On 20 July 2021,northern Henan Province in China experienced catastrophic flooding as a result of an extremely intense rainstorm,with a record-breaking hourly rainfall of 201.9 mm during 0800–0900 UTC and daily accum...On 20 July 2021,northern Henan Province in China experienced catastrophic flooding as a result of an extremely intense rainstorm,with a record-breaking hourly rainfall of 201.9 mm during 0800–0900 UTC and daily accumulated rainfall in Zhengzhou City exceeding 600 mm(“Zhengzhou 7.20 rainstorm”for short).The multi-scale dynamical and thermodynamical mechanisms for this rainstorm are investigated based on station-observed and ERA-5 reanalysis datasets.The backward trajectory tracking shows that the warm,moist air from the northwestern Pacific was mainly transported toward Henan Province by confluent southeasterlies on the northern side of a strong typhoon In-Fa(2021),with the convergent southerlies associated with a weaker typhoon Cempaka(2021)concurrently transporting moisture northward from South China Sea,supporting the rainstorm.In the upper troposphere,two equatorward-intruding potential vorticity(PV)streamers within the planetary-scale wave train were located over northern Henan Province,forming significant divergent flow aloft to induce stronger ascending motion locally.Moreover,the converged moist air was also blocked by the mountains in western Henan Province and forced to rise so that a deep meso-β-scale convective vortex(MβCV)was induced over the west of Zhengzhou City.The PV budget analyses demonstrate that the MβCV development was attributed to the positive feedback between the rainfall-related diabatic heating and high-PV under the strong upward PV advection during the Zhengzhou 7.20 rainstorm.Importantly,the MβCV was forced by upper-level larger-scale westerlies becoming eastward-sloping,which allowed the mixtures of abundant raindrops and hydrometeors to ascend slantwise and accumulate just over Zhengzhou City,resulting in the record-breaking hourly rainfall locally.展开更多
The outputs of the Chinese Academy of Sciences(CAS) Flexible Global Ocean–Atmosphere–Land System(FGOALS-f3-L) model for the baseline experiment of the Atmospheric Model Intercomparison Project simulation in the Diag...The outputs of the Chinese Academy of Sciences(CAS) Flexible Global Ocean–Atmosphere–Land System(FGOALS-f3-L) model for the baseline experiment of the Atmospheric Model Intercomparison Project simulation in the Diagnostic,Evaluation and Characterization of Klima common experiments of phase 6 of the Coupled Model Intercomparison Project(CMIP6) are described in this paper. The CAS FGOALS-f3-L model, experiment settings, and outputs are all given. In total,there are three ensemble experiments over the period 1979–2014, which are performed with different initial states. The model outputs contain a total of 37 variables and include the required three-hourly mean, six-hourly transient, daily and monthly mean datasets. The baseline performances of the model are validated at different time scales. The preliminary evaluation suggests that the CAS FGOALS-f3-L model can capture the basic patterns of atmospheric circulation and precipitation well, including the propagation of the Madden–Julian Oscillation, activities of tropical cyclones, and the characterization of extreme precipitation. These datasets contribute to the benchmark of current model behaviors for the desired continuity of CMIP.展开更多
Foliar diseases are common in most maize-producing regions and have caused serious yield reduction in China. To evaluate genetic resistance of parental lines actively used in maize breeding programs to major foliar di...Foliar diseases are common in most maize-producing regions and have caused serious yield reduction in China. To evaluate genetic resistance of parental lines actively used in maize breeding programs to major foliar diseases, 152 maize inbred lines were tested against northern corn leaf blight(NCLB), southern corn leaf blight(SCLB), Curvularia leaf spot(CLS),gray leaf spot(GLS), common rust, and southern rust from 2003 to 2005. A small number of lines exhibited highly resistant reactions to common rust and southern rust, but none were highly resistant to NCLB, SCLB, CLS, and GLS. Although 53.3%, 40.8%, and 80.7% of lines were resistant to NCLB, SCLB, and common rust, the resistance in most lines was moderate.Resistance to CLS, GLS, and southern rust was rare in this collection of maize lines. Five lines,313, Chang 7-2, Qi 319, Qi 318, and Shen 137, were resistant to five diseases tested. Lines belonging to heterotic subgroup PB exhibited better resistance to the foliar diseases than lines from other heterotic subgroups, such as BSSS, PA, Lancaster, LRC, and PA. The results will be of benefit to breeders for selecting lines in disease resistance breeding programs.展开更多
The Chinese Academy of Sciences(CAS)Flexible Global Ocean Atmosphere Land System(FGOALS-f3-L)model datasets prepared for the sixth phase of the Coupled Model Intercomparison Project(CMIP6)Global Monsoons Model Interco...The Chinese Academy of Sciences(CAS)Flexible Global Ocean Atmosphere Land System(FGOALS-f3-L)model datasets prepared for the sixth phase of the Coupled Model Intercomparison Project(CMIP6)Global Monsoons Model Intercomparison Project(GMMIP)Tier-1 and Tier-3 experiments are introduced in this paper,and the model descriptions,experimental design and model outputs are demonstrated.There are three simulations in Tier-1,with different initial states,and five simulations in Tier-3,with different topographies or surface thermal status.Specifically,Tier-3 contains four orographic perturbation experiments that remove the Tibetan Iranian Plateau,East African and Arabian Peninsula highlands,Sierra Madre,and Andes,and one thermal perturbation experiment that removes the surface sensible heating over the Tibetan Iranian Plateau and surrounding regions at altitudes above 500 m.These datasets will contribute to CMIP6’s value as a benchmark to evaluate the importance of long-term and short-term trends of the sea surface temperature in monsoon circulations and precipitation,and to a better understanding of the orographic impact on the global monsoon system over highlands.展开更多
