New hyperbranched poly（aryleneethynylene）s containing carbazole moieties are synthesized in high yields （up to 87%） by polycyclotrimerization of 3,6-bis（4-ethynylphenyl）-9-octylcarbazole and its copolymerization...New hyperbranched poly（aryleneethynylene）s containing carbazole moieties are synthesized in high yields （up to 87%） by polycyclotrimerization of 3,6-bis（4-ethynylphenyl）-9-octylcarbazole and its copolymerization with 1-octyne catalyzed by CpCo（CO）2 in THF. The structures and properties of the polymers are characterized and evaluated by IR, NMR, TGA, UV, photoluminescence, and cyclic voltammetry analyses. All the polymers are soluble in common organic solvents and show outstanding thermal stability （≥ 430℃）. They graphitize in high yields （up to 79%） when pyrolyzed at 800℃. Upon photoexcitation, the polymers emit a strong deep blue light of ca. 400 nm with quantum yields larger than 60%.展开更多
基金This project was financially supported by National Natural Science Foundation of China(No.50473034).
文摘New hyperbranched poly（aryleneethynylene）s containing carbazole moieties are synthesized in high yields （up to 87%） by polycyclotrimerization of 3,6-bis（4-ethynylphenyl）-9-octylcarbazole and its copolymerization with 1-octyne catalyzed by CpCo（CO）2 in THF. The structures and properties of the polymers are characterized and evaluated by IR, NMR, TGA, UV, photoluminescence, and cyclic voltammetry analyses. All the polymers are soluble in common organic solvents and show outstanding thermal stability （≥ 430℃）. They graphitize in high yields （up to 79%） when pyrolyzed at 800℃. Upon photoexcitation, the polymers emit a strong deep blue light of ca. 400 nm with quantum yields larger than 60%.
