Two new carbonyl manganese compounds were obtained by reactions of 2.6-di(biphenylphosphine) pyridine (PNP) with CpMn(CO)(3). The structures of the compounds were confirmed by elemental analysis, IR, H-1 NMR and P-31 ...Two new carbonyl manganese compounds were obtained by reactions of 2.6-di(biphenylphosphine) pyridine (PNP) with CpMn(CO)(3). The structures of the compounds were confirmed by elemental analysis, IR, H-1 NMR and P-31 NMR. The results showed that the mixed-donor ligand (PNP) was coordinated to manganese only through the phosphorus atom.展开更多
文摘Two new carbonyl manganese compounds were obtained by reactions of 2.6-di(biphenylphosphine) pyridine (PNP) with CpMn(CO)(3). The structures of the compounds were confirmed by elemental analysis, IR, H-1 NMR and P-31 NMR. The results showed that the mixed-donor ligand (PNP) was coordinated to manganese only through the phosphorus atom.
