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Enhanced Potassium‑Ion Storage of the 3D Carbon Superstructure by Manipulating the Nitrogen‑Doped Species and Morphology 被引量:7
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作者 Yanhua Li Kui Xiao +7 位作者 Cong Huang Jin Wang Ming Gao Aiping Hu Qunli Tang Binbin Fan Yali Xu xiaohua chen 《Nano-Micro Letters》 SCIE EI CAS CSCD 2021年第1期1-14,共14页
Potassium-ion batteries(PIBs)are attractive for gridscale energy storage due to the abundant potassium resource and high energy density.The key to achieving high-performance and large-scale energy storage technology l... Potassium-ion batteries(PIBs)are attractive for gridscale energy storage due to the abundant potassium resource and high energy density.The key to achieving high-performance and large-scale energy storage technology lies in seeking eco-efficient synthetic processes to the design of suitable anode materials.Herein,a spherical sponge-like carbon superstructure(NCS)assembled by 2D nanosheets is rationally and efficiently designed for K+storage.The optimized NCS electrode exhibits an outstanding rate capability,high reversible specific capacity(250 mAh g^(−1) at 200 mA g^(−1) after 300 cycles),and promising cycling performance(205 mAh g^(−1) at 1000 mA g^(−1) after 2000 cycles).The superior performance can be attributed to the unique robust spherical structure and 3D electrical transfer network together with nitrogen-rich nanosheets.Moreover,the regulation of the nitrogen doping types and morphology of NCS-5 is also discussed in detail based on the experiments results and density functional theory calculations.This strategy for manipulating the structure and properties of 3D materials is expected to meet the grand challenges for advanced carbon materials as high-performance PIB anodes in practical applications. 展开更多
关键词 POLYIMIDE NITROGEN-DOPED Potassium-ion battery 3D carbon material
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Oxygen-Containing Functional Groups Regulating the Carbon/Electrolyte Interfacial Properties Toward Enhanced K^(+)Storage 被引量:1
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作者 Yufan Peng Zhen chen +7 位作者 Rui Zhang Wang Zhou Peng Gao Jianfang Wu Hui Liu Jilei Liu Aiping Hu xiaohua chen 《Nano-Micro Letters》 SCIE EI CAS CSCD 2021年第12期29-43,共15页
Oxygen-containing functional groups were found to e ectively boost the K^(+)storage performance of carbonaceous materials,however,the mechanism behind the performance enhancement remains unclear.Herein,we report highe... Oxygen-containing functional groups were found to e ectively boost the K^(+)storage performance of carbonaceous materials,however,the mechanism behind the performance enhancement remains unclear.Herein,we report higher rate capability and better long-term cycle performance employing oxygen-doped graphite oxide(GO)as the anode material for potassium ion batteries(PIBs),compared to the raw graphite.The in situ Raman spectroscopy elucidates the adsorption-intercalation hybrid K^(+)storage mechanism,assigning the capacity enhancement to be mainly correlated with reversible K^(+)adsorption/desorption at the newly introduced oxygen sites.It is unraveled that the C=O and COOH rather than C-O-C and OH groups contribute to the capacity enhancement.Based on in situ Fourier transform infrared(FT-IR)spectra and in situ electrochemical impedance spectroscopy(EIS),it is found that the oxygen-containing functional groups regulate the components of solid electrolyte interphase(SEI),leading to the formation of highly conductive,intact and robust SEI.Through the systematic investigations,we hereby uncover the K^(+)storage mechanism of GO-based PIB,and establish a clear relationship between the types/contents of oxygen functional groups and the regulated composition of SEI. 展开更多
关键词 Oxygen-containing functional groups Solid electrolyte interphase In situ spectroscopic characterization Potassium ion batteries
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腮腺多形性腺瘤与腺淋巴瘤的CT影像特征及对比分析 被引量:5
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作者 郭作梁 陈晓华 +1 位作者 马兴灿 马树华 《心电图杂志(电子版)》 2019年第1期22-23,共2页
目的探究腮腺多形性腺瘤与腺淋巴瘤的CT影像特征及对比分析。方法选取我院2015年9月-2018年8月收治治疗的腮腺多形腺瘤和腺淋巴瘤患者各20例作为研究对象,其中腮腺淋巴瘤共25个病灶,腮腺多形性腮腺瘤共21个病灶,所有患者都完成了CT平扫... 目的探究腮腺多形性腺瘤与腺淋巴瘤的CT影像特征及对比分析。方法选取我院2015年9月-2018年8月收治治疗的腮腺多形腺瘤和腺淋巴瘤患者各20例作为研究对象,其中腮腺淋巴瘤共25个病灶,腮腺多形性腮腺瘤共21个病灶,所有患者都完成了CT平扫以及增强扫描。分析比较患者的CT影像资料及病理。结果腮腺多形性腺瘤与腺淋巴瘤的生长轴线、发病部位、平扫及增强扫描CT值、肿瘤内低密度、肿瘤内或附近血管影等均存在统计学差异(P<0.05);在肿瘤大小、形态、左右叶分布方面等差异并不明显(P>0.05)。结论在通过CT影像扫描后可有效鉴别腮腺多形性腺瘤以及腺淋巴瘤,可清楚显示腮腺多形性腺瘤与腺淋巴瘤的部位、数目、周围结构及形态情况。 展开更多
关键词 腮腺 多形性腺瘤 腺淋巴瘤 CT影像 分析
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Preparation and Crystallization of Carbon Nanotube/maleic Anhydride-grafted Polypropylene Composites