Reliable estimation of the pore size distribution(PSD) in porous materials such as metal–organic frameworks(MOFs) and zeolitic imidazolate frameworks(ZIFs) is crucial for accurately assessing adsorption capacity and ...Reliable estimation of the pore size distribution(PSD) in porous materials such as metal–organic frameworks(MOFs) and zeolitic imidazolate frameworks(ZIFs) is crucial for accurately assessing adsorption capacity and corresponding selectivity. In this study, the so-called zeolitic imidazolate framework-7(ZIF-7) is successfully synthesized via relatively fast and convenient microwave technique. The morphology and structure of the obtained MOF were characterized by XRD, SEM and N_2 and CO_2adsorption/desorption isotherms at 77 K and0 °C respectively. Then, to determine the PSD of the fabricated MOF, carbon dioxide isotherms are experimentally measured at various temperatures up to atmospheric pressure. Afterward, the experimental CO_2 isotherms data are utilized in two recently proposed in-house algorithms of SHN1 and SHN2 to extract the true PSD of manufactured ZIF-7. The obtained results revealed that median pore diameter of the fabricated ZIF-7 is estimated around 0.404 nm and 0.370 nm by using CO_2 isotherms at 273 K and 298 K respectively. These values are in good agreement with the real pore diameter of 0.42 nm. Moreover, experimental data of water adsorption isotherms over four different MOFs, borrowed from literature, are employed to illustrate further effectiveness of the above algorithms on successful determination of the corresponding pore size distributions. All predicted PSDs are proved to be in good agreement with those obtained from independent methods such as topology and morphology studies.展开更多
Interannual variations of the Bay of Bengal summer monsoon (BOBSM) onset in association with El Ni-o-Southern Oscillation (ENSO) are reexamined using NCEP1, JRA-55 and ERA20C atmospheric and Hadley sea surface tempera...Interannual variations of the Bay of Bengal summer monsoon (BOBSM) onset in association with El Ni-o-Southern Oscillation (ENSO) are reexamined using NCEP1, JRA-55 and ERA20C atmospheric and Hadley sea surface temperature (SST) reanalysis datasets over the period 1900-2017. Decadal changes exist in the dependence of the BOBSM onset on ENSO, varying with the Pacific Decadal Oscillation (PDO). A higher correlation between the BOBSM onset and ENSO arises during the warm PDO epochs, with distinct late (early) onsets following El Ni-o (La Ni-a) events. In contrast, less significant correlations occur during the cold PDO epochs. The mechanism for the PDO modulating the ENSO-BOBSM onset relationship is through the variations in SST anomaly (SSTA) patterns. During the warm PDO epochs, the superimpositions of the PDO-related and ENSO-related SSTAs lead to the SSTA distribution of an El Ni-o (La Ni-a) event exhibiting significant positive (negative) SSTAs over the tropical central-eastern Pacific and Indian Ocean along with negative (positive) SSTAs, especially over the tropical western Pacific (TWP), forming a strong zonal interoceanic SSTA gradient between the TWP and tropical Indian Ocean. Significant anomalous lower tropospheric easterlies (westerlies) together with upper-tropospheric westerlies (easterlies) are thus induced over the BOB, favoring an abnormally late (early) BOBSM onset. During the cold PDO epochs, however, the superimpositions of PDO-related SSTAs with El Ni-o-related (La Ni-a-related) SSTAs lead to insignificant SSTAs over the TWP and a weak zonal SSTA gradient, without distinct circulation anomalies over the BOB favoring early or late BOBSM onsets.展开更多
Online news recommendation systems aim to address the information explosion of news and make personalized recommendations for users. The key problem of personalized news recommendation is to model users' interests...Online news recommendation systems aim to address the information explosion of news and make personalized recommendations for users. The key problem of personalized news recommendation is to model users' interests and track their changes. A common way to deal with the user modeling problem is to build user profiles from observed behavior. However, the majority of existing methods make static representations of user profiles and little research has focused on effective user modeling that could dynamically capture user interests in news topics. To address this problem, in this paper, we propose UP-TreeRec, a news recommendation framework based on a user profile tree(UP-Tree), which is a novel framework combining content-based and collaborative filtering techniques. First, by exploiting a novel topic model namely UILDA, we obtain the representation vectors for news content in a topic space as the fundamental bridge to associate user interests with news topics. Next, we design a decision tree with a dynamically changeable structure to construct a user interest profile from the user's feedback. Furthermore, we present a clustering-based multidimensional similarity computation method to select the nearest neighbor of the UP-Tree efficiently. We also provide a Map-Reduce framework-based implemen-tation that enables scaling our solution to real-world news recommendation problems. We conducted several experiments compared to the state-of-the-art approaches on real-world datasets and the experimental results demonstrate that our approach significantly improves accuracy and effectiveness in news recommendation.展开更多
