This study investigates the submesoscale fronts and their dynamic effects on the mean flow due to frontal instabilities in the wind-driven summer offshore jet of the western South China Sea(WSCS),using satellite obser...This study investigates the submesoscale fronts and their dynamic effects on the mean flow due to frontal instabilities in the wind-driven summer offshore jet of the western South China Sea(WSCS),using satellite observations,a 500 m-resolution numerical simulation,and diagnostic analysis.Both satellite measurements and simulation results show that the submesoscale fronts occupying a typical lateral scale of O(~10)km are characterized with one order of Rossby(Ro)and Richardson(Ri)numbers in the WSCS.This result implies that both geostrophic and ageostrophic motions feature in these submesoscale fronts.The diagnostic results indicate that a net cross-frontal Ekman transport driven by down-front wind forcing effectively advects cold water over warm water.By this way,the weakened local stratification and strong lateral buoyancy gradients are conducive to a negative Ertel potential vorticity(PV)and triggering frontal symmetric instability(SI)at the submesoscale density front.The cross-front ageostrophic secondary circulation caused by frontal instabilities is found to drive an enhanced vertical velocity reaching O(100)m/d.Additionally,the estimate of the down-front wind forcing the Ekman buoyancy flux(EBF)is found to be scaled with the geostrophic shear production(GSP)and buoyancy flux(BFLUX),which are the two primary energy sources for submesoscale turbulence.The large values of GSP and BFLUX at the fronts suggest an efficient downscale energy transfer from larger-scale geostrophic flows to the submesoscale turbulence owing to down-front wind forcing and frontal instabilities.In this content,submesoscale fronts and their instabilities substantially enhance the local vertical exchanges and geostrophic energy cascade towards smaller-scale.These active submesoscale processes associated density fronts and filaments likely provide new physical interpretations for the filamentary high chlorophyll concentration and frontal downscale energy transfer in the WSCS.展开更多
Bone defect repair remains a troubling problem in clinical orthopedics,which involves complex biological processes.Calcium phosphates(CaPs)have been widely used owing to their advantage of biocompatibility.However,sin...Bone defect repair remains a troubling problem in clinical orthopedics,which involves complex biological processes.Calcium phosphates(CaPs)have been widely used owing to their advantage of biocompatibility.However,single component and traditional fabrication methods cannot meet the requirements of bioadaptability during the tissue repair process.In this work,0%,5%,15%,25%wt%of BG-TCP(bioactive glass-β-tricalcium phosphate)bioresorbable scaffolds with triply-periodic minimal surfaces(TPMS)-gyroid structure were prepared by the stereolithography(SLA)technology.TPMS-gyroid structure provided an accurate mimicry of natural bone tissue,and the incorporation of BG improved the compressive strength ofβ-TCP matrix,matched with the defective bone(2–12 MPa).Rapid but tunable degradation kinetics(compared with pure TCP)of BG enabled the BG-TCP system to sh8ow adaptable biodegradability to new bone generation.In vitro studies have shown that composite scaffolds have better mechanical properties(7.82 MPa),and can released appropriate contents of calcium,phosphorous,and magnesium ions,which promoted the osteogenic differentiation of bone marrow mesenchymal stem cells(BMSCs)and angiogenic ability of endothelial progenitor cells(EPCs).Moreover,the in vivo assessment of rat femoral defect revealed that TPMS-structure-based TCP scaffolds accelerated bone ingrowth to the pores.Moreover,BG-TCP scaffolds,especially 15BG-TCP group,exhibited superior bone regeneration capacity at both 4 and 8 weeks,which achieved an optimal match between the rate of material degradation and tissue regeneration.In summary,this study provides insight into influences of bioactive components(BG)and bionic structures(TPMS)on the physical-chemical properties of materials,cell behavior and tissue regeneration,which offers a promising strategy to design bioadaptive ceramic scaffolds in the clinical treatment of bone defects.展开更多