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作者 xiaohua chen Jing HU +3 位作者 Lingping ZHOU Wenhua LI Zi YANG Yanguo WANG 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2008年第2期279-284,共6页
Carbon nanotube (CNT)/maleic acid anhydride (MAH)-grafted polypropylene (PP) composites were prepared by in situ grafting method. Infrared spectroscopy showed that the CNTs were linked to PP by MAH grafting. The... Carbon nanotube (CNT)/maleic acid anhydride (MAH)-grafted polypropylene (PP) composites were prepared by in situ grafting method. Infrared spectroscopy showed that the CNTs were linked to PP by MAH grafting. The microstructures and calorimetry analysis indicated that the crystallization behaviors of the filled and unfilled PP were quite different. The addition of CNTs dramatically reduced the spherulite size, increased crystallization rate and improved the thermal stability of PP. These results confirmed the expected nucleant effect of CNT on the crystallization of PP. Scanning and transmission electron microscopy showed that the CNTs were dispersed homogeneously, indicating that the original CNT bundles were separated into individual tubes by the grafting. 展开更多
关键词 Carbon nanotubes Chemical treatment RESINS Crystallite size
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Diameters and form of skull base foramen ovale measured by three-dimensional spiral CT thin-slice scan in healthy adults
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作者 xiaohua chen Fengxian Deng +1 位作者 Shuhang Wei Tingsong Fang 《Neural Regeneration Research》 SCIE CAS CSCD 2006年第4期343-346,共4页
BACKGROUND: The accurate measurements of various data of the bone diameters of foramen ovale of living person can change the methods of puncturing trigeminal gasserian ganglion via foramen ovale for treating trifacia... BACKGROUND: The accurate measurements of various data of the bone diameters of foramen ovale of living person can change the methods of puncturing trigeminal gasserian ganglion via foramen ovale for treating trifacial neuralgia from the experience of puncture operator only to puncture by taking the objective data of measurement as the evidence, which is good for improving the accuracy of puncturing trigeminal ganglion and reducing side effects. OBJECTIVE : To observe the forms of foramen ovales in healthy adults displayed by volume rendering and multi-planar reconstruction after three-dimensional spiral CT thin-slice scan of skull base, and measure the longitudinal diameter and transverse diameter. DESIGN : A repetitive observation and measurement SETTINGS : Department of Neurosurgery and Department of Medical Imaging, Foshan Hospital of Traditional Chinese Medicine. PARTICIPANTS: Fifty healthy adults (100 sides), who were examined with three-dimensional spiral CT scan, were randomly selected from the Department of Medical Imaging, Foshan Hospital of Traditional Chinese Medicine from January 2005 to January 2006, including 26 males and 24 females, aged 25-68 years with an average of 48 years old. They were all informed and agreed with the examination. METHODS : The subjects were examined with the Philips 16-slice spiral CT-Mx 8000 IDT CT apparatus (Philips Company, Holland), the scanning ranged from 2 cm below the canthomeatal line to the level of suprasellar cistem. The width of collimator was 0.75 mm, pitch was 0.663; tube current was 350 mA, voltage was 120 kV, resolution was 512×512 matrix; slice thickness of reconstruction was 1 mm, and interval was 0.5 mm. After the three-dimensional spiral CT thin-slice scan of skull base, the image post-processing techniques including volume rendering and multi-planar reconstruction were applied to observe the forms of foramen ovales, and measure the size, longitudinal diameter and transverse diameter of the foramen ovales. The figures of the foramen ovales were drawn with mouse along the boundary of bone porous margin and soft tissue. According to the indications, the diameters were measured with computer to observe the forms of foramen ovales. MAIN OUTCOME MEASURES : The longitudinal diameter, transverse diameter and form of foramen ovales were observed. RESULTS: All the 50 healthy adults (100 sides) were involved in the analysis of results. (1) It was observed in the volume rendering images that foramen ovales had four forms of oval shape (77 sides), kidney shape (12 sides), round shape (7 sides), ribbon shape (4 sides). (2) The longitudinal diameters of left and right foramen ovales were (7.67±1.32) and (7.98±1.45) mm, and the transverse diameters were (4.04±0.83), (4.09±1.07) mm; There was no obvious difference between left and right longitudinal diameters (t = 1.63, P = 0.11 ), and left and right transverse diameters were close (t = 0.45, P= 0.65). CONCLUSION : The non-invasive techniques of volume rendering and multi-planar reconstruction after three-dimensional spiral CT thin-slice scan can clearly display the formand size of foramen ovale in healthy adults. 展开更多
