Gibberellins (GAs) play important roles in many essential plant growth and development processes. A family of nuclear growth-repressing DELLA proteins is the key component in GA signaling. GA perception is mediated ...Gibberellins (GAs) play important roles in many essential plant growth and development processes. A family of nuclear growth-repressing DELLA proteins is the key component in GA signaling. GA perception is mediated by GID1, and the key event of GA signaling is the degradation of DELLA proteins via the 26S proteasome pathway. DELLA proteins integrating other plant hormones signaling and environmental cue modulating plant growth and development have been revealed. GA turning on the de-DELLA-repressing system is conserved, and independently establishes step-by-step recruitment of GA-stimulated GID1-DELLA interaction and DELLA growth-repression functions during land plant evolution. These discoveries open new prospects for the understanding of GA action and DELLA-mediated signaling in plants.展开更多
In situ measurements of austenite grain growth were made at various temperatures in the range of 1273-1473 K with subsequent isothermal holding time of 3600 s for the Nb-Ti-bearing and Nb-Ti-free high carb on steel by...In situ measurements of austenite grain growth were made at various temperatures in the range of 1273-1473 K with subsequent isothermal holding time of 3600 s for the Nb-Ti-bearing and Nb-Ti-free high carb on steel by using a confocal laser scanning microscope.The solid solute behavior of Nb-Ti carbides during austenitizing process was analyzed.The experimental results indicate that the austenite grains of both steels grow up gradually with increasing the heating temperature and holding time;the size and growth rate of austenite grain of Nb-Ti-bearing high carbon steel are much lower than those of Nb-Ti-free high carbon steel.A large amount of(Nb,Ti)(C,N)nanoparticles are observed in Nb-Tibearing steel,which retain the strong pinning effect on austenite grain boundary.The kinetics model of austenite grain growth of Nb-Ti-bearing steel during isothermal heat treatment is obtained and the predicted values calculated by using the model meet the experimental values very well.展开更多
The corrosion behavior of high-strength steel used for flexible riser exposed to CO_(2-)saturated saline solution and CO_(2-) saturated vapor environments was studied through immersion experiment and electrochemical c...The corrosion behavior of high-strength steel used for flexible riser exposed to CO_(2-)saturated saline solution and CO_(2-) saturated vapor environments was studied through immersion experiment and electrochemical corrosion experiment. The corrosion behavior and mechanism of the tested steel were analyzed on the basis of corrosion kinetics, nature of corrosion products, corrosion product morphology, elemental distribution and polarization curves. The experimental results showed that the microstructure of the tested steel was bainitic microstructure. The corrosive activity of the tested steel exposed to CO_(2-) saturated vapor environment was significantly lower than that exposed to CO_(2-) saturated saline solution environment.On prolonging the exposure time, the corrosion rate gradually decreased, the corrosion heterogeneity increased, and the dimensions of FeCO_3 crystals gradually became small. At later stages of corrosion, the corrosion current density decreased significantly and the anodic Tafel slope increased, indicating that the corrosion process was strongly inhibited. The corrosion mechanism of low-alloy steel with bainitic microstructure was proposed based on experimental results.展开更多
Hydrogen trapping behavior of V–N microalloyed X80 pipeline steels was studied by means of hydrogen permeation and hydrogen induced cracking(HIC)tests.In addition,the electrochemical performance of the steels in 3.5 ...Hydrogen trapping behavior of V–N microalloyed X80 pipeline steels was studied by means of hydrogen permeation and hydrogen induced cracking(HIC)tests.In addition,the electrochemical performance of the steels in 3.5 wt.%NaCl solution was investigated.Results indicated that the microstructure of experimental steels mainly consisted of acicular ferrite and polygonal ferrite(PF).When the fraction of PF was 9.1%and 30.4%,hydrogen effective diffusion coefficient was 1.624×10^(−6) and 3.121×10^(−6) cm^(2)/s,respectively.The pipeline steels were not susceptible to HIC.Numerous potential hydrogen traps distributed in homogeneous dispersion were conducive to high HIC resistance.With increasing the fraction of PF from 9.1%to 30.4%,the corrosion current density increased from 5.39×10^(−6) to 9.49×10^(−6) A cm^(−2),the corrosion potential decreased from−0.48 to−0.57 V,and the charge transfer resistance decreased from 2301 to 2068Ωcm^(2),respectively.Increased fraction of PF was disadvantageous for corrosion resistance because of galvanic corrosion.展开更多
