Main observation and conclusion A full account of the total synthesis of(-)-pallambins A-D(1-6)is described.The strategy was devised by simulating their biosynthetic pathway.The left-part bicyclo[3.2.1]octane system o...Main observation and conclusion A full account of the total synthesis of(-)-pallambins A-D(1-6)is described.The strategy was devised by simulating their biosynthetic pathway.The left-part bicyclo[3.2.1]octane system of pallambins C and D was efficiently constructed via a palladium-catalyzed oxidative cyclization.展开更多
基金This research was supported by the National Natural Science Foundation of China(Nos.21925101 and 21572008).
文摘Main observation and conclusion A full account of the total synthesis of(-)-pallambins A-D(1-6)is described.The strategy was devised by simulating their biosynthetic pathway.The left-part bicyclo[3.2.1]octane system of pallambins C and D was efficiently constructed via a palladium-catalyzed oxidative cyclization.