关键词 Diameters and form of skull base foramen ovale measured by three-dimensional spiral CT thin-slice scan in healthy adults CT base
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Simulating Error-Opening of Pressure Relief Valves of a Station on a Continuous Undulating Oil Pipeline with Large Elevation Difference
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作者 xiaohua chen Caifu Lan +3 位作者 Honghao Zheng Wang Li Chao Zhao Wenjun Dang 《Energy Engineering》 EI 2022年第4期1439-1452,共14页
For oil pipeline in mountain areas,high hydrostatic pressure in the pipeline may cause error-opening of pressure relief valves,and oil is discharged from the pipeline to the pressure relief tanks,bringing spilling-ove... For oil pipeline in mountain areas,high hydrostatic pressure in the pipeline may cause error-opening of pressure relief valves,and oil is discharged from the pipeline to the pressure relief tanks,bringing spilling-over risk of the pressure relief tanks.Therefore,simulating the error-opening situations of the pressure relief valves and investigating the oil discharge process are necessary for checking the possibility of the spilling-over accident and then proposing measures to improve the pressure relief system.This research focuses on a continuous undulating oil pipeline with large elevation difference and a station along this pipeline,which is named B station in this paper,is studied.By OLGA software,simulation model of the pressure relief system of B station is established,and the accuracy of the model is verified by reconstructing a real accident and making a comparison with the actual accident data.The maximum discharge rate reached 8284 m3/h when the pressure relief valve was opened by mistake in the inlet and outlet of the station.The accumulated filling time of the two pressure relief tanks is 200 s,which is in good agreement with the accident data.On this basis,for error-opening of the pressure relief valves at the inlet and outlet of B station,simulation is performed to investigate variations of the discharge velocity,discharge flow rate,accumulated discharge volume and ventilation volume of the vent valve.The discharge velocity is found to be over the maximum velocity allowed for safety consideration.According to the accumulated discharge volume,it is inferred that spilling over of the pressure relief tanks will be caused once error-opening of the pressure relief valve occurs.Also it is judged that the existing breathing valve can not satisfy the ventilation requirement in case of failure of the pressure relief valves.From these simulation results,it is proposed that increasing the number of vent valves,replacing the manual valves with electrically operated valves,and employing security control interlock protection program are improvement measures to guarantee safe,efficient and reliable operation of the pressure relief system at B station. 展开更多
关键词 Continuous undulating oil pipeline large elevation difference pressure relief system error-opening oil dis-charge improvement measure
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Synthesis and Thermoelectric Property of 1D Flexible PEDOT: p-TSA/Glass Fiber
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作者 xiaohua chen Guangshi Tang +1 位作者 Junqing Pan Hanfu Wang 《Journal of Minerals and Materials Characterization and Engineering》 2018年第3期448-463,共16页
Exploiting the thermal insulation properties of glass fiber and excellent conductivity of conducting polymer, a novel one-dimensional (1D) composite thermoelectric material, based on poly(3,4-ethylenedioxythiophene): ... Exploiting the thermal insulation properties of glass fiber and excellent conductivity of conducting polymer, a novel one-dimensional (1D) composite thermoelectric material, based on poly(3,4-ethylenedioxythiophene): p-toluenesulfonic acid (PEDOT: p-TSA)/glass fiber, is prepared by coating the PEDOT: p-TSA on the surface of glass fiber with in situ polymerization method. We hope the materials can bring out the performance of the “electron conductor, photon glass”. During the polymerization process, the effects of oxidant concentration and dopant mass fraction on thermoelectric properties of the materials are investigated. The group type of the polymer chain and the morphology of the samples were characterized by Fourier transform infrared spectroscopy (FT-IR) and scanning electron microscopy (SEM), respectively. The maximal Seebeck coefficient (S) and electric conductivity (σ) of the pristine sample are 32 μVK-1 and 169 Sm-1, respectively. After further post-processing with methanol, the thermoelectric properties of materials were improved, and the maximum value of S and σ increased greatly to 48.5 μVK-1 and 3184 Sm-1, respectively. The maximal power factor (PF) of materials also increased from 0.12 μWm-1 K-2 to 6.74 μWm-1 K-2. Moreover, we have proposed a preliminary explanation on the carrier transport mechanism. 展开更多