The structure-property relationship in heat-affected zone (HAZ)of a low-carbon steel bearing V-N subjected to gasshielded arc welding was explored.The microstructural characteristics of base metal (BM),coarse-grained ...The structure-property relationship in heat-affected zone (HAZ)of a low-carbon steel bearing V-N subjected to gasshielded arc welding was explored.The microstructural characteristics of base metal (BM),coarse-grained HAZ (CGHAZ),fine-grained HAZ,and intercritical HAZ were significantly different.The effect of grain-refinement strengthening and transformation hardening on HAZ contributed to equivalent hardness of 260.8-278.5 HV in comparison with BM hardness of 272.0 HV.Moreover,excellent impact toughness at -20 ℃ was obtained because of high resistance to crack propagation by high-misorientation boundaries,leading to impact fracture consisting of dimples.In CGHAZ,free N was partly fixed by V(C,N)precipitates,such that the deterioration effect of N on toughness was considered to be nearly eliminated.In comparison with CGHAZ,weld metal contained higher fraction of acicular ferrite with fine plates,while the impact toughness was inferior because of the detrimental influence of coarse inclusions from the welding wire.The nanoscale V(C,N)precipitates in CGHAZ had weak effect on toughness because of small size.展开更多
The effects of tempering temperature on the microstructure and mechanical properties of high-strength structural steel containing niobium were investigated to examine the roles of nanoscale precipitates and metastable...The effects of tempering temperature on the microstructure and mechanical properties of high-strength structural steel containing niobium were investigated to examine the roles of nanoscale precipitates and metastable austenite in determining the yield strength and toughness.After hot-rolling and quenching,three experimental steels were tempered at 590,630,and 670℃.During tempering,nanoscale Nb(C,N)precipitates were formed with the recovery of quenched martensite.The average diameters of Nb(C,N)precipitates increased from 5.4 to 8.2 nm as the tempering temperature was increased.Notably,reversed austenite with a volume fraction of 9%was formed at tempering temperatures up to 670℃.The yield strengths of steel containing tempered martensite tempered at 590 and 630℃ were 965 and 831 MPa,and the tensile strengths were 998 and 879 MPa,respectively.However,the steel comprising reversed austenite and tempered martensite tempered at 670℃ showed continuous yielding behavior,affording yield and tensile strengths of 610 and 889 MPa,respectively.The impact energy increased from 105 to 260 J at−60℃ with increasing tempering temperature.Reversed austenite improves low-temperature toughness by significantly increasing the crack propagation energy.展开更多
Carbon dioxide corrosion behavior of low-alloy pipeline steel with 1% Cr exposed to CO2-saturated solution was investigated by immersion experiment. SEM, EDX, TEM, EPMA and XRD were utilized to investigate the microst...Carbon dioxide corrosion behavior of low-alloy pipeline steel with 1% Cr exposed to CO2-saturated solution was investigated by immersion experiment. SEM, EDX, TEM, EPMA and XRD were utilized to investigate the microstructure, corrosion morphologies, corrosion phases and elements distribution of corrosion scale. The results demon strate that the microstructure of tested steel consists of ferrite and carbides. During the corrosion process, ferrite dissolves preferentially, leaving carbide particles behind. The residual carbide particles may promote the nucleation of FeCO3 crystal. The phase comprising of the inner layer is Cr compound, and the one of the outer layer is FeCO3. The formation process of corrosion scale can be illustrated as follows: Firstly, a thin scale consisting of thin inner layer and outer layer is formed, which represents poor corrosion resistance; then, the inner layer changes little, once it has been formed, and the outer layer becomes thick and compact, which demonstrates that a fine corrosion resistance is obtained. The chemical elements of chromium and molybdenum accumulate in the inner layer of corrosion scale. The corrosion behavior of low- alloy steel based on microstructure and morphology characterization is also discussed.展开更多
基金the Hi-Tech Research and Development (863) Program ofChina (2007AA10Z190)the National Natural Science Foundation of China(30771164 and 30770208)China Postdoctoral Science Foundation Funded Project
文摘Gibberellins (GAs) play important roles in many essential plant growth and development processes. A family of nuclear growth-repressing DELLA proteins is the key component in GA signaling. GA perception is mediated by GID1, and the key event of GA signaling is the degradation of DELLA proteins via the 26S proteasome pathway. DELLA proteins integrating other plant hormones signaling and environmental cue modulating plant growth and development have been revealed. GA turning on the de-DELLA-repressing system is conserved, and independently establishes step-by-step recruitment of GA-stimulated GID1-DELLA interaction and DELLA growth-repression functions during land plant evolution. These discoveries open new prospects for the understanding of GA action and DELLA-mediated signaling in plants.
