In the present paper,a microwave absorber with nanoscale gradient structure was proposed for enhancing the electromagnetic absorption performance.The inorganic-organic competitive coating strategy was employed,which c...In the present paper,a microwave absorber with nanoscale gradient structure was proposed for enhancing the electromagnetic absorption performance.The inorganic-organic competitive coating strategy was employed,which can effectively adjust the thermodynamic and kinetic reactions of iron ions during the solvothermal process.As a result,Fe nanoparticles can be gradually decreased from the inner side to the surface across the hollow carbon shell.The results reveal that it offers an outstanding reflection loss value in combination with broadband wave absorption and flexible adjustment ability,which is superior to other relative graded distribution structures and satisfied with the requirements of lightweight equipment.In addition,this work elucidates the intrinsic microwave regulation mechanism of the multiscale hybrid electromagnetic wave absorber.The excellent impedance matching and moderate dielectric parameters are exhibited to be the dominative factors for the promotion of microwave absorption performance of the optimized materials.This strategy to prepare gradient-distributed microwave absorbing materials initiates a new way for designing and fabricating wave absorber with excellent impedance matching property in practical applications.展开更多
Heterogenous distribution of crops,feed and livestock across China has halted the circulation of nutrients within the agricultural system and is responsible for massive nutrient losses[1,2].Generated livestock manure ...Heterogenous distribution of crops,feed and livestock across China has halted the circulation of nutrients within the agricultural system and is responsible for massive nutrient losses[1,2].Generated livestock manure exceeded optimal crop requirements in 30%and 50%of over 2300 studied counties when there was improved recycling of nitrogen(N)and phosphorus(P)in the food chain,repectively[2].Most of these counties are located in southern and coastal areas,whereas there is a deficit of livestock manure in northern and western China.Such heterogenous distribution of crop-livestock production led to 4.0 Tg manure N and 0.9 Tg manure P[2],which are economically impossible to recycle and will end up in the surrounding environment.In addition,about 40%of feed protein consumed by domestic livestock production relied on importation,putting China’s livestock production supply at high risk in the post pandemic world[3].Hence,China is facing the twin issues of too many manure nutrients but too little feed nutrients simultaneously.展开更多
Due to the rapid development of mobile Internet services, such as Skype and WeChat, traditional telecom services have suffered a large decline in the business volumes in recent years. Thus, telecom operators pay much ...Due to the rapid development of mobile Internet services, such as Skype and WeChat, traditional telecom services have suffered a large decline in the business volumes in recent years. Thus, telecom operators pay much attention to analyzing the changes of the enterprise performance, in order to adjust market strategies in time. In this paper, we propose a new methodology to analyze the operation data of telecom operators dynamically,which can characterize the changing process of the operating states and predict the developing trends. In particular, the proposed methodology contains two steps: migration pattern analysis and trajectory pattern analysis.Firstly, migration analysis is based on the changing of operating states between two points-in-time, which is referred to as the migration paths. Applying the clustering analysis to the migration paths can obtain the migration patterns, which characterize the changing feature of telecom operators during a short period, e.g. one month. Secondly, we combine a sequence of consecutive migration paths to obtain the migration trajectory. Through analyzing different trajectories based on the hierarchical cluster method and the Markov chain model, we obtain the trajectory patterns,which describe the changing progress during a relatively long period, e.g. one year. Based on the trajectory patterns, we can predict the possible performance changes. Finally, we apply the proposed method to a Chinese telecom operator for an empirical research, and has obtained a lot of development rules which provides insights into current telecom.展开更多
