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Industrial-Scale Polypropylene–Polyethylene Physical Alloying Toward Recycling 被引量:2
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作者 Jinping Qu Zhaoxia Huang +8 位作者 Zhitao Yang Guizhen Zhang xiaochun yin Yanhong Feng Hezhi He Gang Jin Ting Wu Guangjian He Xianwu Cao 《Engineering》 SCIE EI 2022年第2期95-100,共6页
Polypropylene(PP)and polyethylene(PE)play central roles in our daily life.However,their immiscibility presents a major hurdle in both industry and academia when recycling them into alloys with favorable mechanical pro... Polypropylene(PP)and polyethylene(PE)play central roles in our daily life.However,their immiscibility presents a major hurdle in both industry and academia when recycling them into alloys with favorable mechanical properties.Moreover,typical compatibilizer-enabled approaches are limited due to increased environmental concerns.Herein,inspired by a traditional Chinese technique,we report a facile,industry-scale methodology that produces a PP/PE binary blend with a highly ordered honeycomb nanostructure without any additives.Due to its nanostructure,the blend exhibits enhanced tensile properties in com-parison with the parent components or with a sample prepared using an internal mixer.This approach has potential for applications not only in immiscible polymer blending,but also in non-sorting,compatibilizer-free waste plastics recycling.Through this technique,we expect that an environmentally friendly and sustainable plastic wastes recycling avenue can be found,and great economic benefits can be gained. 展开更多
关键词 POLYPROPYLENE POLYETHYLENE Physical alloying Honeycomb structure
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超声波与可调正应力协同混合装置的研制及尼龙6/碳纤维复合材料制备 被引量:3
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作者 殷小春 汪棋 +1 位作者 何光建 冯彦洪 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2022年第8期147-153,161,共8页
提出一种超声波与可调正应力协同作用的新型混合方法及相应装置。通过调节该装置内定子和转子轴之间的偏心距(e_(2))可以调控物料受到的压缩/拉伸应力大小以适合不同的材料体系,同时改变偏心距(e_(2))还可调节熔体厚度以匹配超声波的有... 提出一种超声波与可调正应力协同作用的新型混合方法及相应装置。通过调节该装置内定子和转子轴之间的偏心距(e_(2))可以调控物料受到的压缩/拉伸应力大小以适合不同的材料体系,同时改变偏心距(e_(2))还可调节熔体厚度以匹配超声波的有效作用范围,实现了超声波与正应力协同的熔融混合。利用该装置制备了尼龙6(PA6)/碳纤维(CF)复合材料。扫描电镜和光学显微镜图像表明,在超声波和正应力的协同作用下CF(质量分数25%)均匀分散在基体中且纤维平均保留长度达到291μm;施加超声波后复合材料的拉伸强度和模量分别提高41.4%与30.4%;适当的超声作用使得复合材料电导率提升到8.76×10^(-3) S/m,且逾渗阈值下降超过5%。新设备为高性能聚合物基纤维增强复合材料的制备提供了新途径。 展开更多
关键词 超声波 可调正应力 尼龙6 碳纤维
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聚乳酸/聚丙烯两相体系的光辐照原位反应性增容 被引量:2
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作者 何光建 袁冰玉 +3 位作者 胡文梅 曹贤武 殷小春 朱文利 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2018年第2期105-110,115,共7页
改善聚合物共混物体系的界面相容性一般都采用添加增容剂的方式实现。文中提出在熔融挤出聚乳酸/聚丙烯共混物(PLA/PP)的过程中,通过光引发聚合物两相基体之间原位反应的方式来达到提高相容性的目的。在紫外光辐照作用下,加入的多官能... 改善聚合物共混物体系的界面相容性一般都采用添加增容剂的方式实现。文中提出在熔融挤出聚乳酸/聚丙烯共混物(PLA/PP)的过程中,通过光引发聚合物两相基体之间原位反应的方式来达到提高相容性的目的。在紫外光辐照作用下,加入的多官能团单体三羟甲基丙烷三甲基丙烯酸酯(TMPTA)与聚丙烯和聚乳酸共同反应,在两相界面间生成链接两相结构的接枝或嵌段共聚物作为相间增容剂。通过差示扫描量热仪、扫描电子显微镜、偏光显微镜和旋转流变仪对共混物的结晶性能、微观形貌和动态粘弹性进行了研究。结果表明,原位光辐照反应后的PLA/PP共混物相容性明显提高,分散相PP的粒子尺寸大大降低,PLA相最大结晶成核速率比纯PLA增加超过4倍,且PLA的晶粒细化。PLA与PP相界面发生反应后,产生了支化结构和链缠结,使得储能模量和复数黏度大大增加。 展开更多
关键词 聚乳酸 聚丙烯 光辐照 相容性
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The Effect of Surface Pit Treatment on Fretting Fatigue Crack Initiation
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作者 Qingming Deng xiaochun yin Magd Abdel Wahab 《Computers, Materials & Continua》 SCIE EI 2021年第1期659-673,共15页
This paper analyses the effect of surface treatment on fretting fatigue specimen by numerical simulations using Finite Element Analysis.The processed specimen refers to artificially adding a cylindrical pit to its con... This paper analyses the effect of surface treatment on fretting fatigue specimen by numerical simulations using Finite Element Analysis.The processed specimen refers to artificially adding a cylindrical pit to its contact surface.Then,the contact radius between the pad and the specimen is controlled by adjusting the radius of the pit.The stress distribution and slip amplitude of the contact surface under different contact geometries are compared.The critical plane approach is used to predict the crack initiation life and to evaluate the effect of processed specimen on its fretting fatigue performance.Both crack initiation life and angle can be predicted by the critical plane approach.Ruiz parameter is used to consider the effect of contact slip.It is shown that the crack initial position is dependent on the tensile stress.For same type of model,three kinds of critical plane parameters and Ruiz method provide very similar position of crack initiation.Moreover,the improved sample is much safer than the flat-specimen. 展开更多
关键词 Finite element analysis surface pit stress distribution fretting fatigue critical plane approach
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