Nickel-cobalt/silicon carbide(Ni-Co/SiC)composite coatings were fabricated by supergravity field-enhanced electrodeposition.The surface morphology and the distribution of the SiC particles in the coatings were examine...Nickel-cobalt/silicon carbide(Ni-Co/SiC)composite coatings were fabricated by supergravity field-enhanced electrodeposition.The surface morphology and the distribution of the SiC particles in the coatings were examined by scanning electron microscope and energy dispersive X-ray spectrometry.The preferred orientations of the coatings were measured by X-ray diffractometry.The wear resistance and microhardness were measured by a reciprocating tribometer and a microhardness instrument,respectively.The results revealed that the use of the supergravity field enhanced the smoothness of the as-deposited Ni-Co/SiC coatings,and the SiC nanoparticles were uniformly distributed in comparison with that for conventional electrodeposition.When the rotation speed of the cathode,which provided the supergravity field,was 800 r/min,the SiC content in the coating reached a maximum of 8.1 wt%,which was a much higher content than the 2.2 wt%value obtained under conventional electrodeposition.The highest coating microhardness of 680 HV was also observed at this rotation speed.In addition,the wear resistance of the as-prepared Ni-Co/SiC coatings exhibited improved performance relative to that prepared under normal gravity.A minimum wear weight loss of 1.4 mg together with an average friction coefficient of 0.13 were also realized at a rotation speed of 800 r/min,values which were much lower than those for normal gravity.展开更多
Based on the population floating theory under the Ranis-Fei dual economic structure,this paper designs an econometric model to study the isoquant curve and production factor substitution law. Finally,through the empir...Based on the population floating theory under the Ranis-Fei dual economic structure,this paper designs an econometric model to study the isoquant curve and production factor substitution law. Finally,through the empirical analysis of labor-capital investment in Henan's agricultural production,combined with the principles of isoquant curve model,this paper determines the labor required for a certain scale of investment in agricultural production,and concludes that the fixed assets investment in Henan's agricultural production is not fully utilized,and too much labor is transferred. And this paper makes the corresponding policy recommendations for Henan's macroeconomic development.展开更多
Smart materials that integrate multi-stimuli response,full reversibility,and dual-visual read-out channel are highly desired for anticounterfeiting and information encryption applications.Herein,we developed a multire...Smart materials that integrate multi-stimuli response,full reversibility,and dual-visual read-out channel are highly desired for anticounterfeiting and information encryption applications.Herein,we developed a multiresponsive perchlorate terpyridyl Pt(Ⅱ)nano complex which could undergo fully reversible conversion between three forms stimulated by water or formaldehyde molecule due to the extent of Pt–Pt interaction.Meanwhile,a dual-visual channel,i.e.,the colorimetric channel changed from yellow to orange or red and the corresponding luminescent channel from orange to orange-red or red,has also been found.The weak and equivalent strength of ion-dipole interaction and hydrogen bond that generated between formaldehyde/water and Pt(II)salt result in the easy-control reversibility between the three forms.Furthermore,by introducing different polymer matrices,1Cl·ClO_(4)@PMMA(1Cl·ClO_(4):[Pt(tpy)Cl]·ClO4,tpy:2,2':6',2''-terpyridine),PMMA:poly(methyl methacrylate))and 1Cl·ClO4@PVA(PVA:polyvinyl alcohol)are successfully constructed,which exhibit different reversible behaviors since the PMMA and PVA matrix exert different influences on the strength of hydrogen-bond.Those smart Pt(II)salt nanostructures present great potential for high-security-level anticounterfeiting application.展开更多