This paper firstly introduced policy of photovoltaic agriculture in China. It discussed significance of developing photovoltaic agriculture. Then,it introduced progress in application of photovoltaic agriculture at bo...This paper firstly introduced policy of photovoltaic agriculture in China. It discussed significance of developing photovoltaic agriculture. Then,it introduced progress in application of photovoltaic agriculture at both home and abroad. Finally,it pointed out existing problems in photovoltaic agriculture and came up with recommendations for development of photovoltaic agriculture in China.展开更多
Machine learning has emerged as a powerful tool for the analysis of mesoscopic and atomically resolved images and spectroscopy in electron and scanning probe microscopy,with the applications ranging from feature extra...Machine learning has emerged as a powerful tool for the analysis of mesoscopic and atomically resolved images and spectroscopy in electron and scanning probe microscopy,with the applications ranging from feature extraction to information compression and elucidation of relevant order parameters to inversion of imaging data to reconstruct structural models.However,the fundamental limitation of machine learning methods is their correlative nature,leading to extreme susceptibility to confounding factors.Here,we implement the workflow for causal analysis of structural scanning transmission electron microscopy(STEM)data and explore the interplay between physical and chemical effects in a ferroelectric perovskite across the ferroelectric–antiferroelectric phase transitions.展开更多
Over the last decade,scanning transmission electron microscopy(STEM)has emerged as a powerful tool for probing atomic structures of complex materials with picometer precision,opening the pathway toward exploring ferro...Over the last decade,scanning transmission electron microscopy(STEM)has emerged as a powerful tool for probing atomic structures of complex materials with picometer precision,opening the pathway toward exploring ferroelectric,ferroelastic,and chemical phenomena on the atomic scale.Analyses to date extracting a polarization signal from lattice coupled distortions in STEM imaging rely on discovery of atomic positions from intensity maxima/minima and subsequent calculation of polarization and other order parameter fields from the atomic displacements.Here,we explore the feasibility of polarization mapping directly from the analysis of STEM images using deep convolutional neural networks(DCNNs).In this approach,the DCNN is trained on the labeled part of the image(i.e.,for human labelling),and the trained network is subsequently applied to other images.We explore the effects of the choice of the descriptors(centered on atomic columns and grid-based),the effects of observational bias,and whether the network trained on one composition can be applied to a different one.This analysis demonstrates the tremendous potential of the DCNN for the analysis of high-resolution STEM imaging and spectral data and highlights the associated limitations.展开更多
Chemical vapor deposition(CVD)is one of the most versatile techniques for the controlled synthesis of functional nanomaterials.When multiple precursors are induced,the CVD process often gives rise to the growth of dop...Chemical vapor deposition(CVD)is one of the most versatile techniques for the controlled synthesis of functional nanomaterials.When multiple precursors are induced,the CVD process often gives rise to the growth of doped or alloy compounds.In this work,we demonstrate the self-assembly of a variety of‘phase-separated’functional nanostructures from a single CVD in the presence of various precursors.In specific,with silicon substrate and powder of Mn and SnTe as precursors,we achieved self-organized nanostructures including Si/SiOx core-shell nanowire heterostructures both with and without embedded manganese silicide particles,Mn11Si19 nanowires,and SnTe nanoplates.The Si/SiOx core-shell nanowires embedded with manganese silicide particles were grown along the<111>direction of the crystalline Si via an Au-catalyzed vapor-liquid-solid process,in which the Si and Mn vapors were supplied from the heated silicon substrates and Mn powder,respectively.In contrast,direct vapor-solid deposition led to particle-free<110>-oriented Si/SiOx core-shell nanowires and<100>-oriented Mn11Si19 nanowires,a promising thermoelectric material.No Sn or Te impurities were detected in these nanostructures down to the experimental limit.Topological crystalline insulator SnTe nanoplates with dominant{100}and{111}facets were found to be free of Mn(and Si)impurities,although nanoparticles and nanowires containing Mn were found in the vicinity of the nanoplates.While multiple-channel transport was observed in the SnTe nanoplates,it may not be related to the topological surface states due to surface oxidation.Finally,we carried out thermodynamic analysis and density functional theory calculations to understand the‘phase-separation’phenomenon and further discuss general approaches to grow phase-pure samples when the precursors contain residual impurities.展开更多
