The microstructure of stress-induced martensite （SIM） in the nanocrystalline NiTi alloy was investigated by means of transmission electron microscopy （TEM）. The result shows that the multi-variant structure of the...The microstructure of stress-induced martensite （SIM） in the nanocrystalline NiTi alloy was investigated by means of transmission electron microscopy （TEM）. The result shows that the multi-variant structure of the martensite is suppressed and only single-variant martensitic twins form after tensile deformation when the grain size is smaller than 80 nm. The normal directions of the （001）B19, twin planes are all. within the range of 45° from the axial direction of the wire. The angle between twin crystals （111）M and （111）x of the SIM is also found to be smaller than that of thermally induced martensite in nanocrystalline NiTi.展开更多
V85Ni15(at%)alloy was proposed as a promising candidate for hydrogen separation membranes.To date,investigations of V85Ni15 alloy have concentrated on hydrogen permeation characteristics,and little work has been done ...V85Ni15(at%)alloy was proposed as a promising candidate for hydrogen separation membranes.To date,investigations of V85Ni15 alloy have concentrated on hydrogen permeation characteristics,and little work has been done on the microstructural development.In the present study,various fabrication and heat-treatment techniques were used to develop different microstructures which would then be tailored to achieve a desired candidate for acceptable mechanical stability while maintaining high hydrogen permeability.The arc-melted(AM)V85Ni15 alloy are supersaturated solid solution with dendritic segregation of Ni-solute atoms.Cold rolling(CR)followed by annealing at 1050℃and 850℃can produce a two-phase(V+σ)microstructure and a three-phase(V+σ+NiV3)microstructure,respectively.Very fine two-phase microstructure obtained at 1050℃involves a simultaneous reaction of second-phase precipitation and V-matrix recrystallization.Sigma phase is formed via primary precipitation,while NiV3 phase is formed by peritectoidal reaction.When AMCR samples were homogenized at1250℃for 2 h and sequential heat-treated at 850℃or900℃for 2 h,precipitation-strengthening microstructure is obtained:large grain structure of V-matrix with uniform distribution of second-phase particles produced by recrystallization and grain growth followed by precipitation process.展开更多
基金financially supported by the National Natural Science Foundation of China(No.51231008)the Key Project of Chinese Ministry of Education(No.313055)
文摘The microstructure of stress-induced martensite （SIM） in the nanocrystalline NiTi alloy was investigated by means of transmission electron microscopy （TEM）. The result shows that the multi-variant structure of the martensite is suppressed and only single-variant martensitic twins form after tensile deformation when the grain size is smaller than 80 nm. The normal directions of the （001）B19, twin planes are all. within the range of 45° from the axial direction of the wire. The angle between twin crystals （111）M and （111）x of the SIM is also found to be smaller than that of thermally induced martensite in nanocrystalline NiTi.
基金the National Natural Science Foundation of China(Nos.51875002 and 51705038)China Postdoctoral Science Foundation(No.2019M652158)the Natural Science Foundation of Jiangsu Province of China(No.BK20150268)。
文摘V85Ni15(at%)alloy was proposed as a promising candidate for hydrogen separation membranes.To date,investigations of V85Ni15 alloy have concentrated on hydrogen permeation characteristics,and little work has been done on the microstructural development.In the present study,various fabrication and heat-treatment techniques were used to develop different microstructures which would then be tailored to achieve a desired candidate for acceptable mechanical stability while maintaining high hydrogen permeability.The arc-melted(AM)V85Ni15 alloy are supersaturated solid solution with dendritic segregation of Ni-solute atoms.Cold rolling(CR)followed by annealing at 1050℃and 850℃can produce a two-phase(V+σ)microstructure and a three-phase(V+σ+NiV3)microstructure,respectively.Very fine two-phase microstructure obtained at 1050℃involves a simultaneous reaction of second-phase precipitation and V-matrix recrystallization.Sigma phase is formed via primary precipitation,while NiV3 phase is formed by peritectoidal reaction.When AMCR samples were homogenized at1250℃for 2 h and sequential heat-treated at 850℃or900℃for 2 h,precipitation-strengthening microstructure is obtained:large grain structure of V-matrix with uniform distribution of second-phase particles produced by recrystallization and grain growth followed by precipitation process.