关键词 THERMOELECTRIC Materials FLEXIBLE Fiber SEEBECK Coefficient ORGANIC-INORGANIC Composite In SITU Polymerization
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<i>STYK1/NOK</i>—A Potential Radiotherapeutic Target and Biomarker for Gastric Cancer and Cervical Cancer
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作者 Ling Gao xiaohua chen +1 位作者 Zenghai Ma Fengsheng Li 《Journal of Cancer Therapy》 2013年第2期575-577,共3页
This article introduced the STYK1/NOK, including its origin, chemical composition and biological function, and the expression of STYK1/NOK in various cancer cell lines was reviewed. Furthermore, our recent study showe... This article introduced the STYK1/NOK, including its origin, chemical composition and biological function, and the expression of STYK1/NOK in various cancer cell lines was reviewed. Furthermore, our recent study showed that STYK1/NOK protein was also over expressed in gastric cancer and cervical cancer specimens, and STYK1/NOK expression increased after tumor cells were irradiated with γ ray. These results indicated that STYK1/NOK might be involved in the occurrence and progress of gastric cancer and cervical cancer, and contribute to the radioresistance of tumor cells. Thus, STYK1/NOK might be a potential therapeutic target and diagnostic marker for gastric cancer and cervical cancer. 展开更多
关键词 Gastric CANCER CERVICAL CANCER STYK1/NOK THERAPEUTIC Target
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Effect of Heat Treatment on Microstructure and Mechanical properties of high strength low alloy(HSLA)steel
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作者 Siyuan ZHAO Kaixuan chen +2 位作者 Yalikun·WUQIKUN xiaohua chen Zidong WANG 《Research and Application of Materials Science》 2019年第2期31-38,共8页
In this paper,a Fe-based Mn-Ni–Cr–Mo high strength low alloy(HSLA)steel was prepared by using Vacuum melting,following by hot rolling with 78%deformation and various heat treatment processes.Microstructure were char... In this paper,a Fe-based Mn-Ni–Cr–Mo high strength low alloy(HSLA)steel was prepared by using Vacuum melting,following by hot rolling with 78%deformation and various heat treatment processes.Microstructure were characterized by optical microscope(OM),scanning electron microscope(SEM)equipped with energy dispersive spectrometer.Tensile tests were performed.After direct quenching(Q)from 860℃,the samples were subjected to secondary quenching(L)at different intercritical temperatures within the two-phase region and various tempering temperatures(T).Results show that QLT treatment increases elongation and decreases yield ratio compared with conventional quenching and tempering process(QT).The optimum QLT heat treatment parameter in terms of temperature are determined as Q:860℃,L:700℃,and T:600℃,resulting in the better combined properties with yield strength of 756MPa,tensile strength of 820MPa,tensile elongation of 16.76%and yield ratio of 0.923. 展开更多
关键词 high STRENGTH low alloy(HSLA)steel QLT heat treatment TEMPERING MICROSTRUCTURES mechanical properties
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Effect of Carbides and γ/γ' Eutectic on Crack Initiation and Propagation in Ni-based Superalloy
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作者 Junwei QIN xiaohua chen +4 位作者 Kaixuan chen Xinghai YANG Weiyang XIE Yanlin WANG Zidong WANG 《Research and Application of Materials Science》 2020年第2期33-42,共10页
The Ni-based Udemit720Li superalloy tends to form largeγ/γ'eutectic on grain boundaries(GBs)during solidification due to the addition of excessive Al and Ti elements,which provides convenience to study the effec... The Ni-based Udemit720Li superalloy tends to form largeγ/γ'eutectic on grain boundaries(GBs)during solidification due to the addition of excessive Al and Ti elements,which provides convenience to study the effect of carbide andγ/γ'eutectic on crack initiation and propagation during tensile process.In this paper,Udemit720Li superalloy samples were prepared by induction melting casting method,arc melting and suction casting method.The microstructure,tensile properties and mechanism of crack initiation and propagation in Ni-based superalloy fabricated by two methods are investigated.The results exhibitγ/γ'eutectic accelerates the stress concentration at GB and thus leads to premature fracture failure.The samples with grain-boundary eutectic have higher strain hardening rate,but their cumulative and local misorientations are lower.For samples without eutectic at GB,the primary crack initiates at grain-boundary carbide along GB and extends along GB or into grain matrix,and exhibits better deformation performance and dislocation storage capacity within grains. 展开更多
