The Binchuan region is located in a seismically active area in northwestern Yunnan,China.The detailed crustal structure is important to understand the tectonic evolution and to assess the seismic hazard in the study a...The Binchuan region is located in a seismically active area in northwestern Yunnan,China.The detailed crustal structure is important to understand the tectonic evolution and to assess the seismic hazard in the study area.With a 2-D dense array deployed in this region,we use teleseismic receiver function traditional imaging methods,including the H-κand common-conversion-point stacking methods,to derive high-resolution crustal thickness and vP/vS ratio maps.Our results indicate that the crustal thickness increases from~40 km to~46 km in the south-north direction,and the average crustal thickness beneath the Binchuan basin is~42 km.Our results agree with previous results but have higher resolution due to dense interstation spacing.展开更多
In recent years,the trifluoromethoxy(OCF3)functional group has received extensive attention in phar-maceuticals,agrochemicals and material sciences.However,the methods for the enantioselective syn-thesis of trifluorom...In recent years,the trifluoromethoxy(OCF3)functional group has received extensive attention in phar-maceuticals,agrochemicals and material sciences.However,the methods for the enantioselective syn-thesis of trifluoromethoxylated stereogenic carbon centers are rare owing to the nature of easy decom-position of OCF3 anion and limited OCF3 reagent.And the asymmetric trifluoromethoxylation will be a hot research topic in near future due to the unique biological properties of a single isomer.This article mainly focuses on the recent advances in the enantioselectiveconstruction of trifluoromethoxylated stereogenic carbon centers.展开更多
The OCF_(3)group has good metabolic stability,suitable lipophilicity and special electrical properties,which can modify the properties of drugs and material molecules.In recent years,trifluoromethoxy compounds have re...The OCF_(3)group has good metabolic stability,suitable lipophilicity and special electrical properties,which can modify the properties of drugs and material molecules.In recent years,trifluoromethoxy compounds have received more and more attention.Both new reagents and new trifluoromethoxylation strategies got a breakthrough.Our group has been committed to the development of trifluoromethoxylation reagents and methods.This account focuses on describing various trifluoromethoxylation reactions with trifluoromethyl sulfonates(TFMS)and(E)-O-trifluoromethyl-benzaldoximes(TFBO)developed by our group.展开更多
基金supported by the National Key R&D Program of China(No.2018YFC1503400)China Earthquake Science Experiment Project,CEA(Nos.2018CSES0101,2018CSES0102 and 2019CSES0107)+2 种基金HKSAR Research Grant Council GRF(No.14305617)CUHK Direct Grant from Faculty of Science,National Natural Scientific Foundation of China(Nos.41974069 and 41790463)Chen Yong Academician Workstation of Yunnan Province in China(No.2014IC007)。
文摘The Binchuan region is located in a seismically active area in northwestern Yunnan,China.The detailed crustal structure is important to understand the tectonic evolution and to assess the seismic hazard in the study area.With a 2-D dense array deployed in this region,we use teleseismic receiver function traditional imaging methods,including the H-κand common-conversion-point stacking methods,to derive high-resolution crustal thickness and vP/vS ratio maps.Our results indicate that the crustal thickness increases from~40 km to~46 km in the south-north direction,and the average crustal thickness beneath the Binchuan basin is~42 km.Our results agree with previous results but have higher resolution due to dense interstation spacing.
文摘In recent years,the trifluoromethoxy(OCF3)functional group has received extensive attention in phar-maceuticals,agrochemicals and material sciences.However,the methods for the enantioselective syn-thesis of trifluoromethoxylated stereogenic carbon centers are rare owing to the nature of easy decom-position of OCF3 anion and limited OCF3 reagent.And the asymmetric trifluoromethoxylation will be a hot research topic in near future due to the unique biological properties of a single isomer.This article mainly focuses on the recent advances in the enantioselectiveconstruction of trifluoromethoxylated stereogenic carbon centers.
基金We are deeply indebted to all of the group members.We also thank the National Key Research and Development Program of China(2016YFA0602900)NFSC(21672110,21925105)+1 种基金the Natu-ral Science Foundation of Tianjin(Grant No.18JCIQJC47000)the Fundamental Research Funds for the Central Universities for financial support.
文摘The OCF_(3)group has good metabolic stability,suitable lipophilicity and special electrical properties,which can modify the properties of drugs and material molecules.In recent years,trifluoromethoxy compounds have received more and more attention.Both new reagents and new trifluoromethoxylation strategies got a breakthrough.Our group has been committed to the development of trifluoromethoxylation reagents and methods.This account focuses on describing various trifluoromethoxylation reactions with trifluoromethyl sulfonates(TFMS)and(E)-O-trifluoromethyl-benzaldoximes(TFBO)developed by our group.
