New C3,4-disubstituted bis-triazolyl glycoligands that feature a glucosyl or galactosyl scaffold incorporating two pyrenyl groups were synthesized via the Cu^1-catalyzed azide-alkyne 1,3-dipolar cycloaddition reaction...New C3,4-disubstituted bis-triazolyl glycoligands that feature a glucosyl or galactosyl scaffold incorporating two pyrenyl groups were synthesized via the Cu^1-catalyzed azide-alkyne 1,3-dipolar cycloaddition reaction （Cue-AAC）. These compounds exert a major emission band corresponding to that of pyrene excimer and respond specifically to mercury with a markedly quenched fluorescence. The epimeric nature of the pyranoglycosyl scaffold is determined influential toward the selectivity of the sensors.展开更多
基金the National Natural Science Foundation of China （Nos. 21176076, 21202045） and the Fundamental Research Funds for the Central Universities （No. WK1013002） for generously providing the funding. Dr. X.-P. He is also supported by China Postdoctoral Science Foundation Funded Projects （Nos. 2011M500069, 2012T50400）.
文摘New C3,4-disubstituted bis-triazolyl glycoligands that feature a glucosyl or galactosyl scaffold incorporating two pyrenyl groups were synthesized via the Cu^1-catalyzed azide-alkyne 1,3-dipolar cycloaddition reaction （Cue-AAC）. These compounds exert a major emission band corresponding to that of pyrene excimer and respond specifically to mercury with a markedly quenched fluorescence. The epimeric nature of the pyranoglycosyl scaffold is determined influential toward the selectivity of the sensors.