A discrepancy remains in the first two leading empirical orthogonal function(EOF) modes of the tropical Pacific sea surface temperature anomaly(SSTA) based on observations since the 1980s. The EOF1 mode, representing ...A discrepancy remains in the first two leading empirical orthogonal function(EOF) modes of the tropical Pacific sea surface temperature anomaly(SSTA) based on observations since the 1980s. The EOF1 mode, representing the El Ni?o-Southern Oscillation(ENSO), is a robust result. However, the EOF2 features either El Ni?o Modoki(EM) or ENSO evolution during different periods, which is probably associated with the impacts of global warming. The underlying question is what the EOF2 mode of the tropical Pacific would be without global warming. Using the CMIP5 preindustrial scenario to exclude the influence of global warming, we find that the EOF1 mode of the tropical Pacific SSTA represents ENSO and that the EOF2 mode is not EM. According to the lead–lag correlation between the ENSO and EOF2 modes, the linkage between these two modes is as follows: …El Ni?o → EOF2 → La Ni?a →–EOF2 → El Ni?o…. By analyzing the evolution of sea surface temperature, surface wind, and subsurface ocean temperature anomalies, we find the mechanism linking the ENSO and EOF2 modes is the air–sea interaction associated with the ENSO cycle. This result suggests that the EOF2 mode represents an aspect of ENSO evolution under preindustrial conditions. Therefore, this study further indicates that the EM is probably due to the influence of global warming.展开更多
Heterogenous distribution of crops,feed and livestock across China has halted the circulation of nutrients within the agricultural system and is responsible for massive nutrient losses[1,2].Generated livestock manure ...Heterogenous distribution of crops,feed and livestock across China has halted the circulation of nutrients within the agricultural system and is responsible for massive nutrient losses[1,2].Generated livestock manure exceeded optimal crop requirements in 30%and 50%of over 2300 studied counties when there was improved recycling of nitrogen(N)and phosphorus(P)in the food chain,repectively[2].Most of these counties are located in southern and coastal areas,whereas there is a deficit of livestock manure in northern and western China.Such heterogenous distribution of crop-livestock production led to 4.0 Tg manure N and 0.9 Tg manure P[2],which are economically impossible to recycle and will end up in the surrounding environment.In addition,about 40%of feed protein consumed by domestic livestock production relied on importation,putting China’s livestock production supply at high risk in the post pandemic world[3].Hence,China is facing the twin issues of too many manure nutrients but too little feed nutrients simultaneously.展开更多
The cold tongue mode(CTM),which represents the out-of-phase relationship in sea surface temperature anomaly(SSTA)variability between the Pacific cold tongue region and elsewhere in the tropical Pacific,shows a long-te...The cold tongue mode(CTM),which represents the out-of-phase relationship in sea surface temperature anomaly(SSTA)variability between the Pacific cold tongue region and elsewhere in the tropical Pacific,shows a long-term cooling trend in the eastern equatorial Pacific.In this study,we investigate how well the CTM is reproduced in historical simulations generated by the 20 models considered in Phase 5 of the Coupled Model Intercomparison Project(CMIP5).Qualitatively,all 20 models roughly capture the cooling SSTA associated with the CTM.However,a quantitative assessment(i.e.,Taylor diagrams and the ratio of the trend between the simulations and observations)shows that only five of these 20 models(i.e.,CESM1-CAM5,CMCC-CM,FGOALS-g2,IPSL-CM5B-LR,and NorESM1-M)can reproduce with useful accuracy the spatial pattern and long-term trend of the CTM.We find that these five models generally simulate the main ocean dynamical process associated with the CTM.That is,these models adequately capture the long-term cooling trend in the vertical advection of the anomalous temperature by the mean upwelling.We conclude that the performance of these CMIP5 models,with respect to simulations of the long-term cooling trend associated with the vertical advection,and the related long-term decreasing trend of the vertical gradient of the oceanic temperature anomaly,can play an important role in successful reproduction of the CTM.展开更多
A recent UN Sustainable Development Goals(SDGs) analysis indicated a significant regression in the global SDG goal scores, particularly in SDG 2—Zero Hunger. The emissions of environmental pollution caused by meeting...A recent UN Sustainable Development Goals(SDGs) analysis indicated a significant regression in the global SDG goal scores, particularly in SDG 2—Zero Hunger. The emissions of environmental pollution caused by meeting food demands have prompted some countries to intensify their climate change mitigation efforts. These circumstances have introduced significant uncertainty to the future global sustainable food development. Additionally, a notable global challenge is the persistence of hidden hunger, primarily characterized by the insufficient consumption of high-quality animal protein. Addressing this issue would necessitate increased environmental costs to attain high-quality food security. The future food system presents a significant challenge in coordinating food security, food quality and environmental quality. This article presents a comprehensive review and proposes a three-step strategy for future agricultural development based on food security, quality, and environmental aspects. This is a novel food system transfer strategy, as it concurrently addresses both global food security and environmental thresholds. It involves the construction of an efficient food system that operates within the constraints of environmental limits. The objective is to align with global SDG indicators and to maintain natural resource consumption and pollutant emissions within planetary boundaries.展开更多
