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PAN-POSS接枝共聚物改性聚环氧乙烷/离子液体凝胶电解质的制备及性能 被引量:1
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作者 龚晓东 罗欢 +3 位作者 刘港 罗聪 牛艳华 李光宪 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2021年第8期138-144,153,共8页
采用自由基聚合法成功合成了聚丙烯腈与笼型倍半硅氧烷的接枝共聚物(PAN-POSS),并将其引入聚环氧乙烷(PEO)/1-乙基-3-甲基咪唑双三氟甲磺酰亚胺盐([EMIM][TFSI])/双三氟甲磺酰亚胺锂(LiTFSI)体系,通过溶剂挥发法制备具有自支撑性的凝胶... 采用自由基聚合法成功合成了聚丙烯腈与笼型倍半硅氧烷的接枝共聚物(PAN-POSS),并将其引入聚环氧乙烷(PEO)/1-乙基-3-甲基咪唑双三氟甲磺酰亚胺盐([EMIM][TFSI])/双三氟甲磺酰亚胺锂(LiTFSI)体系,通过溶剂挥发法制备具有自支撑性的凝胶电解质(GPEs)。采用差示扫描量热分析、热分析、拉伸测试和电化学性能测试等进行表征,研究了PAN-POSS含量对PEO基电解质结晶性能、力学性能、热稳定性和电化学性能的影响。结果表明,在PEO/[EMIM][TFSI]/LiTFSI凝胶电解质体系中,随PAN-POSS含量增加,PEO的结晶度逐渐降低,当质量分数为9%时,结晶度从初始的25.7%降至11.6%。此时,GPEs的室温离子电导率为2.87×10^(-4) S/cm,在0.1 C充电速率下,电池的容量达到130 mAh/g。PAN-POSS的添加提高了GPEs的热稳定性,热降解温度可达到380.6℃,力学性能略有下降,但是仍然达到3.3 MPa,具有良好的自支撑特性。 展开更多
关键词 聚环氧乙烷 聚丙烯腈 笼型倍半硅氧烷 接枝共聚物 凝胶聚合物电解质 离子电导率
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Analysis of Geographical Distribution of Missing Children Based on the Missing Children Mobile GIS Mutual Assistance System of China 被引量:1
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作者 xiaodong gong Hao Cheng +6 位作者 Lu Yang Yueming Duan Yuan Yao Yafei Feng Le Fu Jianhua Liu Mingyi Du 《Journal of Geoscience and Environment Protection》 2017年第12期117-134,共18页
The Missing Children Mobile GIS Mutual Assistance System of China (MCMAS) is a mobile service software based on mobile GIS platform software, and it is committed to providing the most convenient and efficient system o... The Missing Children Mobile GIS Mutual Assistance System of China (MCMAS) is a mobile service software based on mobile GIS platform software, and it is committed to providing the most convenient and efficient system of personally mutual tracing services for missing children family and society. Relying on collaborative utilization of location-based service technology, face image intelligent recognition technology, cloud computing technology, public big data sharing technology, and mobile GIS technology, the MCMAS has achieved prominent application effects since it was deployed. At present, the MCMAS is running soundly, and it has received and released the information about 1011 missing children from May 25, 2016 to May 25, 2017. In order to explore the geographical distribution features and the influencing factors of missing children, the data of missing children are used for spatial and visual analysis by the data mining and GIS technologies. At the same time, we have built the spatial thermodynamic diagram of the big data of China missing children. By comparing provinces and cities with a higher proportion of missing children, the results showed that: 1) The high proportion of missing children spatially concentrated in the eastern part of the China. 2) The number of missing children was significantly correlated with the population density and economic status of the city. Furthermore, the paper macro-levelly presents a basic basis for rescuing the missing children from two aspects: regionally spatial characteristics and influencing factors. 展开更多
关键词 MISSING CHILDREN Mobile GIS Location Based Service SPATIOTEMPORAL BIG Data Mining
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Modeling of the process-induced stress, damage, microstructure, and deformation evolution during the pyrolysis process manufacturing CMCs
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作者 Qiang Liu Suwan Ma +5 位作者 Zeshuai Yuan Yuan Li xiaodong gong Junping Li Man Zhu Tianjian Lu 《Journal of Advanced Ceramics》 SCIE EI CAS CSCD 2023年第12期2345-2359,共15页
An insightful understanding of the formation mechanism of process-inherent defects anddeformation is increasingly important for the property evaluation and structural design of ceramicmatrix composites (CMCs). For thi... An insightful understanding of the formation mechanism of process-inherent defects anddeformation is increasingly important for the property evaluation and structural design of ceramicmatrix composites (CMCs). For this purpose, a coupled thermal–diffusive–mechanical modelingapproach was proposed by considering three important phenomena that occur during the pyrolysisprocess for manufacturing CMCs: variations of the physical and mechanical properties of theconstituents, generation and diffusive of pyrolysis gas, and multiple thermal deformations. Thesynergistic effects of these three phenomena on the stress, damage development, microstructuralmorphology, and process deformation of SiC matrix composites were investigated using finiteelement simulations. This new approach was validated by comparing the simulation and experimentalresults. Significant volume shrinkage of the matrix during the polymer-to-ceramic transformationresulted in large tensile stresses and subsequent highly fragmented microstructure in CMCs. Thepyrolysis-gas-induced expansion on the matrix under a damage state may yield a positive processdeformation of CMCs at the macroscale, overcoming the effects of the volume shrinkage of the bulkmatrix at the microscale. The modeling approach is expected to guide high-quality manufacturing ofCMCs and comprehensive studies of structure–processing–property relationships. 展开更多
关键词 SiC pyrolysis gas process simulation DAMAGE process deformation
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