Colloidal zinc oxide(ZnO) nanocrystals generated from the high temperature and nonaqueous approache are attractive for use in solution-processed electrical and optoelectronic devices. However, the asprepared colloidal...Colloidal zinc oxide(ZnO) nanocrystals generated from the high temperature and nonaqueous approache are attractive for use in solution-processed electrical and optoelectronic devices. However, the asprepared colloidal ZnO nanocrystals by this approach are generally capped by ligands with long alkyl-chains,which is disadvantage for solution-processed devices due to hindering charge transport. Here we demonstrate an effective ligand exchange process for the colloidal ZnO nanocrystals from the high temperature and nonaqueous approach by using n-butylamine. The ligand exchange process was carefully characterized. The thin films based on colloidal ZnO nanocrystals after ligand exchange exhibited dramatically enhanced UV photoconductivity.展开更多
The extraction behavior of Sm(III), Eu(III),Er(III) and Yb(III) with 1- nitroso -2-naphthol (HA) in paraffin has been studied. The composition of,extracted complexes has been determined to be LnA(3) by slope analysis ...The extraction behavior of Sm(III), Eu(III),Er(III) and Yb(III) with 1- nitroso -2-naphthol (HA) in paraffin has been studied. The composition of,extracted complexes has been determined to be LnA(3) by slope analysis method. The effect of temperature on extraction system is also investigated and thermodynamic parameters are obtained.展开更多
基金financially supported by the National Natural Science Foundation of China (51172203)the National High Technology Research and Development Program of China (2011AA050520)+1 种基金the Public Welfare Project of Zhejiang Province (2013C31057)the Natural Science Funds for Distinguished Young Scholar of Zhejiang Province (R4110189)
文摘Colloidal zinc oxide(ZnO) nanocrystals generated from the high temperature and nonaqueous approache are attractive for use in solution-processed electrical and optoelectronic devices. However, the asprepared colloidal ZnO nanocrystals by this approach are generally capped by ligands with long alkyl-chains,which is disadvantage for solution-processed devices due to hindering charge transport. Here we demonstrate an effective ligand exchange process for the colloidal ZnO nanocrystals from the high temperature and nonaqueous approach by using n-butylamine. The ligand exchange process was carefully characterized. The thin films based on colloidal ZnO nanocrystals after ligand exchange exhibited dramatically enhanced UV photoconductivity.
文摘The extraction behavior of Sm(III), Eu(III),Er(III) and Yb(III) with 1- nitroso -2-naphthol (HA) in paraffin has been studied. The composition of,extracted complexes has been determined to be LnA(3) by slope analysis method. The effect of temperature on extraction system is also investigated and thermodynamic parameters are obtained.