Na Cl O has been widely used to restore membrane flux in practical membrane cleaning processes,which would induce the formation of toxic halogenated byproducts.In this study,we proposed a novel heatactivated peroxydis...Na Cl O has been widely used to restore membrane flux in practical membrane cleaning processes,which would induce the formation of toxic halogenated byproducts.In this study,we proposed a novel heatactivated peroxydisulfate(heat/PDS)process to clean the membrane fouling derived from humic acid(HA).The results show that the combination of heat and PDS can achieve almost 100%recovery of permeate flux after soaking the HA-fouled membrane in 1 mmol/L PDS solution at 50℃ for 2 h,which is attributed to the changes of HA structure and enhanced detachment of foulants from membranes.The properties of different treated membranes are characterized by scanning electron microscopy(SEM),atomic force microscope(AFM),attenuated total reflection Fourier transform infrared spectroscopy(ATRFTIR),and X-ray photoelectron spectroscopy(XPS),demonstrating that the reversible and irreversible foulants could be effectively removed by heat/PDS cleaning.The filtration process and fouling mechanism of the cleaned membrane were close to that of the virgin membrane,illustrating the good reusability of the cleaned membrane.Additionally,heat/PDS which can avoid the generation of halogenated byproducts shows comparable performance to Na Cl O on membrane cleaning and high performance for the removal of fouling caused by sodium alginate(SA),HA-bovine serum albumin(BSA)-SA mixture and algae,further suggesting that heat/PDS would be a potential alternative for membrane cleaning in practical application.展开更多
Plasma-activated water(PAW)has been utilised in various application fields,and a deep understanding on the plasma chemistry is the foundation of application-orientated optimisation.In this paper,a global model is buil...Plasma-activated water(PAW)has been utilised in various application fields,and a deep understanding on the plasma chemistry is the foundation of application-orientated optimisation.In this paper,a global model is built to study the chemical properties of PAW produced by a dielectric barrier discharge that is powered by nanosecond voltage pulses.The applied voltage is firstly repeated with 10 kHz frequency for 100 s,and then shut down for 200 s afterglow,providing a long-term evolution regarding the production and consumption of some typical reactive oxygen/nitrogen species(RONS)in PAW.The calculated results agree principally with experimental measurements from literature.During the pulsed discharge,the water gradually acidises,and the long-lived species accumulate;while in the afterglow,most of the aqueous RONS decay rapidly,except for O_(3aq),NO_(3aq)^(−),H_(2)O_(2aq)and N_(2)O_(aq),which might be the main sources to sustain long-term effects.Furthermore,the effects of applied voltage and gap distance on RONS are investigated.Correlation analyses from Pearson correlation coefficient indicate that gaseous RONS are more sensitive to the gap distance,while the aqueous ones are more sensitive to the voltage amplitude,suggesting the possibility to independently regulating the gaseous and aqueous chemistry.展开更多
Aims Aquatic plants play an important role in freshwater ecosystems.Previous works have largely focused on the functional significance of plant above ground parts,with much less attention on the root structures of aqu...Aims Aquatic plants play an important role in freshwater ecosystems.Previous works have largely focused on the functional significance of plant above ground parts,with much less attention on the root structures of aquatic plants.In this study,we divided 21 aquatic plants(including five introduced plants)into multiple plant groups(different life forms,monocot/eudicot and introduced/native)with the goal of addressing two questions:(i)what root structures do aquatic plants exhibit,and(ii)are there differences among these plant groups?Methods Twenty-one aquatic plants belonging to four life forms(free-float-ing,emergent,floating-leaved and submerged)were collected at the near flowering stage from a typical macrophyte-dominated lake in the yangtze River Basin,China.The following root topological parameters were quantified:altitude(a),path length(pe),magnitude(M),mean topological length(b),topological index(TI)and normed indices qa and qb.Important Findings The root topological indices TI,qa and qb for the 21 aquatic plants were 0.724±0.013,0.290±0.031 and 0.152±0.024(means±S.E.),respectively,revealing a general pattern of dichotomous branching,except for the aquatic root of Myriophyllum aquati-cum(Vell.)Verdc.,which displays herringbone branching.All three topological indices were significantly lower for monocots(TI=0.700±0.130,qa=0.191±0.149 and qb=0.086±0.236)than eudicots(TI=0.752±0.206,qa=0.405±0.569 and qb=0.229±0.393),indicating that the roots of monocots are typi-cally more dichotomous-like than those of eudicots.Among the four life forms,the three topological indices for emergent plants(TI=0.832±0.006,qa=0.616±0.018 and qb=0.381±0.014)were significantly higher than those of the other three life forms.Overall,there was no difference between the topological indices of introduced and native aquatic plants,but the introduced species M.aquaticum and Alternanthera philoxeroides(Mart.)Griseb.had both aquatic and edaphic roots as well as unusual functions,which may help explain their strong viability.展开更多
