Polyether moiety was introduced to the phosphinite and the phosphinite modified rhodium complex formed in situ was highly active in the hydroformylation of higher olefins in organic monophase system. After reaction, ...Polyether moiety was introduced to the phosphinite and the phosphinite modified rhodium complex formed in situ was highly active in the hydroformylation of higher olefins in organic monophase system. After reaction, on cooling to room temperature, the catalyst could precipitate out from organic phase and was easily separated by decantation and reused six times without obvious decreasing in activity.展开更多
基金This work was supported by the National Natural Science Foundation of China (Grant No. 29906001)and the Research Institute of Petroleum Processing.
文摘Polyether moiety was introduced to the phosphinite and the phosphinite modified rhodium complex formed in situ was highly active in the hydroformylation of higher olefins in organic monophase system. After reaction, on cooling to room temperature, the catalyst could precipitate out from organic phase and was easily separated by decantation and reused six times without obvious decreasing in activity.
