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天津市地下水硝酸盐污染现状与年际变化规律研究
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作者 李明悦 廉晓娟 +1 位作者 朱静华 高贤彪 《环境保护前沿》 2013年第3期90-94,共5页
硝酸盐含量是衡量地下水水质的重要指标,直接关系到人类的健康。为了摸清天津市地下水硝酸盐污染现状,2005~2008年连续8年对天津市地下水进行了取样调查及硝酸盐含量监测,对地下水硝酸盐污染现状及年际变化规律进行了分析研究。结果表明... 硝酸盐含量是衡量地下水水质的重要指标,直接关系到人类的健康。为了摸清天津市地下水硝酸盐污染现状,2005~2008年连续8年对天津市地下水进行了取样调查及硝酸盐含量监测,对地下水硝酸盐污染现状及年际变化规律进行了分析研究。结果表明,天津市地下水含量总体较低,平均值为6.82 mg/L,其中约14.98%的地下水样超过WHO饮用水标准,约10.84%的地下水样超过我国地下水质量标准。地下水硝酸盐含量年际之间变化较大,总体表现为先降低后增加后又趋于平缓的趋势,由2005年的11.88 mg/L降至2007年的3.59 mg/L,而后逐渐升高至2012年的7.52 mg/L。不同监测时期地下水10 mg/L、20 mg/L超标率与相应时期地下水平均含量均呈极显著正相关。地下水平均含量每升高1 mg/L,10 mg/L、20 mg/L超标率分别提高1.90和1.67个百分点。 展开更多
关键词 天津市 地下水 硝酸盐 变化规律 污染
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新型Ti_(3)C_(2)MXene的化学制备及基于MXene忆阻器特性与机理
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作者 王钰琪 张缪城 +7 位作者 徐威 沈心怡 高斐 朱家乐 万相 连晓娟 许剑光 童祎 《物理化学学报》 SCIE CAS CSCD 北大核心 2022年第3期15-22,共8页
阻变器件是一种微电子器件,具有阻值可在两个甚至两个以上的阻态之间重复变化的特点。忆阻器作为新型的阻变器件,具有可连续变化的丰富阻态。近年来因其具备简单的二端结构、高集成度以及低工作电压等特性,在新型非易失性存储以及构建... 阻变器件是一种微电子器件,具有阻值可在两个甚至两个以上的阻态之间重复变化的特点。忆阻器作为新型的阻变器件,具有可连续变化的丰富阻态。近年来因其具备简单的二端结构、高集成度以及低工作电压等特性,在新型非易失性存储以及构建神经形态系统等方面被广泛研究。但其在实现应用的过程中仍存在着稳定性较差等问题。近期一些工作证明了二维材料如氧化石墨烯在优化忆阻器性能方面具备良好的应用潜力。MXene是一种具备类似石墨烯结构的新型二维过渡金属碳/氮化物,因其具备二维层状结构显现出特殊的力学以及电学特性,有望应用于忆阻器中以提高器件的电学性能。在本文中,我们通过化学湿法刻蚀制备了Ti_(3)C_(2)粉末,通过旋涂工艺在忆阻器结构中引入Ti_(3)C_(2)薄膜。Ti_(3)C_(2)MXene与SiO_(2)同时作为忆阻器阻变层,制备了Cu/Ti_(3)C_(2)/SiO_(2)/W结构的忆阻器,并且对其相关电学特性进行了探究。在该器件上,通过实验测得忆阻器典型的开关特性曲线并在双向直流电压下针对高、低阻态的可重复性、稳定性进行了实验。结果表明该器件能够在100个扫描循环过程中保持稳定的高、低阻态达到10^(4) s以上。同时,该器件状态能够受脉冲电压调节,实现突触间典型的双脉冲易化行为。实验结果表明基于Ti_(3)C_(2)MXene的忆阻器将有望应用于构建新兴存储设备以及人工神经形态系统。 展开更多
关键词 阻变器件 忆阻器 湿法刻蚀 MXene 导电特性 导电机理
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Effects of Different Drip Irrigation Fertilizers on Nutrient Levels in Celery and Soil under Drip Irrigation
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作者 Jun YANG xiaojuan lian +2 位作者 Yan WANG Yuliang ZHANG Zhengxiang WANG 《Agricultural Biotechnology》 CAS 2017年第2期34-40,44,共8页
This study was conducted to investigate the effects of different fertilizers on nitrogen, phosphorus and potassium 'absorption and distribution by celeo, and the changes of soil nutrients in the 0 -40 cm soil layer u... This study was conducted to investigate the effects of different fertilizers on nitrogen, phosphorus and potassium 'absorption and distribution by celeo, and the changes of soil nutrients in the 0 -40 cm soil layer under drip irrigation, so as to provide a theoretical basis for nutrient management of greenhouse celery culti- vation and special fertilizer development. With celery as an experiment material and the ratio of conventional fertilization as control treatment, the effects of different ratios of nitrogen, phosphorus and potassium on nutrient absorption by celery and changes of soil nutrients were investigated by plot experiment in greenhouse. The results showed that the contents and distribution proportions of N and P in leaf were higher than those in stem, while for K, the content and distribution proportion were higher in stem than in leaf. The absorption amount of K was the highest in celery, followed by N, and the absorption amount of P element was the least. The mean ratio of N, P and K in celery was 1:0.556: 1.609. There were