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一种在室温附近具有高热电性能的准一维块体材料
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作者 董庆新 项俊森 +15 位作者 王振 李云岫 卢瑞 张特 陈楠 黄奕飞 王义炎 朱文亮 李国栋 赵怀周 郑兴华 张帅 任治安 杨炯 陈根富 孙培杰 《Science Bulletin》 SCIE EI CAS CSCD 2023年第9期920-927,M0004,共9页
在低维材料体系中探索高热电性能是热电材料研究领域的一个重要方向.实际上,近年来所发现的热电材料中的很大一部分,比如Bi_(2)Te_(3),SnSe,Mg_(3)Sb_(2)等,都具有准二维晶体结构.但是,到目前为止对准一维材料的热电研究还非常少见.本... 在低维材料体系中探索高热电性能是热电材料研究领域的一个重要方向.实际上,近年来所发现的热电材料中的很大一部分,比如Bi_(2)Te_(3),SnSe,Mg_(3)Sb_(2)等,都具有准二维晶体结构.但是,到目前为止对准一维材料的热电研究还非常少见.本文报道了一种在室温附近具有高热电性能的准一维块体材料:TLCu_(3)Te_(2).在室温下,该材料沿单晶针状方向具有高达1.3的热电优值;在400 K时,其热电优值甚至可以达到1.5,一定程度超越了目前该温区的商用材料热电性能.通过详细的热电输运实验并结合第一性原理计算,作者发现TlCu_(3)Te_(2)的高热电优值主要起源于饼状费米口袋的高度各向异性准一维电子色散关系带来的大热电功率因子,以及准一维重元素复杂晶格导致的极低热导率.该研究表明准一维块体材料中的单轴性热电效应是一个值得深入探索的热电材料新领地. 展开更多
关键词 热电性能 热电材料 热电优值 热电效应 准一维 第一性原理计算 一维材料 低维材料
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Study on the Heat Conduction of Phase-Change Material Microcapsules 被引量:3
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作者 Gangtao Zhao Xiaohui Xu +2 位作者 Lin Qiu xinghua zheng Dawei Tang 《Journal of Thermal Science》 SCIE EI CAS CSCD 2013年第3期257-260,共4页
The 3ω approach was used to measure the effective thermal conductivity of phase-change material microcapsules (PCMMs) based on urea formaldehyde and sliced paraffin. The effective thermal conductivities of PCMMs with... The 3ω approach was used to measure the effective thermal conductivity of phase-change material microcapsules (PCMMs) based on urea formaldehyde and sliced paraffin. The effective thermal conductivities of PCMMs with different densities were measured within the phase-change temperature range. The relationships between effective thermal conductivity, density and temperature were analysed. The effective thermal conductivity reached peak values within the phase-change temperature range and the temperature peak value was consistent with the peak value of the phase-change temperature. The effective thermal conductivity increased with increasing density due to the decreased porosity of samples and their increased solid-phase conduction. 展开更多
关键词 3ω-method EFFECTIVE THERMAL conductivity PHASE-CHANGE MATERIAL MICROCAPSULES
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Thermally drawn multifunctional fibers: Toward the next generation of information technology 被引量:2
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作者 Yanan Shen Zhe Wang +7 位作者 hixun Wang Jiajia Wang Xiao Yang xinghua zheng Haisheng Chen Kaiwei Li Lei Wei Ting Zhang 《InfoMat》 SCIE CAS 2022年第7期98-119,共22页
As the fundamental building block of optical fiber communication technology,thermally drawn optical fibers have fueled the development and prosperity of modern information society.However,the conventional step-index c... As the fundamental building block of optical fiber communication technology,thermally drawn optical fibers have fueled the development and prosperity of modern information society.However,the conventional step-index configured silica optical fibers have scarcely altered since their invention.In recent years,thermally drawn multifunctional fibers have emerged as a new yet promising route to enable unprecedented development in information technology.By adopting the well-developed preform-to-fiber manufacturing technique,a broad range of functional materials can be seamlessly integrated into a single fiber on a kilometer length scale to deliver sophisticated functions.Functions such as photodetection,imaging,acoustoelectric detection,chemical sensing,tactile sensing,biological probing,energy harvesting and storage,data storage,program operation,and information processing on fiber devices.In addition to the original light-guiding function,these flexible fibers can be woven into fab-rics to achieve large-scale personal health monitoring and interpersonal com-munication.Thermally drawn multifunctional fibers have opened up a new stage for the next generation of information technology.This review article summarizes an overview of the basic concepts,fabrication processes,and developments of multifunctional fibers.It also highlights the significant pro-gress and future development in information applications. 展开更多
关键词 acoustoelectric fiber biological probe energy fiber integrated circuit fiber multifunctional fiber optoelectronic fiber
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Enhanced ferro-/piezoelectric properties of tape-casting-derived Er^(3+)-doped Ba_(0.85)Ca_(0.15)Ti_(0.9)Zr_(0.1O3) optoelectronic thick films 被引量:1
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作者 Jie XU Qiling LU +4 位作者 Jinfeng LIN Cong LIN xinghua zheng Tengfei LIN Xiao WU 《Journal of Advanced Ceramics》 SCIE CAS CSCD 2020年第6期693-702,共10页
Er^(3+)-doped Ba_(0.85)Ca_(0.15)Ti_(0.9)Zr_(0.1O3)(xEr-BCTZ,x=0,0.005,0.01,0.015)multifunctional thick films were prepared by the tape-casting method,using sol-gel-derived nano-sized powders as the matrix material.The... Er^(3+)-doped Ba_(0.85)Ca_(0.15)Ti_(0.9)Zr_(0.1O3)(xEr-BCTZ,x=0,0.005,0.01,0.015)multifunctional thick films were prepared by the tape-casting method,using sol-gel-derived nano-sized powders as the matrix material.The surface morphologies,photoluminescence,and electrical properties were investigated.Dense microstructures with pure perovskite structure were obtained in the thick films.By doping an appropriate amount of Er^(3+),the samples exhibit superior up-conversion photoluminescence performance and simultaneously enhanced electrical performances.In addition,relatively higher texture fractions(with the largest value of 83.5%)were realized through introducing plate-like BaTiO_(3) templates to make the thick film grow by the[001]_(c) orientation.And the ferro-/piezoelectric properties of the thick films were further improved,showing potential in the applications of micro-optoelectronic devices. 展开更多
关键词 thick films TEXTURE FERROELECTRIC PIEZOELECTRIC PHOTOLUMINESCENCE
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