Multi-model ensemble prediction is an effective approach for improving the prediction skill short-term climate prediction and evaluating related uncertainties. Based on a combination of localized operation outputs of ...Multi-model ensemble prediction is an effective approach for improving the prediction skill short-term climate prediction and evaluating related uncertainties. Based on a combination of localized operation outputs of Chinese climate models and imported forecast data of some international operational models, the National Climate Center of the China Meteorological Administration has established the China multi-model ensemble prediction system version 1.0 (CMMEv1.0) for monthly-seasonal prediction of primary climate variability modes and climate elements. We verified the real-time forecasts of CMMEv1.0 for the 2018 flood season (June-August) starting from March 2018 and evaluated the 1991-2016 hindcasts of CMMEv1.0. The results show that CMMEv1.0 has a significantly high prediction skill for global sea surface temperature (SST) anomalies, especially for the El Nino-Southern Oscillation (ENSO) in the tropical central-eastern Pacific. Additionally, its prediction skill for the North Atlantic SST triple (NAST) mode is high, but is relatively low for the Indian Ocean Dipole (IOD) mode. Moreover, CMMEv1.0 has high skills in predicting the western Pacific subtropical high (WPSH) and East Asian summer monsoon (EASM) in the June-July-August (JJA) season. The JJA air temperature in the CMMEv1.0 is predicted with a fairly high skill in most regions of China, while the JJA precipitation exhibits some skills only in northwestern and eastern China. For real-time forecasts in March-August 2018, CMMEv1.0 has accurately predicted the ENSO phase transition from cold to neutral in the tropical central-eastern Pacific and captures evolutions of the NAST and IOD indices in general. The system has also captured the main features of the summer WPSH and EASM indices in 2018, except that the predicted EASM is slightly weaker than the observed. Furthermore, CMMEv1.0 has also successfully predicted warmer air temperatures in northern China and captured the primary rainbelt over northern China, except that it predicted much more precipitation in the middle and lower reaches of the Yangtze River than observation.展开更多
With the intention to explore excellent magnetocaloric materials, the intermetallic compound GdPd was synthesized by arc melting and heat treatment. The microstructure, magnetic and magnetocaloric properties of the in...With the intention to explore excellent magnetocaloric materials, the intermetallic compound GdPd was synthesized by arc melting and heat treatment. The microstructure, magnetic and magnetocaloric properties of the intermetallic compound of GdPd were investigated by X-ray diffraction(XRD), scanning electron microscopy(SEM) and the physical property measurement system(PPMS). A large reversible magnetocaloric effect is observed in GdPd accompanied by a second order magnetic phase transition from paramagnetism to ferromagnetism at ~39 K. The paramagnetic Curie temperature(θp) and the effective magnetic moment(μ(eff))are determined to be 34.7 K and 8.12 μB/Gd,respectively. The maximum entropy change(|△SM(Max)|) and the relative cooling power(RCP) under a field change of 5 T are estimated to be 20.14 J/(kg·K) and 433 J/kg, respectively. The giant reversible magnetocaloric effects(both the large△SM and the high RCP) together with the absence of thermal and field hysteresis make the GdPd compound an attractive candidate for low-temperature magnetic refrigeration.展开更多
Dear Editor,Phospholipid molecules are unevenly distributed in membrane bilayers of eukaryotic cells.Phosphatidylethanolamine(PE)and phosphatidylserine(PS)are concentrated in the cytoplasmic leaflet,whereas phosphatid...Dear Editor,Phospholipid molecules are unevenly distributed in membrane bilayers of eukaryotic cells.Phosphatidylethanolamine(PE)and phosphatidylserine(PS)are concentrated in the cytoplasmic leaflet,whereas phosphatidylcholine(PC)is enriched in the exoplasmic leaflet(lumenal or extracellular leaflet)(van Meer et al.2008).Type 4 P-type ATPases(P4-ATPases)are the phospholipid flippases which move specific lipids from the exoplasmic leaflet to the cytoplasmic leaflet.P4-ATPases belong to the P-type ATPase family.P4-ATPases are conserved in eukaryotes.展开更多
Using a fixed point method, in this paper we discuss the existence and uniqueness of positive solutions to a class system of nonlinear fractional differential equations with delay and obtain some new results.
基金supported by the National Natural Science Foundation of China(Grant Nos.42288101,and 42175076)the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDB40000000)the Open Research Fund Program of Plateau Atmosphere and Environment Key Laboratory of Sichuan Province(Project PAEKL-2022-K02).
