Liquid-phase epoxidation of styrene with atmospheric O_2 was conducted over CoAPO-5 molecular sieves.The catalytic performance of CoAPO-5 can be significantly improved by alkali metal salt impregnated on it,and styren...Liquid-phase epoxidation of styrene with atmospheric O_2 was conducted over CoAPO-5 molecular sieves.The catalytic performance of CoAPO-5 can be significantly improved by alkali metal salt impregnated on it,and styrene conversion and selectivity to styrene oxide reached 85%and 69%respectively when CsCl was impregnated on it.The catalyst was recyclable and exhibited similar catalytic activity and selectivity even after three catalytic reaction cycles.展开更多
基金supported by the National Natural Science Foundation of China(No.20971095)the Science Foundation of Shanxi Province(No.2010011014-4)the Foundation for Returned Overseas Scholars of Shanxi Province(No.2008-10)
文摘Liquid-phase epoxidation of styrene with atmospheric O_2 was conducted over CoAPO-5 molecular sieves.The catalytic performance of CoAPO-5 can be significantly improved by alkali metal salt impregnated on it,and styrene conversion and selectivity to styrene oxide reached 85%and 69%respectively when CsCl was impregnated on it.The catalyst was recyclable and exhibited similar catalytic activity and selectivity even after three catalytic reaction cycles.
