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多面体低聚倍半硅氧烷杂化丙烯酸树脂的制备及性能 被引量:1
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作者 陈雅 安秋凤 +2 位作者 李卫卫 王笑鸽 王玉峰 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2020年第9期46-53,共8页
采用二次聚合工艺将七异丁基甲基丙烯酰氧丙基POSS(T8^MA/7i-POSS)、八甲基丙烯酰氧丙基POSS(T8^MA-POSS)与甲基丙烯酸甲酯(MMA)进行自由基聚合反应,制备得到POSS/PMMA杂化材料。通过红外光谱、核磁共振氢谱、X射线衍射等手段对聚合物... 采用二次聚合工艺将七异丁基甲基丙烯酰氧丙基POSS(T8^MA/7i-POSS)、八甲基丙烯酰氧丙基POSS(T8^MA-POSS)与甲基丙烯酸甲酯(MMA)进行自由基聚合反应,制备得到POSS/PMMA杂化材料。通过红外光谱、核磁共振氢谱、X射线衍射等手段对聚合物的结构进行了表征,结果表明多面体低聚倍半硅氧烷(POSS)分子成功被引入聚合物链段中;通过原子力显微镜、扫描电镜对杂化材料形貌进行分析,结果表明POSS的引入增加了杂化材料表面粗糙度,出现明显凹凸结构;通过热重分析、差示扫描量热分析对杂化材料热性能进行分析,结果表明当T8^MA/7i-POSS添加量为20%、T8^MA-POSS添加量为5%时,PMMA的玻璃化转变温度从91.73℃提高到129.58℃,表现出良好的热性能。 展开更多
关键词 官能化多面体低聚倍半硅氧烷 杂化材料 改性 聚甲基丙烯酸甲酯 自由基聚合反应
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Blockchain data secure sharing protocol based on threshold Paillier algorithm
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作者 Likai Jia Xiubo Chen +3 位作者 Luxi Liu xiaoge wang Ke Xiao Gang Xu 《High-Confidence Computing》 EI 2023年第4期7-12,共6页
With the development of Internet technology,secure storage and secure sharing of data have become increasingly important.Traditional data sharing schemes exist a series of problems including lack of security and low e... With the development of Internet technology,secure storage and secure sharing of data have become increasingly important.Traditional data sharing schemes exist a series of problems including lack of security and low efficiency.In this paper,we construct a secure and efficient data sharing scheme based on threshold Paillier algorithm and blockchain technology,which achieves secure data storage and sharing without a third-party institution.Firstly,we propose a(t,l)threshold Paillier blockchain data sharing scheme,which effectively prevents decryption failures caused by the loss of a single node’s private key.Secondly,we propose a combined on-chain and off-chain data storage scheme,we store the ciphertext on the cloud server and the ciphertext hash value on the blockchain,which not only ensures the integrity of the data but also solves the storage limitation problem on the blockchain.Finally,we use the simulation paradigm to prove the security of the scheme in the semi-honest model.The discussion results of the comparison and the analysis of performance show that the blockchain data security sharing scheme proposed in this paper has lower computational overhead and higher security than other similar schemes. 展开更多
关键词 Blockchain Secure sharing data Privacy protection Threshold Paillier cryptosystem
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Borates as a new direction in the design of oxide ion conductors
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作者 Xiaohui Li Li Yang +10 位作者 Zhenyu Zhu xiaoge wang Pohua Chen Senchuan Huang Xianyi Wei Guohong Cai Pascal Manuel Sihai Yang Jianhua Lin Xiaojun Kuang Junliang Sun 《Science China Materials》 SCIE EI CAS CSCD 2022年第10期2737-2745,共9页
Lowering the operating temperature of solid oxide fuel cells(SOFCs)has extensively stimulated the development of new oxide ion conductors.Here,inspired by the structural commonalities of oxide ion conductors,the inabi... Lowering the operating temperature of solid oxide fuel cells(SOFCs)has extensively stimulated the development of new oxide ion conductors.Here,inspired by the structural commonalities of oxide ion conductors,the inability to accommodate oxygen vacancies in the rigid,isolated,3-fold tetrahedral rings of SrSi/GeO_(3)-based materials,and the considerable flexibility of BO_(n) polyhedra in terms of coordination number,rotation,deformation,and linkage,we report the first borate-base family of oxide ion conductors,(Gd/Y)_(1−x)Zn_(x)BO_(3−0.5x),through combined computational prediction and experimental verification.The oxygen vacancies in(Gd/Y)BO_(3)can be accommodated by forming B_(3)O_(8)units in isolated,3-fold,tetrahedral rings of B_(3)O_(9)and transported through a cooperative mechanism of oxygen exchange between the B_(3)O_(9)and B_(3)O_(8)units,which is assisted by the intermediate opening and extending of these units.This study opens a new scientific field of the borate system for designing and discovering oxide ion conductors. 展开更多
关键词 solid oxide fuel cells (Gd/Y)1−xZnxBO3−0.5x oxide ion migration mechanism borate oxide ion conductors ab initio molecular dynamics simulations
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Erratum to:Borates as a new direction in the design of oxide ion conductors(vol 65,issue 10,page 2737,2022)
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作者 Xiaohui Li Li Yang +10 位作者 Zhenyu Zhu xiaoge wang Bohua Chen Senchuan Huang Xianyi Wei Guohong Cai Pascal Manuel Sihai Yang Jianhua Lin Xiaojun Kuang Junliang Sun 《Science China Materials》 SCIE EI CAS CSCD 2022年第11期3186-3186,共1页
In the version of the article originally published in the volume 62,issue 10,2022 of Sci.china Mater.(page 2737-2745,https://doi.org/10.1007/s40843-022-2044-3).The chemical shift reported in Figure 5f for the^(11)B so... In the version of the article originally published in the volume 62,issue 10,2022 of Sci.china Mater.(page 2737-2745,https://doi.org/10.1007/s40843-022-2044-3).The chemical shift reported in Figure 5f for the^(11)B solid-state NMR spectra is incorrect because no parameter correction was performed during data processing. 展开更多
关键词 FIGURE CORRECTION processing.
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