文摘On 20 July 2021,northern Henan Province in China experienced catastrophic flooding as a result of an extremely intense rainstorm,with a record-breaking hourly rainfall of 201.9 mm during 0800–0900 UTC and daily accumulated rainfall in Zhengzhou City exceeding 600 mm(“Zhengzhou 7.20 rainstorm”for short).The multi-scale dynamical and thermodynamical mechanisms for this rainstorm are investigated based on station-observed and ERA-5 reanalysis datasets.The backward trajectory tracking shows that the warm,moist air from the northwestern Pacific was mainly transported toward Henan Province by confluent southeasterlies on the northern side of a strong typhoon In-Fa(2021),with the convergent southerlies associated with a weaker typhoon Cempaka(2021)concurrently transporting moisture northward from South China Sea,supporting the rainstorm.In the upper troposphere,two equatorward-intruding potential vorticity(PV)streamers within the planetary-scale wave train were located over northern Henan Province,forming significant divergent flow aloft to induce stronger ascending motion locally.Moreover,the converged moist air was also blocked by the mountains in western Henan Province and forced to rise so that a deep meso-β-scale convective vortex(MβCV)was induced over the west of Zhengzhou City.The PV budget analyses demonstrate that the MβCV development was attributed to the positive feedback between the rainfall-related diabatic heating and high-PV under the strong upward PV advection during the Zhengzhou 7.20 rainstorm.Importantly,the MβCV was forced by upper-level larger-scale westerlies becoming eastward-sloping,which allowed the mixtures of abundant raindrops and hydrometeors to ascend slantwise and accumulate just over Zhengzhou City,resulting in the record-breaking hourly rainfall locally.
基金funded by the National Key Research and development Program of China (Grant No. 2017YFA0604004)the National Natural Science Foundation of China (Grant Nos. 91737306, U1811464, 41530426, 91837101, 41730963, and 91637312)
文摘The outputs of the Chinese Academy of Sciences(CAS) Flexible Global Ocean–Atmosphere–Land System(FGOALS-f3-L) model for the baseline experiment of the Atmospheric Model Intercomparison Project simulation in the Diagnostic,Evaluation and Characterization of Klima common experiments of phase 6 of the Coupled Model Intercomparison Project(CMIP6) are described in this paper. The CAS FGOALS-f3-L model, experiment settings, and outputs are all given. In total,there are three ensemble experiments over the period 1979–2014, which are performed with different initial states. The model outputs contain a total of 37 variables and include the required three-hourly mean, six-hourly transient, daily and monthly mean datasets. The baseline performances of the model are validated at different time scales. The preliminary evaluation suggests that the CAS FGOALS-f3-L model can capture the basic patterns of atmospheric circulation and precipitation well, including the propagation of the Madden–Julian Oscillation, activities of tropical cyclones, and the characterization of extreme precipitation. These datasets contribute to the benchmark of current model behaviors for the desired continuity of CMIP.
基金Financial support provided by the Ministry of Agriculture of China (No. 2003-Q03) is gratefully appreciated
文摘Foliar diseases are common in most maize-producing regions and have caused serious yield reduction in China. To evaluate genetic resistance of parental lines actively used in maize breeding programs to major foliar diseases, 152 maize inbred lines were tested against northern corn leaf blight(NCLB), southern corn leaf blight(SCLB), Curvularia leaf spot(CLS),gray leaf spot(GLS), common rust, and southern rust from 2003 to 2005. A small number of lines exhibited highly resistant reactions to common rust and southern rust, but none were highly resistant to NCLB, SCLB, CLS, and GLS. Although 53.3%, 40.8%, and 80.7% of lines were resistant to NCLB, SCLB, and common rust, the resistance in most lines was moderate.Resistance to CLS, GLS, and southern rust was rare in this collection of maize lines. Five lines,313, Chang 7-2, Qi 319, Qi 318, and Shen 137, were resistant to five diseases tested. Lines belonging to heterotic subgroup PB exhibited better resistance to the foliar diseases than lines from other heterotic subgroups, such as BSSS, PA, Lancaster, LRC, and PA. The results will be of benefit to breeders for selecting lines in disease resistance breeding programs.
基金funded by the National Natural Science Foundation of China (Grant Nos. 91737306, 91637312, 41730963, 91837101, 91637208, 41530426)the Key Research Program of Frontier Sciences, Chinese Academy of Sciences (Grant QYZDY-SSW-DQC018)
文摘The Chinese Academy of Sciences(CAS)Flexible Global Ocean Atmosphere Land System(FGOALS-f3-L)model datasets prepared for the sixth phase of the Coupled Model Intercomparison Project(CMIP6)Global Monsoons Model Intercomparison Project(GMMIP)Tier-1 and Tier-3 experiments are introduced in this paper,and the model descriptions,experimental design and model outputs are demonstrated.There are three simulations in Tier-1,with different initial states,and five simulations in Tier-3,with different topographies or surface thermal status.Specifically,Tier-3 contains four orographic perturbation experiments that remove the Tibetan Iranian Plateau,East African and Arabian Peninsula highlands,Sierra Madre,and Andes,and one thermal perturbation experiment that removes the surface sensible heating over the Tibetan Iranian Plateau and surrounding regions at altitudes above 500 m.These datasets will contribute to CMIP6’s value as a benchmark to evaluate the importance of long-term and short-term trends of the sea surface temperature in monsoon circulations and precipitation,and to a better understanding of the orographic impact on the global monsoon system over highlands.