基金supported by the Chinese Academy of Sciences under contract Nos ZDBS-LY-DQC011ZDRW-XH-2019-2 and ISEE2018PY05+4 种基金the Southern Marine Science and Engineering Guangdong Laboratory(Guangzhou)under contract No.GML2019ZD0303the National Natural Science Foundation of China under contract Nos 41776040 and 92058201the Pilot National Laboratory for Marine Science and Technology(Qingdao)under contract No.OCFL-201804the State Key Laboratory of Tropical Oceanography under contract No.LTO1907the Guangzhou Science and Technology Project under contract No.201904010420。
文摘This study investigates the submesoscale fronts and their dynamic effects on the mean flow due to frontal instabilities in the wind-driven summer offshore jet of the western South China Sea(WSCS),using satellite observations,a 500 m-resolution numerical simulation,and diagnostic analysis.Both satellite measurements and simulation results show that the submesoscale fronts occupying a typical lateral scale of O(~10)km are characterized with one order of Rossby(Ro)and Richardson(Ri)numbers in the WSCS.This result implies that both geostrophic and ageostrophic motions feature in these submesoscale fronts.The diagnostic results indicate that a net cross-frontal Ekman transport driven by down-front wind forcing effectively advects cold water over warm water.By this way,the weakened local stratification and strong lateral buoyancy gradients are conducive to a negative Ertel potential vorticity(PV)and triggering frontal symmetric instability(SI)at the submesoscale density front.The cross-front ageostrophic secondary circulation caused by frontal instabilities is found to drive an enhanced vertical velocity reaching O(100)m/d.Additionally,the estimate of the down-front wind forcing the Ekman buoyancy flux(EBF)is found to be scaled with the geostrophic shear production(GSP)and buoyancy flux(BFLUX),which are the two primary energy sources for submesoscale turbulence.The large values of GSP and BFLUX at the fronts suggest an efficient downscale energy transfer from larger-scale geostrophic flows to the submesoscale turbulence owing to down-front wind forcing and frontal instabilities.In this content,submesoscale fronts and their instabilities substantially enhance the local vertical exchanges and geostrophic energy cascade towards smaller-scale.These active submesoscale processes associated density fronts and filaments likely provide new physical interpretations for the filamentary high chlorophyll concentration and frontal downscale energy transfer in the WSCS.
基金supported by the Sichuan Meteorological Bureau,the Sichuan Meteorological Observation and Data Centerthe Heavy Rain and Drought-Flood Disasters in Plateau and Basin Key Laboratory of Sichuan Province[grant number SCQXKJQN202121]+1 种基金the Key Technology Development Project of Weather Forecasting[grant number YBGJXM(2020)1A-08]the Innovative Development Project of the China Meteorological Administration[grant number CXFZ2021Z007]。
基金financially supported by the National Key Research and Development Program of China(Nos.2022YFB4601402)the National Natural Science Foundation of China(Nos.32201109,51772233)+2 种基金the Guangdong Basic and Applied Basic Research Foundation(Nos.2022B1515120052,2021A1515110557)the Key Basic Research Program of Shenzhen(No.JCYJ20200109150218836)the Chaozhou Branch of Chemistry and Chemical Engineering Guangdong Laboratory(No.HJL202202A002)。
文摘Bone defect repair remains a troubling problem in clinical orthopedics,which involves complex biological processes.Calcium phosphates(CaPs)have been widely used owing to their advantage of biocompatibility.However,single component and traditional fabrication methods cannot meet the requirements of bioadaptability during the tissue repair process.In this work,0%,5%,15%,25%wt%of BG-TCP(bioactive glass-β-tricalcium phosphate)bioresorbable scaffolds with triply-periodic minimal surfaces(TPMS)-gyroid structure were prepared by the stereolithography(SLA)technology.TPMS-gyroid structure provided an accurate mimicry of natural bone tissue,and the incorporation of BG improved the compressive strength ofβ-TCP matrix,matched with the defective bone(2–12 MPa).Rapid but tunable degradation kinetics(compared with pure TCP)of BG enabled the BG-TCP system to sh8ow adaptable biodegradability to new bone generation.In vitro studies have shown that composite scaffolds have better mechanical properties(7.82 MPa),and can released appropriate contents of calcium,phosphorous,and magnesium ions,which promoted the osteogenic differentiation of bone marrow mesenchymal stem cells(BMSCs)and angiogenic ability of endothelial progenitor cells(EPCs).Moreover,the in vivo assessment of rat femoral defect revealed that TPMS-structure-based TCP scaffolds accelerated bone ingrowth to the pores.Moreover,BG-TCP scaffolds,especially 15BG-TCP group,exhibited superior bone regeneration capacity at both 4 and 8 weeks,which achieved an optimal match between the rate of material degradation and tissue regeneration.In summary,this study provides insight into influences of bioactive components(BG)and bionic structures(TPMS)on the physical-chemical properties of materials,cell behavior and tissue regeneration,which offers a promising strategy to design bioadaptive ceramic scaffolds in the clinical treatment of bone defects.
