The role of the rare earth element Sm in as-cast Zn-5AI alloy was studied in this work.A three times higher improvement than the control group on corrosion resistance was found with rare earth Sm adding(0.15 wt%).By u...The role of the rare earth element Sm in as-cast Zn-5AI alloy was studied in this work.A three times higher improvement than the control group on corrosion resistance was found with rare earth Sm adding(0.15 wt%).By using an electron prove micro analyzer(EPMA),focused ion beam(FIB)and scanning Kelvin probe force microscopy(SKPFM)techniques,two main mechanisms of the premium performance of the Sm adding were revealed.One was that the non-uniform nucleation and component undercooling induced by Sm adding,reduced theα-AI layer spacing thus improved the covering efficiency of the Al_(2)O_(3)film.The other was that the dissolved Sm in the Zn/Al eutectic structure modulated the electron work function thus induced the attenuation of Volta potential discrepancy.The experimental results show that when the addition of Sm is 0.15 wt%,the minimum Volta potential difference betweenα-AI andη-Zn phases is achieved,and excessive or deficient Sm addition will increase the Volta potential difference.展开更多
Considering the influence of hydrogen gas generated during electrochemical machining on the conductivity of electrolyte, a two-phase turbulent flow model is presented to describe the gas bubbles distribution.The k-e t...Considering the influence of hydrogen gas generated during electrochemical machining on the conductivity of electrolyte, a two-phase turbulent flow model is presented to describe the gas bubbles distribution.The k-e turbulent model is used to describe the electrolyte flow field.The Euler–Euler model based on viscous drag and pressure force is used to calculate the twodimensional distribution of gas volume fraction.A multi-physics coupling model of electric field,two-phase flow field and temperature field is established and solved by weak coupling iteration method.The numerical simulation results of gas volume fraction, temperature and conductivity in equilibrium state are discussed.The distributions of machining gap at different time are analyzed.The predicted results of the machining gap are consistent with the experimental results, and the maximum deviation between them is less than 50 lm.展开更多
基金the National Natural Science Foundation of China(51974097,52161010)Central Government Guides Local Science and Technology Development Special Projects(20194011)+1 种基金the Program of"One Hundred Talented People"of Guizhou Province(20164014)Guizhou Province Science and Technology Project(20175656,20175788,20191414,20192162)。
文摘The role of the rare earth element Sm in as-cast Zn-5AI alloy was studied in this work.A three times higher improvement than the control group on corrosion resistance was found with rare earth Sm adding(0.15 wt%).By using an electron prove micro analyzer(EPMA),focused ion beam(FIB)and scanning Kelvin probe force microscopy(SKPFM)techniques,two main mechanisms of the premium performance of the Sm adding were revealed.One was that the non-uniform nucleation and component undercooling induced by Sm adding,reduced theα-AI layer spacing thus improved the covering efficiency of the Al_(2)O_(3)film.The other was that the dissolved Sm in the Zn/Al eutectic structure modulated the electron work function thus induced the attenuation of Volta potential discrepancy.The experimental results show that when the addition of Sm is 0.15 wt%,the minimum Volta potential difference betweenα-AI andη-Zn phases is achieved,and excessive or deficient Sm addition will increase the Volta potential difference.
基金funded by the National Natural Science Foundation of China(Nos.51775161 and 51775158)。
文摘Considering the influence of hydrogen gas generated during electrochemical machining on the conductivity of electrolyte, a two-phase turbulent flow model is presented to describe the gas bubbles distribution.The k-e turbulent model is used to describe the electrolyte flow field.The Euler–Euler model based on viscous drag and pressure force is used to calculate the twodimensional distribution of gas volume fraction.A multi-physics coupling model of electric field,two-phase flow field and temperature field is established and solved by weak coupling iteration method.The numerical simulation results of gas volume fraction, temperature and conductivity in equilibrium state are discussed.The distributions of machining gap at different time are analyzed.The predicted results of the machining gap are consistent with the experimental results, and the maximum deviation between them is less than 50 lm.