关键词 SUPERALLOY Carbides EUTECTIC CRACK
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用于精准蛋白降解和癌症治疗的刺激响应型PROTAC进展 被引量:1
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作者 高晶 杨镭 +12 位作者 雷书敏 周峰 聂辉军 彭浡 徐田锋 陈小华 杨小宝 盛春泉 饶燏 蒲侃义 金坚 徐志爱 于海军 《Science Bulletin》 SCIE EI CAS CSCD 2023年第10期1069-1085,M0004,共18页
刺激响应型蛋白质降解靶向嵌合体(PROTAC)前药可在特定刺激条件下激活PROTAC分子,实现特定区域和细胞的靶蛋白降解,从而克服不可控蛋白降解导致的毒副作用,是改善PROTAC疗效和成药性的有效策略.本文系统总结了目前用于特异性降解病灶组... 刺激响应型蛋白质降解靶向嵌合体(PROTAC)前药可在特定刺激条件下激活PROTAC分子,实现特定区域和细胞的靶蛋白降解,从而克服不可控蛋白降解导致的毒副作用,是改善PROTAC疗效和成药性的有效策略.本文系统总结了目前用于特异性降解病灶组织目标蛋白从而精准治疗肿瘤的各种刺激响应型PROTAC前药策略.首先,本文介绍了PROTAC的发展历程和作用原理,以及目前进入临床试验阶段的PROTAC分子;然后,介绍了细胞内原位生成PROTAC的前药策略,以及各种刺激手段激活的PROTAC前药,包括外源性的光、X-射线以及内源性的肿瘤微环境的乏氧、活性氧和酶等;接着,概括了配体修饰型的主动靶向PROTAC前药,包括抗体、叶酸、适配体等修饰策略.本文重点强调了基于纳米递药系统的PROTAC前药策略,其可实现特异性肿瘤组织药物递送和精准蛋白降解.最后,本文对PROTAC的未来发展进行了探讨和展望. 展开更多
关键词 PROTAC Stimuli-activatable prodrug Preciseprotein degradation NANOMEDICINE Combinatory therapy
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Single-cell transcriptome landscape and antigen receptor dynamic during SARS-CoV-2 vaccination
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作者 Xiaojian Cao xiaohua chen +7 位作者 Yaqi Zhu Xiaojuan Gou Keyi Yan Bing Yang Dong Men Lei Liu Yong-an Zhang Gang Cao 《Genes & Diseases》 SCIE CSCD 2023年第4期1675-1686,共12页
Vaccination by inactivated vaccine is an effective strategy to prevent the COVID-19pandemic.However,the detailed molecular immune response at single-cell level is poorly un-derstood.In this study,we systematically del... Vaccination by inactivated vaccine is an effective strategy to prevent the COVID-19pandemic.However,the detailed molecular immune response at single-cell level is poorly un-derstood.In this study,we systematically delineated the landscape of the pre-and post-vaccination single-cell transcriptome,TCR(T cell antigen receptor)and BCR(B cell antigen re-ceptor)expression profile of vaccinated candidates.The bulk TCR sequencing analysis of COV-ID-19 patients was also performed.Enrichment of a clonal CD8+T cell cluster expressingspecific TCR was identified in both vaccination candidates and COVID-19 patients.These clonalCD8+T cells showed high expression of cytotoxicity,phagosome and antigen presentationrelated genes.The cellecell interaction analysis revealed that monocytes and dendritic cellscould interact with these cells and initiate phagocytosis via ICAM1-ITGAM and ITGB2 signaling.Together,our study systematically deciphered the detailed immunological response duringSARS-CoV-2 vaccination and infection.It may facilitate understanding the immune responseand the T-cell therapy against COVID-19. 展开更多
关键词 COVID-19 SARS-CoV-2 Single-cell sequencing TCR sequencing VACCINATION
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Small molecules in the treatment of COVID-19
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作者 Sibei Lei xiaohua chen +2 位作者 Jieping Wu Xingmei Duan Ke Men 《Signal Transduction and Targeted Therapy》 SCIE CSCD 2023年第1期38-76,共39页
The outbreak of COVID-19 has become a global crisis,and brought severe disruptions to societies and economies.Until now,effective therapeutics against COVID-19 are in high demand.Along with our improved understanding ... The outbreak of COVID-19 has become a global crisis,and brought severe disruptions to societies and economies.Until now,effective therapeutics against COVID-19 are in high demand.Along with our improved understanding of the structure,function,and pathogenic process of SARS-CoV-2,many small molecules with potential anti-COVID-19 effects have been developed.So far,several antiviral strategies were explored.Besides directly inhibition of viral proteins such as RdRp and M^(pro),interference of host enzymes including ACE2 and proteases,and blocking relevant immunoregulatory pathways represented by JAK/STAT,BTK,NF-κB,and NLRP3 pathways,are regarded feasible in drug development.The development of small molecules to treat COVID-19 has been achieved by several strategies,including computer-aided lead compound design and screening,natural product discovery,drug repurposing,and combination therapy.Several small molecules representative by remdesivir and paxlovid have been proved or authorized emergency use in many countries.And many candidates have entered clinical-trial stage.Nevertheless,due to the epidemiological features and variability issues of SARS-CoV-2,it is necessary to continue exploring novel strategies against COVID-19.This review discusses the current findings in the development of small molecules for COVID-19 treatment.Moreover,their detailed mechanism of action,chemical structures,and preclinical and clinical efficacies are discussed. 展开更多
