A CrO3 catalyzed oxidation of homopropargyl alcohols with tert-butyl hydroperoxide under microwave irradiation was found to be an efficient and rapid alternative for the preparation of 1,2-allenic ketones.The advantag...A CrO3 catalyzed oxidation of homopropargyl alcohols with tert-butyl hydroperoxide under microwave irradiation was found to be an efficient and rapid alternative for the preparation of 1,2-allenic ketones.The advantages of this procedure include short reaction time,less adverse impact on the environment and reasonably high efficiency.展开更多
基金the National Natural Science Foundation of China(Nos20772025 and 20972042)Innovation Scientists and Technicians Troop Construction Projects of Henan Province(No104100510019)+1 种基金Natural Science Foundation of Henan Province(No092300410237)the Natural Science Foundation of Department of Education of Henan Province(Nos2009A150017 and 2008A150013)
文摘A CrO3 catalyzed oxidation of homopropargyl alcohols with tert-butyl hydroperoxide under microwave irradiation was found to be an efficient and rapid alternative for the preparation of 1,2-allenic ketones.The advantages of this procedure include short reaction time,less adverse impact on the environment and reasonably high efficiency.