With the benefits of low latency,wide transmission bandwidth,and large mode field area,hollow-core antiresonant fiber(HC-ARF)has been a research hotspot in the past decade.In this paper,a hollow core step-index antire...With the benefits of low latency,wide transmission bandwidth,and large mode field area,hollow-core antiresonant fiber(HC-ARF)has been a research hotspot in the past decade.In this paper,a hollow core step-index antiresonant fiber(HC-SARF),with stepped refractive indices cladding,is proposed and numerically demonstrated with the benefits of loss reduction and bending improvement.Glass-based capil-laries with both high(n=1.45)and low(as low as n=1.36)refractive indices layers are introduced and formatted in the cladding air holes.Using the finite element method to perform numerical analysis of the designed fiber,results show that at the laser wavelengths of 980 and 1064 nm,the confinement loss is favorably reduced by about 6 dB/km compared with the conventional uniform cladding HC-ARF.The bending loss,around 15 cm bending radius of this fiber,is also reduced by 2 dB/km.The cladding air hole radius in this fiber is further investigated to optimize the confinement loss and the mode field diameter with single-mode transmission behavior.This proposed HC-SARF has great potential in optical fiber transmission and high energy delivery.展开更多
基金the National Natural Science Foundation of China(52102372,52162007,52163032)China Postdoctoral Science Foundation(2022M712321)the Jiangsu Province Postdoctoral Research Funding Program(2021K473C).
文摘In the present paper,a microwave absorber with nanoscale gradient structure was proposed for enhancing the electromagnetic absorption performance.The inorganic-organic competitive coating strategy was employed,which can effectively adjust the thermodynamic and kinetic reactions of iron ions during the solvothermal process.As a result,Fe nanoparticles can be gradually decreased from the inner side to the surface across the hollow carbon shell.The results reveal that it offers an outstanding reflection loss value in combination with broadband wave absorption and flexible adjustment ability,which is superior to other relative graded distribution structures and satisfied with the requirements of lightweight equipment.In addition,this work elucidates the intrinsic microwave regulation mechanism of the multiscale hybrid electromagnetic wave absorber.The excellent impedance matching and moderate dielectric parameters are exhibited to be the dominative factors for the promotion of microwave absorption performance of the optimized materials.This strategy to prepare gradient-distributed microwave absorbing materials initiates a new way for designing and fabricating wave absorber with excellent impedance matching property in practical applications.
基金the National Key R&D Program of China(2016YFD0800106)the National Natural Science Foundation of China(31572210,31872403,71961137011)+5 种基金Key Research Program of Frontier Sciences-CAS(QYZDY-SSWSMC014)Key Laboratory of Agricultural Water Resources-CAS(ZD201802)the Key Research Program-CAS(KFJ-STS-ZDTP-053)Hebei Dairy Cattle Innovation Team of Modern Agroindustry Technology Research System,China(HBCT2018120206)the Youth Innovation Promotion Association,CAS(2019101)Outstanding Young Scientists Project of Natural Science Foundation of Hebei(C2019503054).
文摘Heterogenous distribution of crops,feed and livestock across China has halted the circulation of nutrients within the agricultural system and is responsible for massive nutrient losses[1,2].Generated livestock manure exceeded optimal crop requirements in 30%and 50%of over 2300 studied counties when there was improved recycling of nitrogen(N)and phosphorus(P)in the food chain,repectively[2].Most of these counties are located in southern and coastal areas,whereas there is a deficit of livestock manure in northern and western China.Such heterogenous distribution of crop-livestock production led to 4.0 Tg manure N and 0.9 Tg manure P[2],which are economically impossible to recycle and will end up in the surrounding environment.In addition,about 40%of feed protein consumed by domestic livestock production relied on importation,putting China’s livestock production supply at high risk in the post pandemic world[3].Hence,China is facing the twin issues of too many manure nutrients but too little feed nutrients simultaneously.