文摘In situ measurements of austenite grain growth were made at various temperatures in the range of 1273-1473 K with subsequent isothermal holding time of 3600 s for the Nb-Ti-bearing and Nb-Ti-free high carb on steel by using a confocal laser scanning microscope.The solid solute behavior of Nb-Ti carbides during austenitizing process was analyzed.The experimental results indicate that the austenite grains of both steels grow up gradually with increasing the heating temperature and holding time;the size and growth rate of austenite grain of Nb-Ti-bearing high carbon steel are much lower than those of Nb-Ti-free high carbon steel.A large amount of(Nb,Ti)(C,N)nanoparticles are observed in Nb-Tibearing steel,which retain the strong pinning effect on austenite grain boundary.The kinetics model of austenite grain growth of Nb-Ti-bearing steel during isothermal heat treatment is obtained and the predicted values calculated by using the model meet the experimental values very well.
基金financial support from the National High Technology Research and Development Program of China (Grant No. 2015AA03A501)Doctoral Scientific Research Foundation of Jiangsu University of Science and Technology (1062931702)
文摘The corrosion behavior of high-strength steel used for flexible riser exposed to CO_(2-)saturated saline solution and CO_(2-) saturated vapor environments was studied through immersion experiment and electrochemical corrosion experiment. The corrosion behavior and mechanism of the tested steel were analyzed on the basis of corrosion kinetics, nature of corrosion products, corrosion product morphology, elemental distribution and polarization curves. The experimental results showed that the microstructure of the tested steel was bainitic microstructure. The corrosive activity of the tested steel exposed to CO_(2-) saturated vapor environment was significantly lower than that exposed to CO_(2-) saturated saline solution environment.On prolonging the exposure time, the corrosion rate gradually decreased, the corrosion heterogeneity increased, and the dimensions of FeCO_3 crystals gradually became small. At later stages of corrosion, the corrosion current density decreased significantly and the anodic Tafel slope increased, indicating that the corrosion process was strongly inhibited. The corrosion mechanism of low-alloy steel with bainitic microstructure was proposed based on experimental results.
基金This study is financially supported by the National High Technology Research and Development Program of China(863 Program)(Grant No.2015AA03A501).
文摘Hydrogen trapping behavior of V–N microalloyed X80 pipeline steels was studied by means of hydrogen permeation and hydrogen induced cracking(HIC)tests.In addition,the electrochemical performance of the steels in 3.5 wt.%NaCl solution was investigated.Results indicated that the microstructure of experimental steels mainly consisted of acicular ferrite and polygonal ferrite(PF).When the fraction of PF was 9.1%and 30.4%,hydrogen effective diffusion coefficient was 1.624×10^(−6) and 3.121×10^(−6) cm^(2)/s,respectively.The pipeline steels were not susceptible to HIC.Numerous potential hydrogen traps distributed in homogeneous dispersion were conducive to high HIC resistance.With increasing the fraction of PF from 9.1%to 30.4%,the corrosion current density increased from 5.39×10^(−6) to 9.49×10^(−6) A cm^(−2),the corrosion potential decreased from−0.48 to−0.57 V,and the charge transfer resistance decreased from 2301 to 2068Ωcm^(2),respectively.Increased fraction of PF was disadvantageous for corrosion resistance because of galvanic corrosion.