基金supported by the Natural Science Foundation of China(Nos.52070081,51578258 and 51878308)the National Key Research and Development Program of China(No.2022YFC3203500)。
文摘Na Cl O has been widely used to restore membrane flux in practical membrane cleaning processes,which would induce the formation of toxic halogenated byproducts.In this study,we proposed a novel heatactivated peroxydisulfate(heat/PDS)process to clean the membrane fouling derived from humic acid(HA).The results show that the combination of heat and PDS can achieve almost 100%recovery of permeate flux after soaking the HA-fouled membrane in 1 mmol/L PDS solution at 50℃ for 2 h,which is attributed to the changes of HA structure and enhanced detachment of foulants from membranes.The properties of different treated membranes are characterized by scanning electron microscopy(SEM),atomic force microscope(AFM),attenuated total reflection Fourier transform infrared spectroscopy(ATRFTIR),and X-ray photoelectron spectroscopy(XPS),demonstrating that the reversible and irreversible foulants could be effectively removed by heat/PDS cleaning.The filtration process and fouling mechanism of the cleaned membrane were close to that of the virgin membrane,illustrating the good reusability of the cleaned membrane.Additionally,heat/PDS which can avoid the generation of halogenated byproducts shows comparable performance to Na Cl O on membrane cleaning and high performance for the removal of fouling caused by sodium alginate(SA),HA-bovine serum albumin(BSA)-SA mixture and algae,further suggesting that heat/PDS would be a potential alternative for membrane cleaning in practical application.
基金National Natural Science Foundation of China,Grant/Award Number:51977085。
文摘Plasma-activated water(PAW)has been utilised in various application fields,and a deep understanding on the plasma chemistry is the foundation of application-orientated optimisation.In this paper,a global model is built to study the chemical properties of PAW produced by a dielectric barrier discharge that is powered by nanosecond voltage pulses.The applied voltage is firstly repeated with 10 kHz frequency for 100 s,and then shut down for 200 s afterglow,providing a long-term evolution regarding the production and consumption of some typical reactive oxygen/nitrogen species(RONS)in PAW.The calculated results agree principally with experimental measurements from literature.During the pulsed discharge,the water gradually acidises,and the long-lived species accumulate;while in the afterglow,most of the aqueous RONS decay rapidly,except for O_(3aq),NO_(3aq)^(−),H_(2)O_(2aq)and N_(2)O_(aq),which might be the main sources to sustain long-term effects.Furthermore,the effects of applied voltage and gap distance on RONS are investigated.Correlation analyses from Pearson correlation coefficient indicate that gaseous RONS are more sensitive to the gap distance,while the aqueous ones are more sensitive to the voltage amplitude,suggesting the possibility to independently regulating the gaseous and aqueous chemistry.
基金Special Foundation of National Science and Technology Basic Research(2013FY112300).
文摘Aims Aquatic plants play an important role in freshwater ecosystems.Previous works have largely focused on the functional significance of plant above ground parts,with much less attention on the root structures of aquatic plants.In this study,we divided 21 aquatic plants(including five introduced plants)into multiple plant groups(different life forms,monocot/eudicot and introduced/native)with the goal of addressing two questions:(i)what root structures do aquatic plants exhibit,and(ii)are there differences among these plant groups?Methods Twenty-one aquatic plants belonging to four life forms(free-float-ing,emergent,floating-leaved and submerged)were collected at the near flowering stage from a typical macrophyte-dominated lake in the yangtze River Basin,China.The following root topological parameters were quantified:altitude(a),path length(pe),magnitude(M),mean topological length(b),topological index(TI)and normed indices qa and qb.Important Findings The root topological indices TI,qa and qb for the 21 aquatic plants were 0.724±0.013,0.290±0.031 and 0.152±0.024(means±S.E.),respectively,revealing a general pattern of dichotomous branching,except for the aquatic root of Myriophyllum aquati-cum(Vell.)Verdc.,which displays herringbone branching.All three topological indices were significantly lower for monocots(TI=0.700±0.130,qa=0.191±0.149 and qb=0.086±0.236)than eudicots(TI=0.752±0.206,qa=0.405±0.569 and qb=0.229±0.393),indicating that the roots of monocots are typi-cally more dichotomous-like than those of eudicots.Among the four life forms,the three topological indices for emergent plants(TI=0.832±0.006,qa=0.616±0.018 and qb=0.381±0.014)were significantly higher than those of the other three life forms.Overall,there was no difference between the topological indices of introduced and native aquatic plants,but the introduced species M.aquaticum and Alternanthera philoxeroides(Mart.)Griseb.had both aquatic and edaphic roots as well as unusual functions,which may help explain their strong viability.
基金supported by the National Science Foundation of China(NSFC)(31930074,41877415 and 32001157)the Science and Technology Service Network Initiative(KFJ-STS-QYZD-156)+2 种基金the Chinese Academy of Sciences(CAS)the Project of the Young Scientist Group(2021NIGLAS-CJH01)Nanjing Institute of Geography and Limnology(NIGLAS),CAS.