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基于Acidithiobacillus ferrooxidans介导的共沉淀对酸性体系中重金属的固定(英文)
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作者 甘敏 李明明 +4 位作者 曾健 刘新星 朱建裕 胡岳华 邱冠周 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2017年第5期1156-1164,共9页
研究Acidithiobacillus ferrooxidans对酸性水体中复合重金属共沉淀过程的促进作用。A.ferrooxidans显著地提高了共沉淀体系中Fe(II)离子的氧化速率及硫酸羟基铁氧体的形成。在A.ferrooxidans存在的条件下Cu(II)浓度降低至0.058 mmol/L,... 研究Acidithiobacillus ferrooxidans对酸性水体中复合重金属共沉淀过程的促进作用。A.ferrooxidans显著地提高了共沉淀体系中Fe(II)离子的氧化速率及硫酸羟基铁氧体的形成。在A.ferrooxidans存在的条件下Cu(II)浓度降低至0.058 mmol/L,而Cd在生物体系中浓度降至最低0.085 mmol/L。Pb主要以铅矾形式沉淀,硫酸羟基铁氧体促进了残余铅离子的沉淀。通过XRD、SEM和FTIR等技术对形成产物进行系统表征。共沉淀体系中主要的组分为高结晶度的黄钾铁矾,而A.ferrooxidans促进施式矿物在一价阳离子缺乏的反应后期形成。A.ferrooxidans存在体系中较高的Fe(II)离子氧化速率和Fe(III)离子供应速度有利于多面体晶体形成及其晶粒尺径增加。复合重金属离子进入硫酸羟基铁氧体的晶体结构,通过A.ferrooxidans介导的共沉淀能够高效地将重金属离子从酸性废水中去除。 展开更多
关键词 共沉淀 嗜酸氧化亚铁硫杆菌 复合重金属 硫酸羟基铁氧体 酸性水体
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改性海泡石作为循环使用的吸附剂在酸性溶液中吸附Pd(Ⅱ)的应用 被引量:3
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作者 肖勇 冯宁宁 +6 位作者 王润华 董海刚 郭子文 崔浩 武海艳 刘新星 谢建平 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2020年第5期1375-1386,共12页
研究以改性海泡石作为吸附剂从酸性溶液中回收Pd(Ⅱ)的吸附特性和机理;通过等温模型、动力学和热力学模型分析改性海泡石对Pd(Ⅱ)的吸附特性;利用SEM-EDS、TEM和XPS技术研究改性海泡石对Pd(Ⅱ)的吸附机理。Langmuir模型表明,当温度为30... 研究以改性海泡石作为吸附剂从酸性溶液中回收Pd(Ⅱ)的吸附特性和机理;通过等温模型、动力学和热力学模型分析改性海泡石对Pd(Ⅱ)的吸附特性;利用SEM-EDS、TEM和XPS技术研究改性海泡石对Pd(Ⅱ)的吸附机理。Langmuir模型表明,当温度为30℃时,改性海泡石对Pd(Ⅱ)的最大吸附量为322.58 mg/g。动力学实验结果表明,准二级动力学模型能较好地模拟改性海泡石对Pd(Ⅱ)的吸附过程,化学吸附为改性海泡石吸附Pd(Ⅱ)的控速步骤。当Pd(Ⅱ)的初始浓度为100 mg/L时,1 g/L改性海泡石可吸附99%的Pd(Ⅱ)。吸附-脱附循环实验结果表明,改性海泡石具有良好的稳定性和重复使用性。本研究结果表明,改性海泡石是一种可高效且经济的Pd(Ⅱ)回收材料。 展开更多
关键词 改性海泡石 吸附 脱附 动力学
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High material quality growth of AlInAsSb thin films on GaSb substrate by molecular beam epitaxy 被引量:1
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作者 常发冉 郝瑞亭 +8 位作者 齐通通 赵其琛 刘欣星 李勇 顾康 郭杰 王国伟 徐应强 牛智川 《Chinese Physics B》 SCIE EI CAS CSCD 2019年第2期449-453,共5页
In this paper, high material quality Al_(0.4) In_(0.6) AsSb quaternary alloy on GaSb substrates is demonstrated. The quality of these epilayers is assessed using a high-resolution x-ray diffraction, Fourier transform ... In this paper, high material quality Al_(0.4) In_(0.6) AsSb quaternary alloy on GaSb substrates is demonstrated. The quality of these epilayers is assessed using a high-resolution x-ray diffraction, Fourier transform infrared(FTIR) spectrometer,and atomic force microscope(AFM). The x-ray diffraction exhibits high order satellite peaks with a measured period of 31.06 ?(theoretical value is 30.48 ?), the mismatch between the GaSb substrate and AlInAsSb achieves-162 arcsec,and the root-mean square(RMS) roughness for typical material growths has achieved around 1.6 ? over an area of 10 μm×10 μm. At room temperature, the photoluminescence(PL) spectrum shows a cutoff wavelength of 1.617 μm. 展开更多
关键词 AlInAsSb short-wavelength digital ALLOY
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Large Amplitude Oscillatory Shear Studies on the Strain-stiffening Behavior of Gelatin Gels
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作者 Wei-xiang Sun Li-zhen Huang +2 位作者 Yan-rui Yang xin-xing liu 童真 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2015年第1期70-83,共14页
Linear and nonlinear viscoelasticity of gelatin solutions was investigated by rheology. The dynamic mechanical properties during the sol-gel transition of gelatin followed the time-cure superposition. The fractal dime... Linear and nonlinear viscoelasticity of gelatin solutions was investigated by rheology. The dynamic mechanical properties during the sol-gel transition of gelatin followed the time-cure superposition. The fractal dimension df of the critical gel was estimated as 1.76, which indicated a loose network. A high sol fraction ws = 0.61 was evaluated from the plateau modulus by semi-empirical models. Strain-stiffening behavior was observed under large amplitude oscillatory shear(LAOS) for the gelatin gel. The strain and frequency dependence of the minimum strain modulus GM, energy dissipation Ed, and nonlinear viscoelastic parameter NE was illustrated in Pipkin diagrams and explained by the strain induced helix formation reported previously by others. The BST model described the strain-stiffening behavior of gelatin gel quite well, whereas the Gent and worm-like chain network models overestimated the strain-stiffening at large strains. 展开更多
关键词 Gelatin Large amplitude oscillatory shear Strain-stiffening.
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