关键词 finding TREATMENT SMALL
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Biosorption of clofibric acid and carbamazepine in aqueous solution by agricultural waste rice straw 被引量:6
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作者 Zhanguang Liu Xuefei Zhou +3 位作者 xiaohua chen Chaomeng Dai Juan Zhang Yalei Zhang 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2013年第12期2384-2395,共12页
Due to their widespread use, clofibric acid (CA) and carbamazepine (CBZ) have been frequently detected simultaneously at relatively high concentrations in aquatic environments. In this study, agricultural waste ri... Due to their widespread use, clofibric acid (CA) and carbamazepine (CBZ) have been frequently detected simultaneously at relatively high concentrations in aquatic environments. In this study, agricultural waste rice straw was employed as a potentially low-cost, effective and easy-to-operate biosorbent (RSB) to remove CA and CBZ. The adsorption of both pharmaceuticals followed pseudo second-order kinetics, and intraparticle diffusion was an important rate-limiting step. The adsorption isotherms of both drugs were fit well with Freundlich model. The adsorption of CA onto RSB was exothermic and was more likely to be dominated by physical processes, while the adsorption of CBZ was endothermic. Solution pH was determined to be the most important factor for CA adsorption, such that the adsorption capacity of CA onto RSB increased with the decline of solution pH. In the lower range of solution pH below 3. l, the CA removal efficiency was enhanced with the increase of biosorbent dosage. The CBZ removal efficiency was enhanced with the increase of RSB dosage without pH control. The maximum adsorption capacities were 126.3 mg/g for CA and 40.0 mg/g for CBZ. 展开更多
关键词 BIOSORPTION clofibric acid CARBAMAZEPINE rice straw agricultural waste uniform design
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Optimizing Mechanical Properties of AlCoCrFeNiTi_x High-Entropy Alloys by Tailoring Microstructures 被引量:6
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作者 Yinfeng WANG Shengguo MA +3 位作者 xiaohua chen Juyan SHI Yong ZHANG Junwei QIAO 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 2013年第3期277-284,共8页
The effects of Ti additions and the heat treatment on the mechanical properties of AlCoCrFeNiTix (x = 0, 0.2, 0.3, 0.4 and 0.5) high-entropy alloys (HEAs) were studied. The results show that the dendrite phase wit... The effects of Ti additions and the heat treatment on the mechanical properties of AlCoCrFeNiTix (x = 0, 0.2, 0.3, 0.4 and 0.5) high-entropy alloys (HEAs) were studied. The results show that the dendrite phase with a body-centered-cubic (bcc) structure transforms into the interdendrite phase with a new bcc structure. With the increase of the Ti contents and heat-treatment temperature, the average hardness and yield strengths are greatly improved, and the highest hardness and yielding strength are 583 HV and 2.07 GPa, respectively in the investigated HEA system. The as-cast and annealed HEAs exhibit excellent mechanical properties, combining with high yielding strength and plasticity. The solid solution strengthening mechanism of Ti additions is responsible for the strengthening effect of AlCoCrFeNiTix HEAs. 展开更多
关键词 High-entropy alloy MICROSTRUCTURE Compressive property HARDNESS Heat treatment
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DNA Extraction Protocol for Biological Ingredient Analysis of Liuwei Dihuang Wan 被引量:5
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作者 Xinwei cheng xiaohua chen +6 位作者 Xiaoquan Su Huanxin Zhao Maozhen Han Cunpei Bo Jian Xu Hong Bai Kang Ning 《Genomics, Proteomics & Bioinformatics》 SCIE CAS CSCD 2014年第3期137-143,共7页
Traditional Chinese medicine (TCM) clinical practice. So far, the methods commonly preparations are widely used for healthcare and used for quality evaluation of TCM preparations mainly focused on chemical ingredien... Traditional Chinese medicine (TCM) clinical practice. So far, the methods commonly preparations are widely used for healthcare and used for quality evaluation of TCM preparations mainly focused on chemical ingredients. The biological ingredient analysis of TCM preparations is also important because TCM preparations usually contain both plant and animal ingredients, which often include some mis-identified herbal materials, adulterants or even some biological contaminants. For biological ingredient analysis, the efficiency of DNA extraction is an important factor which might affect the accuracy and reliability of identification. The component complexity in TCM