To ensure authenticity of sesame oil,an authentication technology was proposed using ion mobility spectrometry(IMS)and chemometrics.One-class classification(OCC)methods including one-class partial least squares(OCPLS)...To ensure authenticity of sesame oil,an authentication technology was proposed using ion mobility spectrometry(IMS)and chemometrics.One-class classification(OCC)methods including one-class partial least squares(OCPLS)and one-class support vector machine(OCSVM)were employed to build authentication models for sesame oil.Subsequently,an independent test set was used to validate the constructed models.Validation set of 45 adulterated oils indicated that prediction correction rate of OCPLS model reached 95.6%(43 out of 45).Moreover,the complete set of sesame oils adulterated by sesame oil essence could be identified as counterfeit.Compared with previous studies,OCPLS model could work to identify untargeted adulteration.In conclusion,OCC method could effectively detect adulterated sesame oils containing as little as 10%other vegetable oils.This study provided a rapid screening method for adulterated sesame oil in market surveillance and a reference for developing authentication methods of other edible oils.展开更多
Authenticity of blended oil has drawn increasing attentions. In this study, sesamin was selected as marker of sesame oil to verify authentication of blended oil with sesame oil on label. A simple method based on liqui...Authenticity of blended oil has drawn increasing attentions. In this study, sesamin was selected as marker of sesame oil to verify authentication of blended oil with sesame oil on label. A simple method based on liquid chromatography-tandem mass spectrometry (LC-MS/MS) combined with solid-phase extraction (SPE) was used to detect sesamin. It has high sensitivity with low limit of detection (LOD) and limit of quantification (LOQ) being 20 ng/mL and 70 ng/mL respectively. Recoveries from 80.16% to 102.50% in 4 different oils indicated it’s reliable to quantify sesamin in edible oil. Four blended oils were used as validation samples and results showed this method could effectively detect whether sesame oil exists. In this study, a simple method was proposed for sesamin determination by LC-MS/MS and SPE in edible oils for the first time and provided an effective guide to identify authenticity of blended oils.展开更多
The origin traceability of edible oil is an effective way to protect the legitimate rights and interests of producers and consumers.This review briefly summarizes research progress on origin traceability technologies ...The origin traceability of edible oil is an effective way to protect the legitimate rights and interests of producers and consumers.This review briefly summarizes research progress on origin traceability technologies for edible oils including stable isotope ratio mass spectrometry,mineral element fingerprint analysis,organic component fingerprint analysis,near-infrared spectroscopy,nuclear magnetic resonance technology and biochemical analysis.Moreover,the development trends in edible oil origin traceability technology were proposed.展开更多
基金This work was supported by the National Science and Technology Major Project of China(2017YFC1601700)the National Nature Foundation Committee of P.R.China(31871886)+2 种基金the National Major Project for Agro-product Quality&Safety Risk Assessment(GJFP2019003)the earmarked fund for China Agricultural Research System(CARS-12)the Fundamental Research Funds for Central Non-profit Scientific Institution(1610172018002 and 1610172018012).
文摘To ensure authenticity of sesame oil,an authentication technology was proposed using ion mobility spectrometry(IMS)and chemometrics.One-class classification(OCC)methods including one-class partial least squares(OCPLS)and one-class support vector machine(OCSVM)were employed to build authentication models for sesame oil.Subsequently,an independent test set was used to validate the constructed models.Validation set of 45 adulterated oils indicated that prediction correction rate of OCPLS model reached 95.6%(43 out of 45).Moreover,the complete set of sesame oils adulterated by sesame oil essence could be identified as counterfeit.Compared with previous studies,OCPLS model could work to identify untargeted adulteration.In conclusion,OCC method could effectively detect adulterated sesame oils containing as little as 10%other vegetable oils.This study provided a rapid screening method for adulterated sesame oil in market surveillance and a reference for developing authentication methods of other edible oils.
文摘Authenticity of blended oil has drawn increasing attentions. In this study, sesamin was selected as marker of sesame oil to verify authentication of blended oil with sesame oil on label. A simple method based on liquid chromatography-tandem mass spectrometry (LC-MS/MS) combined with solid-phase extraction (SPE) was used to detect sesamin. It has high sensitivity with low limit of detection (LOD) and limit of quantification (LOQ) being 20 ng/mL and 70 ng/mL respectively. Recoveries from 80.16% to 102.50% in 4 different oils indicated it’s reliable to quantify sesamin in edible oil. Four blended oils were used as validation samples and results showed this method could effectively detect whether sesame oil exists. In this study, a simple method was proposed for sesamin determination by LC-MS/MS and SPE in edible oils for the first time and provided an effective guide to identify authenticity of blended oils.
基金This work was supported by the National Nature Foundation Committee of P.R.China(31871886,31671858)the earmarked fund for China Agriculture research system(CARS-12)+2 种基金the Hunan Provincial Natural Science Foundation of China(2019JJ40114)the Scientific Research Fund of Hunan Provincial Education Department,China(18A108)the Major Research plan of the Changsha(kq1801016).
文摘The origin traceability of edible oil is an effective way to protect the legitimate rights and interests of producers and consumers.This review briefly summarizes research progress on origin traceability technologies for edible oils including stable isotope ratio mass spectrometry,mineral element fingerprint analysis,organic component fingerprint analysis,near-infrared spectroscopy,nuclear magnetic resonance technology and biochemical analysis.Moreover,the development trends in edible oil origin traceability technology were proposed.
