国产高温拌合型环氧沥青的固化行为与性能

利用荧光显微镜、差示扫描量热仪(DSC)、万能试验机、布氏黏度仪研究国产高温拌合型环氧沥青的微观固化形态、非等温条件下的固化行为、力学性能及施工和易性。观察发现,环氧沥青60℃固化4 d期间是"点-线-交联网状"的微观变化过程。DSC研究显示升温速率越高,环氧沥青固化热越小,沥青并不参与环氧树脂的自催化反应,但对环氧树脂固化体系有稀释作用。拉伸试验结果表明,环氧沥青结合料150℃容留1 h、2 h、3 h、4 h后,环氧树脂与基质沥青的相容性均较好,拉伸强度最大6.46 MPa,断裂伸长率265%。布氏黏度试验得到高温拌合型环氧沥青结合料在160℃、 2 h时黏度为1750 mPa·s。

Morphology Change of Metastable Regrown Graphite with Boron Additive under HPHT

By temperature gradient method under high pressure and high temperature （HPHT）, with NiMnCo alloy as the solvent metal, at diamond-stable region of about 5.4 GPa and 1500 K, metastable regrown graphite crystals of different morphology were synthesized. With B as an additive incorporated into the NiMnCo-C system, metastable regrown graphite crystals of sphere-like shape were firstly obtained under HPHT. If the growth system does not contain B, sheet-like regrown graphite crystals, most with regular hexagonal morphology, are grown upwards and standing vertically in the metal solvent. When B additive of 1.0 wt pct was added into carbon source （graphite powder）, all metastable regrown graphite crystals took on the habit of regular sphere-like morphology, and were grown by a spiral layer growth mechanism.

Effect of Seed Sizes on Growth of Large Synthetic Diamond Crystals

For the growth of large synthetic diamond crystals by temperature gradient method （TGM）, the grit sizes of seed crystals have great effects on the growth rate and quality of large grown crystals. Because of the limited area of seed surfaces, the maximum diffusion flux of carbon source, which could be absorbed by the seed, is related to the seed size. And with increasing the seed sizes, the growth rates also increase markedly. However, the seed sizes should be lower than a certain value, which determines the crystal quality directly. For example, with NiMnCo alloy as the metal solvent, when the seed size increases from 0.5 to 1.8 mm, the growth rate increases greatly from about 1.1 to 3.2 mg/h; when the size is beyond 2.0 mm, more and more metal inclusions would be incorporated into the grown crystals, and the crystal quality is destroyed heavily. Finite element analysis （FEA） shows that, due to the special assembly of growth cell, the diffusion of carbon source in the metal solvent is very inhomogeneous, which could be substantiated directly by the appearances and shapes of large grown crystals and the remains of carbon source. And this inhomogeneous diffusion of carbon source would be very harmful to the growth of large diamond crystals, especially when large-size seed crystals are used.

High-thermoelectric performance of TiO_(2-x)fabricated under high pressure at high temperatures

We present the work about the initiative fabrication of multi-scale hierarchical TiO2-x by our strategy,combining high pressure and high temperature(HPHT)reactive sintering with appropriate ratio of coarse Ti to nanosized TiO_(2).Ubiquitous lattice defects engineering has also been achieved in our samples by HPHT.The thermoelectric performance was significantly enhanced,and rather low thermal conductivity(1.60 W m^(-1)K^(-1))for titanium oxide was reported here for TiO1.76.Correspondingly,a high dimensionless figure of merit(zT)up to 0.33 at 700℃was realized in it.As far as we know,this value is an enhancement of 43%of the ever best result about nonstoichiometric TiO_(2)and the result is also exciting for oxide thermoelectric materials.The moderate power factor,the significantly reduced thermal conductivity and the remarkable synergy between electrical properties and thermal conductivity are responsible for the excellent thermoelectric performance.We develop a facile strategy for preparing multi-scale hierarchical TiO_(2-x)and its superior ability to optimize thermoelectric performance has been demonstrated here.

Three-axis coupled flight control law design forflying wing aircraft using eigenstructure assignment method

Due to elimination of horizontal and vertical tails,flying wing aircraft has poor longitudinal and directional dynamic characteristics.In addition,flying wing aircraft uses drag rudders for yaw control,which tends to generate strong three-axis control coupling.To overcome these problems,a flight control law design method that couples the longitudinal axis with the lateraldirectional axes is proposed.First,the three-axis coupled control augmentation structure is specified.In the structure,a‘‘soft/hard"cross-connection method is developed for three-axis dynamic decoupling and longitudinal control response decoupling from the drag rudders;maneuvering turn angular rate estimation and subtraction are used in the yaw axis to improve the directional damping.Besides,feedforward control is adopted to improve the maneuverability and control decoupling performance.Then,detailed design methods for feedback and feedforward control parameters are established using eigenstructure assignment and model following technique.Finally,the proposed design method is evaluated and compared with conventional method by numeric simulations.The influences of control derivatives variation of drag rudders on the method are also analyzed.It is demonstrated that the method can effectively improve the dynamic characteristics of flying wing aircraft,especially the directional damping characteristics,and decouple the longitudinal responses from the drag rudders.

Thermoelectric properties of In-substituted Ge-based clathrates prepared by HPHT

Bulk materials Ba_(8)Ga_(16)In_(x)Ge_(30-x)(x=0.5,1.0,1.5)were prepared by High-Pressure and High-Temperature(HPHT)method and the crystal structure has been confirmed by X-ray diffraction and cell refinement.The actual In composition was much lower than the starting composition,and lattice constants increased with the increase of substitution.As the temperature increased,the Seebeck coefficient and electrical resistivity increased first and then decreased,while the thermal conductivity was the opposite,which leads to significant enhancement on thermoelectric properties of the clathrates.The substitution of indium elements decreased the seebeck coefficient and electrical resistivity,and also changed the microstructure of the compounds.A minimum thermal conductivity of 0.84Wm^(-1)1K^(-1)was obtained,and a good ZT value of 0.52 was achieved.The grain boundaries and lattice defects generated by high pressure can effectively scatter phonons of different frequencies,which reduce the lattice thermal conductivity.

Thermoelectric performance of Cu_(2)Se bulk materials by hightemperature and high-pressure synthesis

Polycrystalline Cu_(2)Se bulk materials were synthesized by high-pressure and high-temperature(HPHT)technique.The effects of synthetic temperature and pressure on the thermoelectric properties of Cu_(2)Se materials were investigated.The results indicate that both synthetic temperature and pressure determine the microstructure and thermoelectric performance of Cu2Se compounds.The increase of synthetic temperature can effectively enhance the electrical conductivity and decrease the lattice thermal conductivity.A two-fold improvement in the power factor is obtained at synthetic temperature of 1000℃ compared to that obtained at room temperature.All b-Cu2Se samples exhibit low and temperatureindependent lattice thermal conductivity ranging from 0.3 to 0.5 Wm^(-1)K^(-1) due to the intrinsic superionic feature and the abundant lattice defects produced at high pressure.A maximum zT of 1.19 at 723 K was obtained for the sample synthesized at 3 GPa and 1000℃.These findings indicate that HPHT technology is an efficient approach to synthesize Cu_(2)Se-based bulk materials.