The effects of Co2O3 on the crystallization and colorization of lithium aluminosilicate glass ceramic were investigated by using differential thermal analysis (DTA), X-ray diffractometry (XRD) and scanning electron mi...The effects of Co2O3 on the crystallization and colorization of lithium aluminosilicate glass ceramic were investigated by using differential thermal analysis (DTA), X-ray diffractometry (XRD) and scanning electron microscope (SEM). The results showed that the introduction of Co2O3 not only changed the color of lithium aluminosilicate glass but also affected its crystallization by increasing the crystallizing maximum peak temperature (Tp) and weakening the crystallization ability. In addition, the color of LAS glass ceramics could be achieved by controlling the suitable Co2O3 and appropriate crystallization temperature.展开更多
The effect of single coloring agent Nd(NO3)3 on the crystallization, microstructure and colorization of Li2O-Al2O3-SiO2 (LAS) glass ceramics were investigated by differential thermal analysis (DTA), X-ray diffractomet...The effect of single coloring agent Nd(NO3)3 on the crystallization, microstructure and colorization of Li2O-Al2O3-SiO2 (LAS) glass ceramics were investigated by differential thermal analysis (DTA), X-ray diffractometry (XRD) and scanning electron microscopy (SEM). The introduction of little neodymium has no effect on the crystallization manner and the formation of main crystallization phase, but more neodymium will weaken the crystallization of LAS glass. Little neodymium can increase the glossiness of LAS glass ceramic, while more neodymium can color LAS glass with light purple or red purple. The colorability of neodymium for LAS glass ceramic decreases with the increase of crystallization temperature.展开更多
Wearable electronics have promising applications in human-machine interfaces due to their excellent flexibility,stretchability and human friendliness,and one of the key points of wearable electronics is to develop str...Wearable electronics have promising applications in human-machine interfaces due to their excellent flexibility,stretchability and human friendliness,and one of the key points of wearable electronics is to develop strain sensors with high sensitivity and working range.Herein,a high-performance Eco-flex@AgNW/graphite/Pt hybrid strain sensor was fabricated by suction filtrating,transferring and surface sputtering sequentially.The suction filtrating of AgNW and graphite dispersions on a wrinkle-shape Nylon filter,transferring of AgNW/graphite layer onto Ecoflex and further surface sputtering by Pt allow the construction of fingerprint bionic Ecoflex@AgNW/graphite/Pt hybrid strain sensor.The resul-tant fingerprint bionic hybrid strain sensor possesses high sensitivity of 2064.1 at the strain of 140%e155%,a wide working range of 0e155%,a short response time(111 ms and 189 ms for tensile and releasing process)and excellent cyclic stability over 5000 cycles.This study provides a universal tech-nique for the preparation of strain sensors with promising applications in the field of next-generation intelligent wearable electronics.展开更多
SiC honeycomb ceramics with parallel channels and macroporous walls were prepared by combining extrusion molding with pressureless sintering technology in the presence of starch.The extrusion molding constructed honey...SiC honeycomb ceramics with parallel channels and macroporous walls were prepared by combining extrusion molding with pressureless sintering technology in the presence of starch.The extrusion molding constructed honeycomb structure with parallel channels,while the starch formed spherical macropores on the channel walls.The density and bending strength of SiC honeycomb ceramics decreased with the increase of starch content,while the phase compositions did not vary with the starch content.The control in starch addition could adjust the pore structures on the channel walls of SiC honeycomb ceramics.展开更多
Bamboo charcoal was expected to be a renewable carbon source for carbide materials in carbothermal reduction because of its superior characteristics.SiC powders with characteristic shapes were fabricated by carbotherm...Bamboo charcoal was expected to be a renewable carbon source for carbide materials in carbothermal reduction because of its superior characteristics.SiC powders with characteristic shapes were fabricated by carbothermal reduction with industrial silica sol and bamboo charcoal particles as silicon and carbon sources respectively,and the effects of reacting temperature and time on shape evolutions and properties of the as-prepared SiC powders were investigated.The silica sol/bamboo charcoal system was firstly transformed into SiO_(2)/C system by the transition of silica sol and graphitization of bamboo charcoal,and the carbothermal reduction between SiO_(2) and C occurred at/above 1600℃.The characteristic shapes of SiC particles were transformed from string-beads-like to dumbbell-like and rod-like with the increase of reacting temperature.The prepared SiC powders are expected to become new raw material for silicon carbide ceramic composites.展开更多
Silver nanowire(AgNW)has become one of the best candidates for flexible transparent electromagnetic(EMI)shielding materials,while the low corrosion resistance of AgNW hinders its application in environments with high ...Silver nanowire(AgNW)has become one of the best candidates for flexible transparent electromagnetic(EMI)shielding materials,while the low corrosion resistance of AgNW hinders its application in environments with high content of corrosive substances.Herein,an AgNW/poly(3,4-ethylene dioxythiophene)/poly(styrene sulfonate)(PEDOT:PSS)@nickel electrode was prepared through ultrasonic spray coating and electroplating methods.PEDOT:PSS is sprayed to improve the conductivity of the AgNW network,and a 9.8-16.5 nm Ni layer is deposited on the AgNW/PEDOT:PSS to protect the AgNWs from corrosion.The AgNW/PEDOT:PSS@Ni electrode shows a sheet resistance of 29 U·sq^(-1),a transmittance of 78.18%,an average EMI shielding efficiency of 19.64 dB and excellent corrosion resistance in Na2S solution.The resultant AgNW/PEDOT:PSS@Ni electrode is promisingly used in high corrosion resistance transparent EMI shielding film.展开更多
文摘The effects of Co2O3 on the crystallization and colorization of lithium aluminosilicate glass ceramic were investigated by using differential thermal analysis (DTA), X-ray diffractometry (XRD) and scanning electron microscope (SEM). The results showed that the introduction of Co2O3 not only changed the color of lithium aluminosilicate glass but also affected its crystallization by increasing the crystallizing maximum peak temperature (Tp) and weakening the crystallization ability. In addition, the color of LAS glass ceramics could be achieved by controlling the suitable Co2O3 and appropriate crystallization temperature.
