We investigated the spatial distribution （horizontal and vertical concentrations） of copper （Cu）, lead （Pb）, zinc （Zn）, and cadmium （Cd） in five wetland types （mudflat, aquaculture wetland, water area, farm...We investigated the spatial distribution （horizontal and vertical concentrations） of copper （Cu）, lead （Pb）, zinc （Zn）, and cadmium （Cd） in five wetland types （mudflat, aquaculture wetland, water area, farmland wetland and mangrove） from three areas （Ningde, Fuding, and Xiapu）, China. Cu concentrations in five wetland types descended in the order： farm wetland, mudflat, aquaculture, water area and mangrove. Pb concentrations decreased in the order： aquaculture, mangrove, farm wetland, mudflat, and water area. Zn content decreased in the order： farm wetland, water area, aquaculture, mudflat and mangrove, and Cd content decreased as follows： mangrove, aquacul- ture, water area, rnudflat, and farm wetland. Comparison of the concentrations of the same heavy metals in different areas showed that the highest Cu （63.75 mg kg-1） and Zn （152.32mgkg-1） concentrations occurred in Ningdecoastal wetlands; Pb （110.58 mg kg-1） and Cd （2.81 mg kg-1） contents were highest in Fuding wetlands, and the average contents of all heavy metals were very low in Xiapu wetlands. Examination of the vertical distribution showed that the Cu content was high in all mudflat layers; Pb and Cd concentrations were highest in aquaculture and mangrove wetlands, respectively, and Zn content was highest in farm wetlands. The spatial distribution of Cu and Zn contents for different areas decreased as follows： Ningde 〉 Fuding 〉 Xiapu, for Pb and Cd were most concentrated in Fuding coastal wetlands. Concentrations of Zn and Cu were highly correlated, while Zn and Cu were not significantly correlated with Pb.展开更多
Integrating silica with organic nanoparticles can generate unique properties.Here pillar[5]arene/silica hybrid vesicles were constructed based on the amphiphilic and rigid properties of pillararenes,as well as the cat...Integrating silica with organic nanoparticles can generate unique properties.Here pillar[5]arene/silica hybrid vesicles were constructed based on the amphiphilic and rigid properties of pillararenes,as well as the catalytic hydrolysis of tetraethoxysilane.Such vesicles exhibited the high strength of silica and unique molecular recognition of pillararenes,both of which could tune the pH-trigge red release behavior.Furthermore,a rhodamine B derivative with hexyl group(RhB-C6) was synthesized,which can form a complex with the pillar[5]arene.Based on the host-guest interaction and high strength of silica,the hybrid vesicles could load more RhB-C6 and the rhodamine B was released more slowly compared with the organic vesicles.展开更多
基金supported by the National Natural Science Foundation of China(Grant No.31370624)Key Financing Project of Fujian Provincial Department of Science and Technology(2009N0009)
文摘We investigated the spatial distribution （horizontal and vertical concentrations） of copper （Cu）, lead （Pb）, zinc （Zn）, and cadmium （Cd） in five wetland types （mudflat, aquaculture wetland, water area, farmland wetland and mangrove） from three areas （Ningde, Fuding, and Xiapu）, China. Cu concentrations in five wetland types descended in the order： farm wetland, mudflat, aquaculture, water area and mangrove. Pb concentrations decreased in the order： aquaculture, mangrove, farm wetland, mudflat, and water area. Zn content decreased in the order： farm wetland, water area, aquaculture, mudflat and mangrove, and Cd content decreased as follows： mangrove, aquacul- ture, water area, rnudflat, and farm wetland. Comparison of the concentrations of the same heavy metals in different areas showed that the highest Cu （63.75 mg kg-1） and Zn （152.32mgkg-1） concentrations occurred in Ningdecoastal wetlands; Pb （110.58 mg kg-1） and Cd （2.81 mg kg-1） contents were highest in Fuding wetlands, and the average contents of all heavy metals were very low in Xiapu wetlands. Examination of the vertical distribution showed that the Cu content was high in all mudflat layers; Pb and Cd concentrations were highest in aquaculture and mangrove wetlands, respectively, and Zn content was highest in farm wetlands. The spatial distribution of Cu and Zn contents for different areas decreased as follows： Ningde 〉 Fuding 〉 Xiapu, for Pb and Cd were most concentrated in Fuding coastal wetlands. Concentrations of Zn and Cu were highly correlated, while Zn and Cu were not significantly correlated with Pb.
基金supported by the National Natural Science Foundation of China(No.21774033)the open research fund of Key Laboratory for Organic Electronics and Information Displays。
文摘Integrating silica with organic nanoparticles can generate unique properties.Here pillar[5]arene/silica hybrid vesicles were constructed based on the amphiphilic and rigid properties of pillararenes,as well as the catalytic hydrolysis of tetraethoxysilane.Such vesicles exhibited the high strength of silica and unique molecular recognition of pillararenes,both of which could tune the pH-trigge red release behavior.Furthermore,a rhodamine B derivative with hexyl group(RhB-C6) was synthesized,which can form a complex with the pillar[5]arene.Based on the host-guest interaction and high strength of silica,the hybrid vesicles could load more RhB-C6 and the rhodamine B was released more slowly compared with the organic vesicles.
