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Engineering the Thermoelectrical Properties of PEDOT:PSS by Alkali Metal Ion Effect 被引量:1
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作者 Jingjin Dong Jian Liu +3 位作者 xinkai qiu Ryan Chiechi L.Jan Anton Koster Giuseppe Portale 《Engineering》 SCIE EI 2021年第5期647-654,共8页
Engineering the electrical properties of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate)(PEDOT:PSS)holds great potential for various applications such as sensors,thermoelectric(TE)generators,and hole transport... Engineering the electrical properties of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate)(PEDOT:PSS)holds great potential for various applications such as sensors,thermoelectric(TE)generators,and hole transport layers in solar cells.Various strategies have been applied to achieve optimal electrical properties,including base solution post-treatments.However,the working mechanism and the exact details of the structural transformations induced by base post-treatments are still unclear.In this work,we present a comparative study on the post-treatment effects of using three common and green alkali base solutions:namely LiOH,NaOH,and KOH.The structural modifications induced in the film by the base post-treatments are studied by techniques including atomic force microscopy,grazing-incidence wide-angle X-ray scattering,ultraviolet–visible–near-infrared spectroscopy,and attenuated total reflectance Fourier-transform infrared spectroscopy.Base-induced structural modifications are responsible for an improvement in the TE power factor of the films,which depends on the basic solution used.The results are explained on the basis of the different affinity between the alkali cations and the PSS chains,which determines PEDOT dedoping.The results presented here shed light on the structural reorganization occurring in PEDOT:PSS when exposed to high-pH solutions and may serve as inspiration to create future pH-/ion-responsive devices for various applications. 展开更多
关键词 PEDOT:PSS Thermoelectric properties Alkali base solutions POST-TREATMENT Structure-property relationship Grazing-incidence wide-angle X-ray SCATTERING
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