preparations is high, and DNA might be destroyed or degraded in different degrees after a series of processing procedures. Therefore, it is necessary to establish an effective protocol for DNA extraction from TCM preparations. In this study, we chose a classical TCM preparation, Liuwei Dihuang Wan (LDW), as an example to develop a TCM-specific DNA extraction method. An optimized cetyl trimethyl ammonium bromide (CTAB) method (TCM-CTAB) and three commonly-used extraction kits were tested for extraction of DNA from LDW samples. Experimental results indicated that DNA with the highest purity and concentration was obtained by using TCM-CTAB. To further evaluate the different extraction methods, amplification of the second internal transcribed spacer (ITS2) and the chloroplast genome trnL intron was carried out. 展开更多
关键词 DNA extraction Traditional Chinese medicinepreparation Biological ingredients Liuwei Dihuang Wan
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Using quantile regression to analyze the stressor–response relationships between nutrient levels and algal biomass in three shallow lakes of the Lake Taihu Basin, China 被引量:3
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作者 xiaohua chen Xiaoping Li 《Chinese Science Bulletin》 SCIE EI CAS 2014年第28期3621-3629,共9页
Understanding the stressor–response relationship between nutrient levels and algal biomass is a prerequisite for the management of eutrophication in lakes. In this study, a quantile regression(QR) approach was used t... Understanding the stressor–response relationship between nutrient levels and algal biomass is a prerequisite for the management of eutrophication in lakes. In this study, a quantile regression(QR) approach was used to interpret the stressor–response relationships between nutrient(e.g., phosphorus, nitrogen) concentrations and algal biomass as measured by chlorophyll-a(Chl-a) levels. QR results indicated that Lake Dianshan and Lake Changdang,which are both heavily eutrophicated, were P-limited only.In contrast, Lake Kuilei, which has significantly lower nutrient levels and algal biomass than the other two lakes,was P- and N-limited. Moreover, in Lake Kuilei, N and P levels had significant interaction effects on the algal biomass at the upper quantiles(s [ 0.68). The degree to which the lakes were P-limited increased with rises in the mean total P concentration in the lakes. QR has many advantages over ordinary least squares regression for discriminating limiting factors and, in particular, allows us to estimate changes near the upper extremes of distributions associated with limiting factors. QR is adapted to more specialized risk management problems, such as early warnings of the risk of algal blooms.The probable value-at-risk of harmful algal blooms for Lake Kuilei, Lake Dianshan and Lake Changdang is s = 0.76(Chl-a = 9 mg/m3), s = 0.87(Chl-a = 24 mg/m3) and s = 0.72(Chl-a = 35 mg/m3), respectively. Given the results of the stressor–response relationship analysis, we conclude that reductions in P input represent the most feasible and least costly approach for managing eutrophication in the shallow lakes of the Lake Taihu Basin. To control the magnitude and duration of algal blooms in shallow lakes,reductions in P and N inputs are required. The 95 % CI bounds of slopes indicated that the interactions of nonnutrient factors with nutrients had strong impacts on the algal biomass in lightly eutrophicated Lake Kuilei. It is suggested that, in addition to reductions in nutrient loads,several ecological measures, such as an increase in the biomass of submerged macrophytes and the reduction of hydraulic retention time by flushing, could represent important components of an integrated approach to eutrophication management in the Lake Taihu Basin. 展开更多
关键词 富营养化湖泊 藻类生物量 分位数回归 营养水平 应激反应 太湖流域 回归分析 中国
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Efficient interfacial charge transfer of BiOCl-In_(2)O_(3) step-scheme heterojunction for boosted photocatalytic degradation of ciprofloxacin 被引量:1
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作者 Kaiqiang Xu Jie Shen +2 位作者 Shiying Zhang Difa Xu xiaohua chen 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2022年第26期236-244,共9页
