Hydrogen storage material has been much developed recently because of its potential for proton exchange membrane （PEM） fuel cell applications. A successful solid-state reversible storage material should meet the req...Hydrogen storage material has been much developed recently because of its potential for proton exchange membrane （PEM） fuel cell applications. A successful solid-state reversible storage material should meet the requirements of high storage capacity, suitable thermodynamic properties, and fast adsorption and desorption kinetics. Complex hydrides, including boron hydride and alanate, ammonia borane, metal organic frameworks （MOFs）, covalent organic frameworks （COFs） and zeolitic imidazolate frameworks （ZIFs）, are remarkable hydrogen storage materials because of their advantages of high energy density and safety. This feature article focuses mainly on the thermodynamics and kinetics of these hydrogen storage materials in the past few years.展开更多
基金Acknowledgements The authors gratefully acknowledged the financial support for this work from the National Basic Research Program of China （973 Program） （Grant No. 2010CB631303）, the National Natural Science Foundation of China （Grant Nos. 20833009, 20873148, 20903095, 50901070, 51071146, 51071081, and U0734005）, IUPAC （Project No. 2008-006-3-100）, Dalian Science and Technology Foundation （Grant No. 2009AllGX052）, Liaoning BaiQianWan Talents Program （Project No. 2010921050）, and the State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology （Grant No. KFJJ10-1Z）.
文摘Hydrogen storage material has been much developed recently because of its potential for proton exchange membrane （PEM） fuel cell applications. A successful solid-state reversible storage material should meet the requirements of high storage capacity, suitable thermodynamic properties, and fast adsorption and desorption kinetics. Complex hydrides, including boron hydride and alanate, ammonia borane, metal organic frameworks （MOFs）, covalent organic frameworks （COFs） and zeolitic imidazolate frameworks （ZIFs）, are remarkable hydrogen storage materials because of their advantages of high energy density and safety. This feature article focuses mainly on the thermodynamics and kinetics of these hydrogen storage materials in the past few years.