文摘Reliable estimation of the pore size distribution(PSD) in porous materials such as metal–organic frameworks(MOFs) and zeolitic imidazolate frameworks(ZIFs) is crucial for accurately assessing adsorption capacity and corresponding selectivity. In this study, the so-called zeolitic imidazolate framework-7(ZIF-7) is successfully synthesized via relatively fast and convenient microwave technique. The morphology and structure of the obtained MOF were characterized by XRD, SEM and N_2 and CO_2adsorption/desorption isotherms at 77 K and0 °C respectively. Then, to determine the PSD of the fabricated MOF, carbon dioxide isotherms are experimentally measured at various temperatures up to atmospheric pressure. Afterward, the experimental CO_2 isotherms data are utilized in two recently proposed in-house algorithms of SHN1 and SHN2 to extract the true PSD of manufactured ZIF-7. The obtained results revealed that median pore diameter of the fabricated ZIF-7 is estimated around 0.404 nm and 0.370 nm by using CO_2 isotherms at 273 K and 298 K respectively. These values are in good agreement with the real pore diameter of 0.42 nm. Moreover, experimental data of water adsorption isotherms over four different MOFs, borrowed from literature, are employed to illustrate further effectiveness of the above algorithms on successful determination of the corresponding pore size distributions. All predicted PSDs are proved to be in good agreement with those obtained from independent methods such as topology and morphology studies.
基金supported by the National Key Research and Development Program of China (Grant No. 2018YFC1506004)the Priority Research Program of the Chinese Academy of Sciences (Grant Nos. XDA19070404 and QYZDY-SSW-DQC018)+3 种基金the Natural Science Foundation of China (Grant Nos. 41705065, 41876020 and 41730963)the SOA Program on Global Change and Air-Sea Interactions (Grant No. GASI-IPOVAI-03)the Foundation of Sichuan Education Department (Grant No. 18ZB0122)the Open Foundation of the Plateau Atmosphere and Environment Key Laboratory of Sichuan Province (Grant No. PAEKL-2017-Y6)
文摘Interannual variations of the Bay of Bengal summer monsoon (BOBSM) onset in association with El Ni-o-Southern Oscillation (ENSO) are reexamined using NCEP1, JRA-55 and ERA20C atmospheric and Hadley sea surface temperature (SST) reanalysis datasets over the period 1900-2017. Decadal changes exist in the dependence of the BOBSM onset on ENSO, varying with the Pacific Decadal Oscillation (PDO). A higher correlation between the BOBSM onset and ENSO arises during the warm PDO epochs, with distinct late (early) onsets following El Ni-o (La Ni-a) events. In contrast, less significant correlations occur during the cold PDO epochs. The mechanism for the PDO modulating the ENSO-BOBSM onset relationship is through the variations in SST anomaly (SSTA) patterns. During the warm PDO epochs, the superimpositions of the PDO-related and ENSO-related SSTAs lead to the SSTA distribution of an El Ni-o (La Ni-a) event exhibiting significant positive (negative) SSTAs over the tropical central-eastern Pacific and Indian Ocean along with negative (positive) SSTAs, especially over the tropical western Pacific (TWP), forming a strong zonal interoceanic SSTA gradient between the TWP and tropical Indian Ocean. Significant anomalous lower tropospheric easterlies (westerlies) together with upper-tropospheric westerlies (easterlies) are thus induced over the BOB, favoring an abnormally late (early) BOBSM onset. During the cold PDO epochs, however, the superimpositions of PDO-related SSTAs with El Ni-o-related (La Ni-a-related) SSTAs lead to insignificant SSTAs over the TWP and a weak zonal SSTA gradient, without distinct circulation anomalies over the BOB favoring early or late BOBSM onsets.
基金supported by the Beijing Natural Science Foundation (No.4192008)the General Project of Beijing Municipal Education Commission (No. KM201710005023)
文摘Online news recommendation systems aim to address the information explosion of news and make personalized recommendations for users. The key problem of personalized news recommendation is to model users' interests and track their changes. A common way to deal with the user modeling problem is to build user profiles from observed behavior. However, the majority of existing methods make static representations of user profiles and little research has focused on effective user modeling that could dynamically capture user interests in news topics. To address this problem, in this paper, we propose UP-TreeRec, a news recommendation framework based on a user profile tree(UP-Tree), which is a novel framework combining content-based and collaborative filtering techniques. First, by exploiting a novel topic model namely UILDA, we obtain the representation vectors for news content in a topic space as the fundamental bridge to associate user interests with news topics. Next, we design a decision tree with a dynamically changeable structure to construct a user interest profile from the user's feedback. Furthermore, we present a clustering-based multidimensional similarity computation method to select the nearest neighbor of the UP-Tree efficiently. We also provide a Map-Reduce framework-based implemen-tation that enables scaling our solution to real-world news recommendation problems. We conducted several experiments compared to the state-of-the-art approaches on real-world datasets and the experimental results demonstrate that our approach significantly improves accuracy and effectiveness in news recommendation.