Wire electrochemical machining(WECM) is a flexible and effective method for machining complex-shaped metal components, but the ability to machine large-thickness workpieces is hampered by the difficulty of transportin...Wire electrochemical machining(WECM) is a flexible and effective method for machining complex-shaped metal components, but the ability to machine large-thickness workpieces is hampered by the difficulty of transporting electrolytic products in the narrow machining gap. This paper proposes a novel hybrid machining technique that combines the characteristics of WECM and wire electric discharge machining(WEDM), namely, helical wire electrochemical discharge machining. The formation mechanism of electrical discharge in salt-glycol solution was elucidated.Experiments and simulation were conducted to verify the machining mechanism and investigate the performance of the proposed technique. The results show that as the recast layer can be removed by electrochemical action during the proposed process, the surface quality is effectively improved.Minimum surface roughness of the slit sidewall after machining reaches Ra= 0.12 μm. Minimum standard deviation of the slit after machining reaches 5 μm. Moreover, the existence of the discharges significantly improves the transport of the electrolytic products, thus ensuring high machining efficiency. In the experiments, the maximum feed rate of the helical wire electrochemical discharge machining reaches 7 μm/s(12.6 mm^(2)/min). Finally, mortise structures of Inconel 718 with good machining accuracy and surface quality are fabricated with a feed rate of 5 μm/s(9 mm^(2)/min),demonstrating that electrical discharge assisted helical wire ECM is a promising technique for machining large-thickness hard metal materials.展开更多
The precise regulation of interactions provided by aggregation-induced emission(AIE)probes is of considerable significance for improving the sensing performance in the field of on-site detection.Here,a highly sensitiv...The precise regulation of interactions provided by aggregation-induced emission(AIE)probes is of considerable significance for improving the sensing performance in the field of on-site detection.Here,a highly sensitive perchlorate detection probe was designed by precisely modulating the van der Waals interactions by adjusting the length of the alkyl chain.The optimized AIE probe demonstrated superior perchlorate detection performance owing to its strong van der Waals interactions with perchlorate,including a low detection limit(53.81 nM),rapid response(<5 s),and excellent specificity even in the presence of 16 interfering anions.In addition,a hydrogel-based device loaded with the probe was constructed to achieve ultrasensitive recognition of perchlorate particles with a detection limit as low as 15 fg under a fluorescence microscope.Moreover,the practicality of the probe was further verified by employing a sensing chip in a portable detector,and thus the probe has been proven to be highly promising for trace perchlorate monitoring in real scenarios.We expect the present study to be of great value for the efficient design of high-performance fluorescent probes.展开更多
In aero-engines,mortise-tenon joint structures are often used to connect the blades to the turbine disk.The disadvantages associated with conventional manufacturing techniques mean that a low-cost,high-efficiency,and ...In aero-engines,mortise-tenon joint structures are often used to connect the blades to the turbine disk.The disadvantages associated with conventional manufacturing techniques mean that a low-cost,high-efficiency,and high-quality nickel-based mortise–tenon joint structure is an urgent requirement in the field of aviation engineering.Electrochemical cutting is a potential machining method for manufacturing these parts,as there is no tool degradation in the cutting process and high-quality surfaces can be obtained.To realize the electrochemical cutting of a mortise-tenon joint structure,a method using a tube electrode with helically distributed jet-flow holes on the side-wall is proposed.During feeding,the tube electrode rotates along its central axis.Flow field simulations show that the rotational speed of the tube electrode determines the direct spraying time of the high-speed electrolyte ejected from the jet-flow holes to the machining area,while the electrolyte pressure determines the flow rate of the electrolyte and the velocity of the electrolyte ejected from the jet-flow holes.The machining results using the proposed method are verified experimentally,and the machining parameters are optimized.Finally,mortise and tenon samples are successfully machined using 20 mm thick Inconel 718 alloy with a feeding rate of 5μm/s.展开更多
基金supported by the National Natural Science Foundation of China(21676213,21476183,51372201)the China Postdoctoral Science Foundation(2016M600809)the Natural Science Basic Research Plan in Shaanxi Province of China(2017JM2026)~~
基金This work was supported by grants from the National Natural Science Foundation of China （30225037, 30471991, 30570731）, the 973 Program of China （2006CB503909, 2004CB518603）, the ＂111＂ Project, and the Natural Science Foundation of Jiangsu Province （BK2004082, BIC2006714）.