基金the National Natural Science Foundation of China (Grant No.51604072)the Fundamental Research Funds for the Central Universities (Grant No.N170704016)the National High-Tech R&D Program (863 Program)of China (Grant No.2015AA03A501).
文摘The structure-property relationship in heat-affected zone (HAZ)of a low-carbon steel bearing V-N subjected to gasshielded arc welding was explored.The microstructural characteristics of base metal (BM),coarse-grained HAZ (CGHAZ),fine-grained HAZ,and intercritical HAZ were significantly different.The effect of grain-refinement strengthening and transformation hardening on HAZ contributed to equivalent hardness of 260.8-278.5 HV in comparison with BM hardness of 272.0 HV.Moreover,excellent impact toughness at -20 ℃ was obtained because of high resistance to crack propagation by high-misorientation boundaries,leading to impact fracture consisting of dimples.In CGHAZ,free N was partly fixed by V(C,N)precipitates,such that the deterioration effect of N on toughness was considered to be nearly eliminated.In comparison with CGHAZ,weld metal contained higher fraction of acicular ferrite with fine plates,while the impact toughness was inferior because of the detrimental influence of coarse inclusions from the welding wire.The nanoscale V(C,N)precipitates in CGHAZ had weak effect on toughness because of small size.
基金The authors gratefully acknowledge financial support by the National Key R&D Program of China(Grant No.2017YFB0305300)the Joint Fund project of the Ministry of Education for Equipment Pre-research(6141A020222).
文摘The effects of tempering temperature on the microstructure and mechanical properties of high-strength structural steel containing niobium were investigated to examine the roles of nanoscale precipitates and metastable austenite in determining the yield strength and toughness.After hot-rolling and quenching,three experimental steels were tempered at 590,630,and 670℃.During tempering,nanoscale Nb(C,N)precipitates were formed with the recovery of quenched martensite.The average diameters of Nb(C,N)precipitates increased from 5.4 to 8.2 nm as the tempering temperature was increased.Notably,reversed austenite with a volume fraction of 9%was formed at tempering temperatures up to 670℃.The yield strengths of steel containing tempered martensite tempered at 590 and 630℃ were 965 and 831 MPa,and the tensile strengths were 998 and 879 MPa,respectively.However,the steel comprising reversed austenite and tempered martensite tempered at 670℃ showed continuous yielding behavior,affording yield and tensile strengths of 610 and 889 MPa,respectively.The impact energy increased from 105 to 260 J at−60℃ with increasing tempering temperature.Reversed austenite improves low-temperature toughness by significantly increasing the crack propagation energy.
基金financially supported by National Key Technology Research and Development Program of the Ministry of Science and Technology of China during the ‘‘12th Five- Year Plan’’(Grant No. 2011BAE25B03)
文摘Carbon dioxide corrosion behavior of low-alloy pipeline steel with 1% Cr exposed to CO2-saturated solution was investigated by immersion experiment. SEM, EDX, TEM, EPMA and XRD were utilized to investigate the microstructure, corrosion morphologies, corrosion phases and elements distribution of corrosion scale. The results demon strate that the microstructure of tested steel consists of ferrite and carbides. During the corrosion process, ferrite dissolves preferentially, leaving carbide particles behind. The residual carbide particles may promote the nucleation of FeCO3 crystal. The phase comprising of the inner layer is Cr compound, and the one of the outer layer is FeCO3. The formation process of corrosion scale can be illustrated as follows: Firstly, a thin scale consisting of thin inner layer and outer layer is formed, which represents poor corrosion resistance; then, the inner layer changes little, once it has been formed, and the outer layer becomes thick and compact, which demonstrates that a fine corrosion resistance is obtained. The chemical elements of chromium and molybdenum accumulate in the inner layer of corrosion scale. The corrosion behavior of low- alloy steel based on microstructure and morphology characterization is also discussed.