基金supported by the National Key Research and Development Program on Monitoring,Early Warning and Prevention of Major Natural Disasters(2018YFC1506006)the National Natural Science Foundation of China Project(41805054,41875108,41805041,41705065)the Scientific Research Fund of the Chengdu University of Information Technology(KYTZ201724,KYTZ201602,KYTZ201727)
文摘A discrepancy remains in the first two leading empirical orthogonal function(EOF) modes of the tropical Pacific sea surface temperature anomaly(SSTA) based on observations since the 1980s. The EOF1 mode, representing the El Ni?o-Southern Oscillation(ENSO), is a robust result. However, the EOF2 features either El Ni?o Modoki(EM) or ENSO evolution during different periods, which is probably associated with the impacts of global warming. The underlying question is what the EOF2 mode of the tropical Pacific would be without global warming. Using the CMIP5 preindustrial scenario to exclude the influence of global warming, we find that the EOF1 mode of the tropical Pacific SSTA represents ENSO and that the EOF2 mode is not EM. According to the lead–lag correlation between the ENSO and EOF2 modes, the linkage between these two modes is as follows: …El Ni?o → EOF2 → La Ni?a →–EOF2 → El Ni?o…. By analyzing the evolution of sea surface temperature, surface wind, and subsurface ocean temperature anomalies, we find the mechanism linking the ENSO and EOF2 modes is the air–sea interaction associated with the ENSO cycle. This result suggests that the EOF2 mode represents an aspect of ENSO evolution under preindustrial conditions. Therefore, this study further indicates that the EM is probably due to the influence of global warming.
基金the National Key R&D Program of China(2016YFD0800106)the National Natural Science Foundation of China(31572210,31872403,71961137011)+5 种基金Key Research Program of Frontier Sciences-CAS(QYZDY-SSWSMC014)Key Laboratory of Agricultural Water Resources-CAS(ZD201802)the Key Research Program-CAS(KFJ-STS-ZDTP-053)Hebei Dairy Cattle Innovation Team of Modern Agroindustry Technology Research System,China(HBCT2018120206)the Youth Innovation Promotion Association,CAS(2019101)Outstanding Young Scientists Project of Natural Science Foundation of Hebei(C2019503054).
文摘Heterogenous distribution of crops,feed and livestock across China has halted the circulation of nutrients within the agricultural system and is responsible for massive nutrient losses[1,2].Generated livestock manure exceeded optimal crop requirements in 30%and 50%of over 2300 studied counties when there was improved recycling of nitrogen(N)and phosphorus(P)in the food chain,repectively[2].Most of these counties are located in southern and coastal areas,whereas there is a deficit of livestock manure in northern and western China.Such heterogenous distribution of crop-livestock production led to 4.0 Tg manure N and 0.9 Tg manure P[2],which are economically impossible to recycle and will end up in the surrounding environment.In addition,about 40%of feed protein consumed by domestic livestock production relied on importation,putting China’s livestock production supply at high risk in the post pandemic world[3].Hence,China is facing the twin issues of too many manure nutrients but too little feed nutrients simultaneously.
基金jointly supported by the Strategic Priority Re-search Program of the Chinese Academy of Sciences[grant number XDB40000000]the National Key Research and Development Program of China[grant number 2018YFC1506004]the National Natural Science Foundation of China[grant numbers 41730963 and 41876020].
基金supported jointly by the National Key Research and Development Program on Monitoring,Early Warning and Prevention of Major Natural Disaster(2018YFC1506006)the National Natural Science Foundation of China Project(41805054,41875108,41775072,41705065)the SOA International Cooperation Program on Global Change and Air-Sea Interactions(GASI-IPOVAI-03)
文摘The cold tongue mode(CTM),which represents the out-of-phase relationship in sea surface temperature anomaly(SSTA)variability between the Pacific cold tongue region and elsewhere in the tropical Pacific,shows a long-term cooling trend in the eastern equatorial Pacific.In this study,we investigate how well the CTM is reproduced in historical simulations generated by the 20 models considered in Phase 5 of the Coupled Model Intercomparison Project(CMIP5).Qualitatively,all 20 models roughly capture the cooling SSTA associated with the CTM.However,a quantitative assessment(i.e.,Taylor diagrams and the ratio of the trend between the simulations and observations)shows that only five of these 20 models(i.e.,CESM1-CAM5,CMCC-CM,FGOALS-g2,IPSL-CM5B-LR,and NorESM1-M)can reproduce with useful accuracy the spatial pattern and long-term trend of the CTM.We find that these five models generally simulate the main ocean dynamical process associated with the CTM.That is,these models adequately capture the long-term cooling trend in the vertical advection of the anomalous temperature by the mean upwelling.We conclude that the performance of these CMIP5 models,with respect to simulations of the long-term cooling trend associated with the vertical advection,and the related long-term decreasing trend of the vertical gradient of the oceanic temperature anomaly,can play an important role in successful reproduction of the CTM.