基金partially supported by NSFC (71371034 and 71372194)Beijing Natural Science Foundation (9162011)
文摘Due to the rapid development of mobile Internet services, such as Skype and WeChat, traditional telecom services have suffered a large decline in the business volumes in recent years. Thus, telecom operators pay much attention to analyzing the changes of the enterprise performance, in order to adjust market strategies in time. In this paper, we propose a new methodology to analyze the operation data of telecom operators dynamically,which can characterize the changing process of the operating states and predict the developing trends. In particular, the proposed methodology contains two steps: migration pattern analysis and trajectory pattern analysis.Firstly, migration analysis is based on the changing of operating states between two points-in-time, which is referred to as the migration paths. Applying the clustering analysis to the migration paths can obtain the migration patterns, which characterize the changing feature of telecom operators during a short period, e.g. one month. Secondly, we combine a sequence of consecutive migration paths to obtain the migration trajectory. Through analyzing different trajectories based on the hierarchical cluster method and the Markov chain model, we obtain the trajectory patterns,which describe the changing progress during a relatively long period, e.g. one year. Based on the trajectory patterns, we can predict the possible performance changes. Finally, we apply the proposed method to a Chinese telecom operator for an empirical research, and has obtained a lot of development rules which provides insights into current telecom.
基金Supported by Scientific and Technological Planning Project of Xiamen City(2014S0344)
文摘This paper firstly introduced policy of photovoltaic agriculture in China. It discussed significance of developing photovoltaic agriculture. Then,it introduced progress in application of photovoltaic agriculture at both home and abroad. Finally,it pointed out existing problems in photovoltaic agriculture and came up with recommendations for development of photovoltaic agriculture in China.
基金The work at the University of Maryland was supported in part by the National Institute of Standards and Technology Cooperative Agreement 70NANB17H301the Center for Spintronic Materials in Advanced infoRmation Technologies(SMART)one of centers in nCORE,a Semiconductor Research Corporation(SRC)program sponsored by NSF and NISTA.N.M.work was partially supported by the European Union’s Horizon 2020 research and innovation program under the Marie Skłodowska-Curie(grant agreement No 778070).
文摘Machine learning has emerged as a powerful tool for the analysis of mesoscopic and atomically resolved images and spectroscopy in electron and scanning probe microscopy,with the applications ranging from feature extraction to information compression and elucidation of relevant order parameters to inversion of imaging data to reconstruct structural models.However,the fundamental limitation of machine learning methods is their correlative nature,leading to extreme susceptibility to confounding factors.Here,we implement the workflow for causal analysis of structural scanning transmission electron microscopy(STEM)data and explore the interplay between physical and chemical effects in a ferroelectric perovskite across the ferroelectric–antiferroelectric phase transitions.
基金This STEM effort is based upon work supported by the U.S.Department of Energy(DOE),Office of Science,Basic Energy Sciences(BES),Materials Sciences and Engineering Division(S.V.K.,C.T.N.).This ML effort is based upon work supported by the U.S.DOE,Office of Science,Office of Basic Energy Sciences Data,Artificial Intelligence and Machine Learning at DOE Scientific User Facilities(A.G.).The work was performed and partially supported(M.Z.)at Oak Ridge National Laboratory’s Center for Nanophase Materials Sciences(CNMS),a U.S.DOE,Office of Science User Facility.The work at the University of Maryland was supported in part by the National Institute of Standards and Technology Cooperative Agreement 70NANB17H301 and the Center for Spintronic Materials in Advanced Information Technologies(SMART)one of the centers in nCORE,a Semiconductor Research Corporation(SRC)program sponsored by NSF and NIST.The authors gratefully acknowledge Dr.Karren More(CNMS)for careful reading and editing the manuscript.
