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自然环境中能否出现可有效降解碳氟链的微生物 被引量:2
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作者 肖子冰 邢航 +1 位作者 窦增培 肖进新 《日用化学工业》 CAS 北大核心 2021年第12期1242-1249,共8页
全氟或多氟烷基物质(PFAS)的碳氟链具有很强的化学惰性,随着环境保护和健康观念的不断加强,PFAS的大量使用引发了公众的担忧。PFAS在很多应用领域中是不可替代的,尤其是高技术领域或外部条件苛刻的场合,因此最积极的应对策略是探索可行... 全氟或多氟烷基物质(PFAS)的碳氟链具有很强的化学惰性,随着环境保护和健康观念的不断加强,PFAS的大量使用引发了公众的担忧。PFAS在很多应用领域中是不可替代的,尤其是高技术领域或外部条件苛刻的场合,因此最积极的应对策略是探索可行的后处理方法。与物理或化学法处理相比,生物降解在实施条件的便利性以及能源消耗、经济成本方面更具优势。然而,迄今尚未发现能“有效”降解PFAS的微生物,这里的“有效”是指在令人满意的时间内破坏PFAS的C-F键以实现彻底的降解。这意味着微生物要满足降解程度和降解效率的双重要求。本文详细论述了自然环境中能否产生有效降解碳氟链的微生物,以及实验室模拟这一过程可以采取的策略。同时列出了当前微生物降解PFAS的若干证据,未来,期待人类能研制培育出可有效降解碳氟链的微生物品种。 展开更多
关键词 全氟或多氟烷基物质(PFAS) 全氟辛烷磺酸及其衍生物(PFOS) 环境保护 生物降解 微生物 细菌 持久性有机污染物(POPs)
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Fluorinated Surfactants and Fluorinated Polymer Materials(Ⅰ): General Review 被引量:2
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作者 xiao Jinxin Xing Hang +1 位作者 Dou Zengpei xiao zibing 《China Detergent & Cosmetics》 2019年第1期52-62,共11页
Fluorinated surfactants and fluorinated functional materials were introduced. Their fundamental concept, classification and structure, major physicochemical properties, industrial production methods, as well as applic... Fluorinated surfactants and fluorinated functional materials were introduced. Their fundamental concept, classification and structure, major physicochemical properties, industrial production methods, as well as applications in industrial and high technological fields were summarized. Their current environmental problems and the countermeasures in this field were also briefed. 展开更多
关键词 FLUORINATED SURFACTANT FLUORINATED FUNCTIONAL materials FLUOROPOLYMER PFOS POPS
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Fluorinated Surfactants and Fluorinated Polymer Materials(Ⅱ):Environmental and Safety Issues 被引量:2
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作者 Xing Hang Dou Zengpei +1 位作者 xiao zibing xiao Jinxin 《China Detergent & Cosmetics》 2019年第2期66-79,共14页
The environmental and safety issues of perfluorooctane sulfonyl fluoride/perfluorooctane sulfonic acid/ perfluorooctane sulfonates (PFOS) were introduced in detail by summarizing several published reviews, including t... The environmental and safety issues of perfluorooctane sulfonyl fluoride/perfluorooctane sulfonic acid/ perfluorooctane sulfonates (PFOS) were introduced in detail by summarizing several published reviews, including their production, occurrence and emission in environment, exposure and intake to human being, supervision and emission reduction, long-distance transport, bioaccumulation and excretion, degradation and toxicity. Opinion with respect to safety issues of PFOS was also proposed in view of surfactant working field in order to upgrade their application value. The overreaction in the current state for the fear of “fluorine” was concerned. For fire-fighting foams, the issue of “safety” needs to be critically weighed. 展开更多
关键词 FLUOROCARBON surfactant FLUOROPOLYMER PFOS POPS PFOA
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Fluorinated Surfactants and Fluorinated Polymer Materials(Ⅳ): Strategy for Solving PFOS Problems
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作者 Xing Hang Dou Zengpei +1 位作者 xiao zibing xiao Jinxin 《China Detergent & Cosmetics》 2019年第4期69-76,共8页
Fluorinated alkyl substances are irreplaceable in many fields because of the special properties of fluorocarbon chains.Many efforts have been made to solve the historic problems of PFOS.In this paper,several strategie... Fluorinated alkyl substances are irreplaceable in many fields because of the special properties of fluorocarbon chains.Many efforts have been made to solve the historic problems of PFOS.In this paper,several strategies were discussed,including the possibilities in the methods of degradation,separation,recycling use,and reducing the using concentration.The most reliable one is to obtain replacement products of PFOS.Several kinds of replacement products were introduced and their feasibility of application was also discussed. 展开更多
关键词 fluorocarbon surfactant POPS PFOA BIOACCUMULATION TOXICITY sustainability regulation
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Fluorinated Surfactants and Fluorinated Polymer Materials(Ⅲ): Personal Opinion on the Problems of PFOS
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作者 Xing Hang Dou Zengpei +1 位作者 xiao zibing xiao Jinxin 《China Detergent & Cosmetics》 2019年第3期54-62,共9页
As surfactant researchers, we have discussed the current problems of PFOS in China from our personal standpoint. The difficulties in both elimination and investigation on PFOS are analyzed. The production, application... As surfactant researchers, we have discussed the current problems of PFOS in China from our personal standpoint. The difficulties in both elimination and investigation on PFOS are analyzed. The production, application, biodegradation and regulation for some other important fluorinated alkylated substances are also briefly introduced. Finally, the objective and tasks for surfactant researchers are pointed out. 展开更多
关键词 FLUORINATED surfactant FLUOROPOLYMER PFOS POPs PFOA
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