BiOCl as a representative layered bismuth-based photocatalyst with Sillén-structure has aroused wide public concern on photocatalytic degradation.However,the photocatalytic efficiency of pristine BiOCl is current... BiOCl as a representative layered bismuth-based photocatalyst with Sillén-structure has aroused wide public concern on photocatalytic degradation.However,the photocatalytic efficiency of pristine BiOCl is currently restricted by its low optical absorption and charge separation efficiency.Herein,step-scheme(S-scheme)heterojunctions of In_(2)O_(3) nanoparticle and BiOCl micron-sheet were constructed by a convenient molten salt method by using a LiNO_(3)-KNO_(3) system.The In_(2)O_(3)-BiOCl heterojunctions exhibit higher optical absorption performance from 380 nm to 700 nm than the pristine BiOCl and enhanced photocatalytic property toward ciprofloxacin(CIP)degradation under Xenon lamp illumination.The sample 20%In_(2)O_(3) -BiOCl showed the highest photodegradation efficiency,attaining 91%removal of CIP within 35 min,which was 39.6 times and 3.2 times higher than that of pristine In_(2)O_(3) and BiOCl,respectively.The improved photodegradation property mainly resulted from the novel S-scheme mechanism,which boosted highly efficient separation of the photo-induced carriers.The photoluminescence spectrometric test and transient photocurrent response results demonstrated that In_(2)O_(3)-BiOCl composite exhibited efficient separation of photo-generated charge carriers.This work would provide new insights into the design of novel S-scheme photocatalytic systems with applicability in photocatalytic water treatment. 展开更多
关键词 Step-scheme photocatalyst In_(2)O_(3) BiOCl Photocatalytic activity CIPROFLOXACIN
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One-pot synthesis of array-like sulfur-doped carbon nitride with covalently crosslinked ultrathin MoS cocatalyst for drastically enhanced photocatalytic hydrogen evolution
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作者 Shumin Zhang Hu Dong +7 位作者 Changsheng An Zhongfu Li Difa Xu Kaiqiang Xu Zhaohui Wu Jie Shen xiaohua chen Shiying Zhang 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2021年第16期59-67,共9页
Constructing noble-metal-free loaded catalyst with high-efficiency photocatalytic activity by a simple and scalable method is of profound significance for fundamental research and practical application.Herein,a simple... Constructing noble-metal-free loaded catalyst with high-efficiency photocatalytic activity by a simple and scalable method is of profound significance for fundamental research and practical application.Herein,a simple one-pot method was used to synthesize novel samples of array-like sulfur-doped graphitic carbon nitride(SCN)nanosheets with ultrathin MoS2 loading(MS/SCN-x%).The ultrathin MoS2 cocatalyst was evenly distributed on the surface of SCN and was linked to the main catalyst by covalent chemical bonds.Benefited from the multiple advantages of the array-like porous nanosheets structure with rich exposed surface,covalent cross-linking structure,and enhanced visible light absorption,the MS/SCN-2.5%composites drastically improve hydrogen evolution performance,which is superior to original MoS2 nanosheet modified by two-step mixing method,and also rivals with Pt/SCN.The designing strategy of photocatalyst modified by noble-metal-free cocatalyst with covalent bond structure provides fascinating insights into enhanced photocatalytic hydrogen evolution. 展开更多
关键词 Carbon nitride Noble-metal-free cocatalyst Covalent cross-linking Photocatalytic hydrogen evolution
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Deformation Mechanism in Fe_(61)Mn_(18)Si_(11)Cr_(10) Medium Entropy Alloy Under Different Strain Rates
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作者 Shaoheng Sun Yun Zhang +2 位作者 Zhiyong Xue Jiankun Lin xiaohua chen 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 2021年第8期1109-1119,共11页
We introduce a non-equiatomic Fe_(61)Mn_(18)Si_(11)Cr_(10) medium entropy alloy designed by subjecting it to transformation-induced plasticity upon deformation at room temperature. Microstructure characterization carr... We introduce a non-equiatomic Fe_(61)Mn_(18)Si_(11)Cr_(10) medium entropy alloy designed by subjecting it to transformation-induced plasticity upon deformation at room temperature. Microstructure characterization carried out using scanning electron microscopy(SEM), electron backscatter diffraction(EBSD), transmission electron microscopy(TEM) and X-ray diffraction(XRD) shows a homogeneous solid solution FCC + BCC structured dual phase. Investigations on the deformation substructures at specific strain levels via EBSD reveal the deformation-induced transformations of γ→α′ and γ→ ε. The strengths, particularly yield strength, of the designed alloy are found to be higher than these of the well-studied five component FeMnNiCoCr system for the introduction of the hard phase( α′-martensite). When tensile tests are performed at different strain rates of 10^(–4)s^(-1), 10^(–3)s^(-1), 10^(–2)s^(-1), the tested material exhibits a slightly negative strain rate sensitivity and work hardening rate sensitivity. 展开更多
关键词 Medium entropy alloy Dual phase Transformation-induced plasticity(TRIP)effect Strain rate
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