evident dynamic changes in contents of soil available nutrients in the 0 -20 cm soil layer in various growth stages of celery under different drip irrigation fertilizers. The contents of soil available nutrients were higher on the 28'h , 47~ and 83'h d "after fieht planting, while those before field planting and after harvest were lower. So the amounts of soil available nutrients were closely related to the growth stage of celery. In the whole growth period of celery, the mean input amounts of N, P205 and K20 were 805, 1 049 and 916 kg/hm2 , respectively, but the absorption amounts of nutrients by celery were far less than inputs, and the amounts of N, P205 and K20 absorbed by celery" were only 23% -26% , 10% and 31% -35% of the appli- cation amounts, respectively. The apparent balance of N, P2 O5 and Kz O were 613,943 and 609 kg/hm2 , respectively, indicating excess fertilization in this experi- ment. Under this experiment condition, Tj ( N: PzOs: K20 = 1 : 0.63: 1.08) favored increase of celery yield and absorption of nitrogen, phosphorus and petassium by celery. The results will provide a scientific basis for study and utilization of special fertilizer for drip irrigation on celery. Key words Drip irrigation; Fertilizer for drip irrigation; Celery; Soil nutrient; Apparent balance 展开更多
关键词 Drip irrigation Fertilizer for drip irrigation CELERY Soil nutrient Apparent balance
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Micro/nanostructured amorphous TiNbZr films to enhance the adhesion strength and corrosion behavior of stainless steel
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作者 xiaojuan lian Hongzhi Cui +2 位作者 Quanzhi Wang Xiaojie Song Xin Yang 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2023年第33期1-12,共12页
To improve the corrosion resistance of key components and ensure the service safety of marine equipment,here we combined femtosecond(fs)laser fabrication and magnetron sputtering deposition to develop micro/nanostruct... To improve the corrosion resistance of key components and ensure the service safety of marine equipment,here we combined femtosecond(fs)laser fabrication and magnetron sputtering deposition to develop micro/nanostructured amorphous TiNbZr films.Analysis of the compositional,microstructural,corrosion,and mechanical properties was conducted.The results showed that the TiNbZr films were amorphous,and spherical TiNbZr nanoparticles uniformly covered the fs laser-induced periodic fringe structure.A complex hierarchical micro/nanostructure was formed that was hydrophobic and showed enhanced adhesion strength.The TiNbZr films deposited on fs laser-treated substrates provided the best corrosion resistance,showing a self-corrosion current density of 116 nA/cm^(2),excellent passive ability,and pitting resistance.The microscratch test revealed that the micro/nanostructures doubled the binding strength of the TiNbZr/316L interface due to the compositional and structural gradients induced by an approximately 20 nm transition layer formed during fs laser processing.This work provides a new method for obtaining anti-corrosion films with a high adhesion strength for marine applications. 展开更多
关键词 Femtosecond laser Micro/nanostructures ANTI-CORROSION Adhesion strength Magnetron sputtering
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