Under the new energy resource structure,electrocatalysts are key materials for the development of proton membrane fuel cells,electrolysis of aquatic hydrogen devices,and carbon dioxide reduction equipment,to address e...Under the new energy resource structure,electrocatalysts are key materials for the development of proton membrane fuel cells,electrolysis of aquatic hydrogen devices,and carbon dioxide reduction equipment,to address energy shortages and even environmental pollution issues.Although controlling the morphology or doping with heteroatoms for catalyst active centers have accelerated the reaction rate,it is difficult to solve the problems of multiple by-products,and poor stability of catalytic sites.From this,it will be seen that single regulation of metal active centers is difficult to comprehensively solve application problems.Orderly assembly and coordination of catalyst multi-hierarchy structures at the mesoscale above the nanometer level probably be more reasonable strategies,and numerous studies in thermal catalysis have supported this viewpoint.This article reviews the multi-hierarchy design of electrocatalyst active centers,high-energy supports,and peripheral structures in recent years,providing unconventional inspiration about electrocatalyst creation,which perhaps serves as a simple tutorial of electrocatalysis exploration for abecedarian.展开更多
Thermal loss of exhaust flue gas accounts for the largest proportion of the total boiler thermal loss. Nowadays in China, the exhaust gas temperature in many thermal power plants is much higher than the designed value...Thermal loss of exhaust flue gas accounts for the largest proportion of the total boiler thermal loss. Nowadays in China, the exhaust gas temperature in many thermal power plants is much higher than the designed value, thus, the recycle and reuse of the waste heat of tail flue gas is necessary. However, lower exhaust gas temperature will aggravate low temperature corrosion of the tail heating surface, which also causes huge economic losses. In order to solve this problem, this paper designs a monitoring experiment platform of flue gas low temperature corrosion, which can measure the corrosion condition of different materials by different flue gas compositions and temperature corrosion speeds. Besides, effects of low temperature corrosion factors are analyzed to find the best exhaust gas temperature and the surface material of tail heating surface.展开更多
基金supported by the National Natural Science Foundation of China(91963206,21932004,21872067,22172072)the Ministry of Science and Technology of China(2021YFA1500301)。
文摘Under the new energy resource structure,electrocatalysts are key materials for the development of proton membrane fuel cells,electrolysis of aquatic hydrogen devices,and carbon dioxide reduction equipment,to address energy shortages and even environmental pollution issues.Although controlling the morphology or doping with heteroatoms for catalyst active centers have accelerated the reaction rate,it is difficult to solve the problems of multiple by-products,and poor stability of catalytic sites.From this,it will be seen that single regulation of metal active centers is difficult to comprehensively solve application problems.Orderly assembly and coordination of catalyst multi-hierarchy structures at the mesoscale above the nanometer level probably be more reasonable strategies,and numerous studies in thermal catalysis have supported this viewpoint.This article reviews the multi-hierarchy design of electrocatalyst active centers,high-energy supports,and peripheral structures in recent years,providing unconventional inspiration about electrocatalyst creation,which perhaps serves as a simple tutorial of electrocatalysis exploration for abecedarian.
文摘Thermal loss of exhaust flue gas accounts for the largest proportion of the total boiler thermal loss. Nowadays in China, the exhaust gas temperature in many thermal power plants is much higher than the designed value, thus, the recycle and reuse of the waste heat of tail flue gas is necessary. However, lower exhaust gas temperature will aggravate low temperature corrosion of the tail heating surface, which also causes huge economic losses. In order to solve this problem, this paper designs a monitoring experiment platform of flue gas low temperature corrosion, which can measure the corrosion condition of different materials by different flue gas compositions and temperature corrosion speeds. Besides, effects of low temperature corrosion factors are analyzed to find the best exhaust gas temperature and the surface material of tail heating surface.