文摘A recent UN Sustainable Development Goals(SDGs) analysis indicated a significant regression in the global SDG goal scores, particularly in SDG 2—Zero Hunger. The emissions of environmental pollution caused by meeting food demands have prompted some countries to intensify their climate change mitigation efforts. These circumstances have introduced significant uncertainty to the future global sustainable food development. Additionally, a notable global challenge is the persistence of hidden hunger, primarily characterized by the insufficient consumption of high-quality animal protein. Addressing this issue would necessitate increased environmental costs to attain high-quality food security. The future food system presents a significant challenge in coordinating food security, food quality and environmental quality. This article presents a comprehensive review and proposes a three-step strategy for future agricultural development based on food security, quality, and environmental aspects. This is a novel food system transfer strategy, as it concurrently addresses both global food security and environmental thresholds. It involves the construction of an efficient food system that operates within the constraints of environmental limits. The objective is to align with global SDG indicators and to maintain natural resource consumption and pollutant emissions within planetary boundaries.
基金Supported by the National Key Research and Development Program of China(2017YFC1502306,2017YFC1502302,and 2018YFC-1506004)China Meteorological Administration Special Project for Developing Key Techniques for Operational Meteorological Forecast(YBGJXM201805)
文摘Multi-model ensemble prediction is an effective approach for improving the prediction skill short-term climate prediction and evaluating related uncertainties. Based on a combination of localized operation outputs of Chinese climate models and imported forecast data of some international operational models, the National Climate Center of the China Meteorological Administration has established the China multi-model ensemble prediction system version 1.0 (CMMEv1.0) for monthly-seasonal prediction of primary climate variability modes and climate elements. We verified the real-time forecasts of CMMEv1.0 for the 2018 flood season (June-August) starting from March 2018 and evaluated the 1991-2016 hindcasts of CMMEv1.0. The results show that CMMEv1.0 has a significantly high prediction skill for global sea surface temperature (SST) anomalies, especially for the El Nino-Southern Oscillation (ENSO) in the tropical central-eastern Pacific. Additionally, its prediction skill for the North Atlantic SST triple (NAST) mode is high, but is relatively low for the Indian Ocean Dipole (IOD) mode. Moreover, CMMEv1.0 has high skills in predicting the western Pacific subtropical high (WPSH) and East Asian summer monsoon (EASM) in the June-July-August (JJA) season. The JJA air temperature in the CMMEv1.0 is predicted with a fairly high skill in most regions of China, while the JJA precipitation exhibits some skills only in northwestern and eastern China. For real-time forecasts in March-August 2018, CMMEv1.0 has accurately predicted the ENSO phase transition from cold to neutral in the tropical central-eastern Pacific and captures evolutions of the NAST and IOD indices in general. The system has also captured the main features of the summer WPSH and EASM indices in 2018, except that the predicted EASM is slightly weaker than the observed. Furthermore, CMMEv1.0 has also successfully predicted warmer air temperatures in northern China and captured the primary rainbelt over northern China, except that it predicted much more precipitation in the middle and lower reaches of the Yangtze River than observation.
基金Project supported by the National Basic Research Program of China(2014CB643703)the National Key Research and Development Program of China(2016YFB0700901)the National Natural Science Foundation of China(51261004,51461012)
文摘With the intention to explore excellent magnetocaloric materials, the intermetallic compound GdPd was synthesized by arc melting and heat treatment. The microstructure, magnetic and magnetocaloric properties of the intermetallic compound of GdPd were investigated by X-ray diffraction(XRD), scanning electron microscopy(SEM) and the physical property measurement system(PPMS). A large reversible magnetocaloric effect is observed in GdPd accompanied by a second order magnetic phase transition from paramagnetism to ferromagnetism at ~39 K. The paramagnetic Curie temperature(θp) and the effective magnetic moment(μ(eff))are determined to be 34.7 K and 8.12 μB/Gd,respectively. The maximum entropy change(|△SM(Max)|) and the relative cooling power(RCP) under a field change of 5 T are estimated to be 20.14 J/(kg·K) and 433 J/kg, respectively. The giant reversible magnetocaloric effects(both the large△SM and the high RCP) together with the absence of thermal and field hysteresis make the GdPd compound an attractive candidate for low-temperature magnetic refrigeration.
文摘Dear Editor,Phospholipid molecules are unevenly distributed in membrane bilayers of eukaryotic cells.Phosphatidylethanolamine(PE)and phosphatidylserine(PS)are concentrated in the cytoplasmic leaflet,whereas phosphatidylcholine(PC)is enriched in the exoplasmic leaflet(lumenal or extracellular leaflet)(van Meer et al.2008).Type 4 P-type ATPases(P4-ATPases)are the phospholipid flippases which move specific lipids from the exoplasmic leaflet to the cytoplasmic leaflet.P4-ATPases belong to the P-type ATPase family.P4-ATPases are conserved in eukaryotes.
文摘Using a fixed point method, in this paper we discuss the existence and uniqueness of positive solutions to a class system of nonlinear fractional differential equations with delay and obtain some new results.