基金National Key Research and Development Program of China(Grant No.2018YFB1105900)National Basic Research Program of China(973 Program,Grant No.2015CB057502)Fundamental Research Funds for the Central Universities(Grant No.NZ2016106).
文摘Nickel-cobalt/silicon carbide(Ni-Co/SiC)composite coatings were fabricated by supergravity field-enhanced electrodeposition.The surface morphology and the distribution of the SiC particles in the coatings were examined by scanning electron microscope and energy dispersive X-ray spectrometry.The preferred orientations of the coatings were measured by X-ray diffractometry.The wear resistance and microhardness were measured by a reciprocating tribometer and a microhardness instrument,respectively.The results revealed that the use of the supergravity field enhanced the smoothness of the as-deposited Ni-Co/SiC coatings,and the SiC nanoparticles were uniformly distributed in comparison with that for conventional electrodeposition.When the rotation speed of the cathode,which provided the supergravity field,was 800 r/min,the SiC content in the coating reached a maximum of 8.1 wt%,which was a much higher content than the 2.2 wt%value obtained under conventional electrodeposition.The highest coating microhardness of 680 HV was also observed at this rotation speed.In addition,the wear resistance of the as-prepared Ni-Co/SiC coatings exhibited improved performance relative to that prepared under normal gravity.A minimum wear weight loss of 1.4 mg together with an average friction coefficient of 0.13 were also realized at a rotation speed of 800 r/min,values which were much lower than those for normal gravity.
基金Supported by Fund Project of Hubei Provincial Institute of New Countryside Development
文摘Based on the population floating theory under the Ranis-Fei dual economic structure,this paper designs an econometric model to study the isoquant curve and production factor substitution law. Finally,through the empirical analysis of labor-capital investment in Henan's agricultural production,combined with the principles of isoquant curve model,this paper determines the labor required for a certain scale of investment in agricultural production,and concludes that the fixed assets investment in Henan's agricultural production is not fully utilized,and too much labor is transferred. And this paper makes the corresponding policy recommendations for Henan's macroeconomic development.
基金support from the Major Science and Technology Project of Xinjiang(No.2022A01006-3)Science Foundation for Outstanding Young People of Xinjiang(No.2022D01E40)+1 种基金Youth Science Foundation of Xinjiang(No.2022D01C69)Tianchi Doctoral program(Nos.TCBS202130 and 51052300573).
文摘Smart materials that integrate multi-stimuli response,full reversibility,and dual-visual read-out channel are highly desired for anticounterfeiting and information encryption applications.Herein,we developed a multiresponsive perchlorate terpyridyl Pt(Ⅱ)nano complex which could undergo fully reversible conversion between three forms stimulated by water or formaldehyde molecule due to the extent of Pt–Pt interaction.Meanwhile,a dual-visual channel,i.e.,the colorimetric channel changed from yellow to orange or red and the corresponding luminescent channel from orange to orange-red or red,has also been found.The weak and equivalent strength of ion-dipole interaction and hydrogen bond that generated between formaldehyde/water and Pt(II)salt result in the easy-control reversibility between the three forms.Furthermore,by introducing different polymer matrices,1Cl·ClO_(4)@PMMA(1Cl·ClO_(4):[Pt(tpy)Cl]·ClO4,tpy:2,2':6',2''-terpyridine),PMMA:poly(methyl methacrylate))and 1Cl·ClO4@PVA(PVA:polyvinyl alcohol)are successfully constructed,which exhibit different reversible behaviors since the PMMA and PVA matrix exert different influences on the strength of hydrogen-bond.Those smart Pt(II)salt nanostructures present great potential for high-security-level anticounterfeiting application.
基金the financial support provided by the National Natural Science Foundation of China(No.52175413)the Natural Science Foundation of Jiangsu Province(No.BK20192007)+3 种基金the National Natural Science Foundation of China for Creative Research Groups(No.51921003)the Fundamental Research Funds for the Central Universities(No.NS2021034)the Aeronautical Science Foundation of China(No.201907052002)the Interdisciplinary Innovation Fund for Doctoral Students of Nanjing University of Aeronautics and Astronautics(No.KXKCXJJ202207).
