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PNIPAm温敏纳米纤维膜:交联作用下的形貌稳定性和响应行为
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作者 田晓靖 黄至纯 +3 位作者 张青松 王旭 杨宁 邓南平 《物理化学学报》 SCIE CAS CSCD 北大核心 2024年第4期52-67,共16页
聚N-异丙基丙烯酰胺(PNIPAm)交联温敏纳米纤维膜作为一种相变温度易于控制的新兴响应性材料,克服了传统PNIPAm块状水凝胶的生产成本高、响应速率慢和PNIPAm非交联温敏纳米纤维耐水性差的缺点,受到广泛研究并应用于智能开关、温度致动器... 聚N-异丙基丙烯酰胺(PNIPAm)交联温敏纳米纤维膜作为一种相变温度易于控制的新兴响应性材料,克服了传统PNIPAm块状水凝胶的生产成本高、响应速率慢和PNIPAm非交联温敏纳米纤维耐水性差的缺点,受到广泛研究并应用于智能开关、温度致动器、水油分离、药物、细胞控制释放和伤口敷料等领域。形貌稳定性和快速响应性是温敏纳米纤维膜在重复体积变化过程中最大的挑战,同时也作为评价PNIPAm温敏纳米纤维膜的实用性最重要指标引起了人们广泛的关注。本文全面综述了PNIPAm温敏纳米纤维膜近二十年来国内外的突破性进展和非交联作用下PNIPAm温敏纳米纤维膜的形貌变化和响应性,重点综合分析了物理和化学交联中交联反应类型、交联度、交联时间和交联分子量对PNIPAm温敏纳米纤维膜的形貌稳定性和响应行为的影响,为之后纤维膜的交联处理提供了理论支持,并对PNIPAm温敏纳米纤维膜的发展及应用前景进行了展望。 展开更多
关键词 聚N-异丙基丙烯酰胺 纳米纤维膜 形貌稳定性 响应性 耐水性
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Decoupling effects of driving factors on sediment yield in the Chinese Loess Plateau 被引量:2
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作者 xiaojing tian Guangju Zhao +5 位作者 Xingmin Mu Pengfei Zhang Peng Gao Wenyi Sun Xiaoyan Lu Peng tian 《International Soil and Water Conservation Research》 SCIE CSCD 2023年第1期60-74,共15页
Investigations of runoff and sediment yield changes and their relationships with potential driving factors provide good insights for understanding the mechanisms of hydrological processes.This study attempted to prese... Investigations of runoff and sediment yield changes and their relationships with potential driving factors provide good insights for understanding the mechanisms of hydrological processes.This study attempted to present a comprehensive investigation on the spatiotemporal variations of sediment yield in the Loess Plateau using continuous observed data at 46 hydrological stations during 1961-2016,and its responses to changes of precipitation,land use/cover and vegetation cover were analyzed by using the Partial Least Squares-Structural Equation Model(PLS-SEM).The results indicated that sediment yield reduced pro-nouncedly during 1961-2016 in the Loess Plateau,and 77.9%of this variation was explained by the combined effects of precipitation,land-use change,vegetation dynamics and runoff reduction.Indirect effects of precipitation,land-use change,and vegetation cover on sediment yield were 0.242,-0.528 and-0.630(P<0.05),respectively,and direct effect of runoff on sediment yield was 0.833(P<0.05).According to the Pearson Correlation Coefficient,the strongest positive correlation existed between annual sediment yield and runoff(r=0.88,P<0.05),followed by vegetation cover(r=-0.47,P<0.05)and land-use change(i.e.forest land and grassland)suggesting their significant trapping effects on soil erosion.However,lower correlations were examined between sediment yield and precipitation indices(-0.14<r<0.34),and a relatively higher relationship was examined between sediment yield and heavy rainfall(P_(25))(r=034).Overall,changes in runoff and land-use/vegetation cover well explained varia-tions in sediment yield in the Loess Plateau.The findings are expected to provide scientific and technical support for future soil and water conservation planning in the Loess Plateau,and are valuable for sus-tainable water resources and sediment load management in the Yellow River Basin. 展开更多
关键词 Sediment yield Driving factors Correlation analysis PLS-SEM Loess Plateau
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