文摘Over the last decade,scanning transmission electron microscopy(STEM)has emerged as a powerful tool for probing atomic structures of complex materials with picometer precision,opening the pathway toward exploring ferroelectric,ferroelastic,and chemical phenomena on the atomic scale.Analyses to date extracting a polarization signal from lattice coupled distortions in STEM imaging rely on discovery of atomic positions from intensity maxima/minima and subsequent calculation of polarization and other order parameter fields from the atomic displacements.Here,we explore the feasibility of polarization mapping directly from the analysis of STEM images using deep convolutional neural networks(DCNNs).In this approach,the DCNN is trained on the labeled part of the image(i.e.,for human labelling),and the trained network is subsequently applied to other images.We explore the effects of the choice of the descriptors(centered on atomic columns and grid-based),the effects of observational bias,and whether the network trained on one composition can be applied to a different one.This analysis demonstrates the tremendous potential of the DCNN for the analysis of high-resolution STEM imaging and spectral data and highlights the associated limitations.
基金This work was supported,in part,by the Indiana University Vice Provost for Research through the Faculty Research Support Program,National Science Foundation Research Experience for Undergraduates grant PHY-1757646,NSF-DMR-1350002We thank the Indiana University-Bloomington Nanoscale Characterization Facility(NCF)for the use of instruments(The XPS instrument at NCF was funded through grant NSF-DMR-1126394).
文摘Chemical vapor deposition(CVD)is one of the most versatile techniques for the controlled synthesis of functional nanomaterials.When multiple precursors are induced,the CVD process often gives rise to the growth of doped or alloy compounds.In this work,we demonstrate the self-assembly of a variety of‘phase-separated’functional nanostructures from a single CVD in the presence of various precursors.In specific,with silicon substrate and powder of Mn and SnTe as precursors,we achieved self-organized nanostructures including Si/SiOx core-shell nanowire heterostructures both with and without embedded manganese silicide particles,Mn11Si19 nanowires,and SnTe nanoplates.The Si/SiOx core-shell nanowires embedded with manganese silicide particles were grown along the<111>direction of the crystalline Si via an Au-catalyzed vapor-liquid-solid process,in which the Si and Mn vapors were supplied from the heated silicon substrates and Mn powder,respectively.In contrast,direct vapor-solid deposition led to particle-free<110>-oriented Si/SiOx core-shell nanowires and<100>-oriented Mn11Si19 nanowires,a promising thermoelectric material.No Sn or Te impurities were detected in these nanostructures down to the experimental limit.Topological crystalline insulator SnTe nanoplates with dominant{100}and{111}facets were found to be free of Mn(and Si)impurities,although nanoparticles and nanowires containing Mn were found in the vicinity of the nanoplates.While multiple-channel transport was observed in the SnTe nanoplates,it may not be related to the topological surface states due to surface oxidation.Finally,we carried out thermodynamic analysis and density functional theory calculations to understand the‘phase-separation’phenomenon and further discuss general approaches to grow phase-pure samples when the precursors contain residual impurities.
基金the National Natural Science Foundation of China(Grant No.62075074)the National Key R&D Program of China(Nos.2018YFF01011800 and 2018YFB2201901).
文摘With the benefits of low latency,wide transmission bandwidth,and large mode field area,hollow-core antiresonant fiber(HC-ARF)has been a research hotspot in the past decade.In this paper,a hollow core step-index antiresonant fiber(HC-SARF),with stepped refractive indices cladding,is proposed and numerically demonstrated with the benefits of loss reduction and bending improvement.Glass-based capil-laries with both high(n=1.45)and low(as low as n=1.36)refractive indices layers are introduced and formatted in the cladding air holes.Using the finite element method to perform numerical analysis of the designed fiber,results show that at the laser wavelengths of 980 and 1064 nm,the confinement loss is favorably reduced by about 6 dB/km compared with the conventional uniform cladding HC-ARF.The bending loss,around 15 cm bending radius of this fiber,is also reduced by 2 dB/km.The cladding air hole radius in this fiber is further investigated to optimize the confinement loss and the mode field diameter with single-mode transmission behavior.This proposed HC-SARF has great potential in optical fiber transmission and high energy delivery.