文摘Wire electrochemical machining(WECM) is a flexible and effective method for machining complex-shaped metal components, but the ability to machine large-thickness workpieces is hampered by the difficulty of transporting electrolytic products in the narrow machining gap. This paper proposes a novel hybrid machining technique that combines the characteristics of WECM and wire electric discharge machining(WEDM), namely, helical wire electrochemical discharge machining. The formation mechanism of electrical discharge in salt-glycol solution was elucidated.Experiments and simulation were conducted to verify the machining mechanism and investigate the performance of the proposed technique. The results show that as the recast layer can be removed by electrochemical action during the proposed process, the surface quality is effectively improved.Minimum surface roughness of the slit sidewall after machining reaches Ra= 0.12 μm. Minimum standard deviation of the slit after machining reaches 5 μm. Moreover, the existence of the discharges significantly improves the transport of the electrolytic products, thus ensuring high machining efficiency. In the experiments, the maximum feed rate of the helical wire electrochemical discharge machining reaches 7 μm/s(12.6 mm^(2)/min). Finally, mortise structures of Inconel 718 with good machining accuracy and surface quality are fabricated with a feed rate of 5 μm/s(9 mm^(2)/min),demonstrating that electrical discharge assisted helical wire ECM is a promising technique for machining large-thickness hard metal materials.
基金Natural Science Foundation of Xinjiang,Grant/Award Number:2022D01E03West Light Foundation of the Chinese Academy of Sciences,Grant/Award Number:2021-XBQNXZ-023+1 种基金National Natural Science Foundation of China,Grant/Award Numbers:52172168,22104152Key Research Program of Frontier Sciences,CAS,。
文摘The precise regulation of interactions provided by aggregation-induced emission(AIE)probes is of considerable significance for improving the sensing performance in the field of on-site detection.Here,a highly sensitive perchlorate detection probe was designed by precisely modulating the van der Waals interactions by adjusting the length of the alkyl chain.The optimized AIE probe demonstrated superior perchlorate detection performance owing to its strong van der Waals interactions with perchlorate,including a low detection limit(53.81 nM),rapid response(<5 s),and excellent specificity even in the presence of 16 interfering anions.In addition,a hydrogel-based device loaded with the probe was constructed to achieve ultrasensitive recognition of perchlorate particles with a detection limit as low as 15 fg under a fluorescence microscope.Moreover,the practicality of the probe was further verified by employing a sensing chip in a portable detector,and thus the probe has been proven to be highly promising for trace perchlorate monitoring in real scenarios.We expect the present study to be of great value for the efficient design of high-performance fluorescent probes.
基金supported by the National Natural Science Foundation of China(No.91960204)the Natural Science Foundation of Jiangsu Province(No.BK20191279)+1 种基金the Aeronautical Science Foundation of China(No.201907052002)the National Natural Science Foundation of China for Creative Research Groups(No.51921003)。
文摘In aero-engines,mortise-tenon joint structures are often used to connect the blades to the turbine disk.The disadvantages associated with conventional manufacturing techniques mean that a low-cost,high-efficiency,and high-quality nickel-based mortise–tenon joint structure is an urgent requirement in the field of aviation engineering.Electrochemical cutting is a potential machining method for manufacturing these parts,as there is no tool degradation in the cutting process and high-quality surfaces can be obtained.To realize the electrochemical cutting of a mortise-tenon joint structure,a method using a tube electrode with helically distributed jet-flow holes on the side-wall is proposed.During feeding,the tube electrode rotates along its central axis.Flow field simulations show that the rotational speed of the tube electrode determines the direct spraying time of the high-speed electrolyte ejected from the jet-flow holes to the machining area,while the electrolyte pressure determines the flow rate of the electrolyte and the velocity of the electrolyte ejected from the jet-flow holes.The machining results using the proposed method are verified experimentally,and the machining parameters are optimized.Finally,mortise and tenon samples are successfully machined using 20 mm thick Inconel 718 alloy with a feeding rate of 5μm/s.
