknowledge the financial support of the National Natural Science Foundation of China(Project No.CN-20374007 and CN-50203002)Key Project of Science and Technology Foundation of Ministry of Education(03023).
文摘4-（2-Ferrocenylethenyl）-phenyl-POSS Fc-CH=CH-C6H6-（C5H9）7Si8O12 （FEPS, Fc： ferrocene）, containing metal and C=C double bond, was firstly synthesized as a mixture of E/Z isomers by the Wittig reaction. The chemical structure of FEPS was characterized by FTIR, ^1H-, ^13C and ^29Si- NMR.