文摘The effect of single coloring agent Nd(NO3)3 on the crystallization, microstructure and colorization of Li2O-Al2O3-SiO2 (LAS) glass ceramics were investigated by differential thermal analysis (DTA), X-ray diffractometry (XRD) and scanning electron microscopy (SEM). The introduction of little neodymium has no effect on the crystallization manner and the formation of main crystallization phase, but more neodymium will weaken the crystallization of LAS glass. Little neodymium can increase the glossiness of LAS glass ceramic, while more neodymium can color LAS glass with light purple or red purple. The colorability of neodymium for LAS glass ceramic decreases with the increase of crystallization temperature.
基金supported by the Key R&D Program of Zhejiang Province of China(No.2020C01126)the National Key R&D Program of China(2016YFB0401305).
文摘Wearable electronics have promising applications in human-machine interfaces due to their excellent flexibility,stretchability and human friendliness,and one of the key points of wearable electronics is to develop strain sensors with high sensitivity and working range.Herein,a high-performance Eco-flex@AgNW/graphite/Pt hybrid strain sensor was fabricated by suction filtrating,transferring and surface sputtering sequentially.The suction filtrating of AgNW and graphite dispersions on a wrinkle-shape Nylon filter,transferring of AgNW/graphite layer onto Ecoflex and further surface sputtering by Pt allow the construction of fingerprint bionic Ecoflex@AgNW/graphite/Pt hybrid strain sensor.The resul-tant fingerprint bionic hybrid strain sensor possesses high sensitivity of 2064.1 at the strain of 140%e155%,a wide working range of 0e155%,a short response time(111 ms and 189 ms for tensile and releasing process)and excellent cyclic stability over 5000 cycles.This study provides a universal tech-nique for the preparation of strain sensors with promising applications in the field of next-generation intelligent wearable electronics.
基金supported by the Innovation Fund for Technology-based Firms of China(12C26113303061)High Science&Technique Brainstorm Project of Zhejiang Province of China(No.2012C01032-1).
文摘SiC honeycomb ceramics with parallel channels and macroporous walls were prepared by combining extrusion molding with pressureless sintering technology in the presence of starch.The extrusion molding constructed honeycomb structure with parallel channels,while the starch formed spherical macropores on the channel walls.The density and bending strength of SiC honeycomb ceramics decreased with the increase of starch content,while the phase compositions did not vary with the starch content.The control in starch addition could adjust the pore structures on the channel walls of SiC honeycomb ceramics.
基金This work is supported by the High Science&Technique Brainstorm Project of Zhejiang Province of China(No.2012C01032-1)Zhejiang Key Innovation Team Projects(No.2009R50010)Innovation Fund for Technology Based Firms(No.12C26113303061).
文摘Bamboo charcoal was expected to be a renewable carbon source for carbide materials in carbothermal reduction because of its superior characteristics.SiC powders with characteristic shapes were fabricated by carbothermal reduction with industrial silica sol and bamboo charcoal particles as silicon and carbon sources respectively,and the effects of reacting temperature and time on shape evolutions and properties of the as-prepared SiC powders were investigated.The silica sol/bamboo charcoal system was firstly transformed into SiO_(2)/C system by the transition of silica sol and graphitization of bamboo charcoal,and the carbothermal reduction between SiO_(2) and C occurred at/above 1600℃.The characteristic shapes of SiC particles were transformed from string-beads-like to dumbbell-like and rod-like with the increase of reacting temperature.The prepared SiC powders are expected to become new raw material for silicon carbide ceramic composites.
基金supported by the Key R&D Program of Zhejiang Province of China(No.2020C01126)and the National Key R&D Program of China(2016YFB0401305).
文摘Silver nanowire(AgNW)has become one of the best candidates for flexible transparent electromagnetic(EMI)shielding materials,while the low corrosion resistance of AgNW hinders its application in environments with high content of corrosive substances.Herein,an AgNW/poly(3,4-ethylene dioxythiophene)/poly(styrene sulfonate)(PEDOT:PSS)@nickel electrode was prepared through ultrasonic spray coating and electroplating methods.PEDOT:PSS is sprayed to improve the conductivity of the AgNW network,and a 9.8-16.5 nm Ni layer is deposited on the AgNW/PEDOT:PSS to protect the AgNWs from corrosion.The AgNW/PEDOT:PSS@Ni electrode shows a sheet resistance of 29 U·sq^(-1),a transmittance of 78.18%,an average EMI shielding efficiency of 19.64 dB and excellent corrosion resistance in Na2S solution.The resultant AgNW/PEDOT:PSS@Ni electrode is promisingly used in high corrosion resistance transparent EMI shielding film.