An environmentally friendly method for the synthesis of LiMnPO_(4)/C anode material for lithium-ion batteries by solvothermal method is introduced.The modification of the morphology of this precursor is altered by cha...An environmentally friendly method for the synthesis of LiMnPO_(4)/C anode material for lithium-ion batteries by solvothermal method is introduced.The modification of the morphology of this precursor is altered by changing the ratio of the conditioning solvent(water-ethylene glycol solution)and the order of material addition.Ethylene glycol(EG)exerts a considerable influence on synthesizing LiMnPO_(4)/C flake-like nanocrystal,which benefits the extraction/insertion reaction of lithium ions and improves the electrochemical activity and electrochemical performance of LiMnPO_(4)/C material.When the solvent composition is H_(2)O:EG=1:3,exhibiting exceptional charge/discharge performance and rate capability,the specific discharge capacities are 155.8,153.7,148.8,141.4,129.5,and 112.6 mAh g^(−1) at the 0.1,0.2,0.5,1,2,and 5 C rates,respectively.When the charge-discharge rate returns to 0.1 C,the LiMnPO_(4)/C material shows a reversible discharge specific capacity of 153.7 mAh g^(−1).Differential scanning calorimetry(DSC)tests verify that the thermodynamic stability of the prepared LiMnPO_(4)/C(LMP)and commercial LiFePO_(4)(LFP)materials is better than that of commercial nickel-cobalt-aluminum(NCA)ternary materials.These prepared LiMnPO_(4)/C composites have high electrochemical capacity and cycle stability.展开更多
Diseases not only bring troubles to people’s body functions and mind but also influence the appearances and behaviours of human beings.Similarly,we can analyse the diseases from people’s appearances and behaviours a...Diseases not only bring troubles to people’s body functions and mind but also influence the appearances and behaviours of human beings.Similarly,we can analyse the diseases from people’s appearances and behaviours and use the personal medical history for human identification.In this article,medical indicators presented in abnormal changes of human appearances and behaviours caused by physiological or psychological diseases were introduced,and were applied in the field of forensic identification of human images,which we called medical forensic identification of human images(mFIHI).The proposed method analysed the people’s medical signs by studying the appearance and behaviour characteristics depicted in images or videos,and made a comparative examination between the medical indicators of the questioned human images and the corresponding signs or medical history of suspects.Through a conformity and difference analysis on medical indicators and their indicated diseases,it would provide an important information for human identification from images or videos.A case study was carried out to demonstrate and verify the feasibility of the proposed method of mFIHI,and our results showed that it would be important contents and angles for forensic expert manual examination in forensic human image identification.展开更多
基金financial support from Qingyuan Huayuan Institute of Science and Technology Collaborative Innovation Co.,Ltd.,Qingyuan 511517the National Natural Science Foundation of China(No.21776051)+2 种基金the Scientific and Technological Plan of Guangdong(2019B090905007)the Guangzhou University Research Projects(YG2020017)the China Postdoctoral Science Foundation(2020M682662)。
文摘An environmentally friendly method for the synthesis of LiMnPO_(4)/C anode material for lithium-ion batteries by solvothermal method is introduced.The modification of the morphology of this precursor is altered by changing the ratio of the conditioning solvent(water-ethylene glycol solution)and the order of material addition.Ethylene glycol(EG)exerts a considerable influence on synthesizing LiMnPO_(4)/C flake-like nanocrystal,which benefits the extraction/insertion reaction of lithium ions and improves the electrochemical activity and electrochemical performance of LiMnPO_(4)/C material.When the solvent composition is H_(2)O:EG=1:3,exhibiting exceptional charge/discharge performance and rate capability,the specific discharge capacities are 155.8,153.7,148.8,141.4,129.5,and 112.6 mAh g^(−1) at the 0.1,0.2,0.5,1,2,and 5 C rates,respectively.When the charge-discharge rate returns to 0.1 C,the LiMnPO_(4)/C material shows a reversible discharge specific capacity of 153.7 mAh g^(−1).Differential scanning calorimetry(DSC)tests verify that the thermodynamic stability of the prepared LiMnPO_(4)/C(LMP)and commercial LiFePO_(4)(LFP)materials is better than that of commercial nickel-cobalt-aluminum(NCA)ternary materials.These prepared LiMnPO_(4)/C composites have high electrochemical capacity and cycle stability.
基金This work is supported by Shanghai Sailing Program[grant number 17YF1420000]Ministry of Finance of the People's Republic of China[grant numbers GY2018G-6 and GY2020G-8].
文摘Diseases not only bring troubles to people’s body functions and mind but also influence the appearances and behaviours of human beings.Similarly,we can analyse the diseases from people’s appearances and behaviours and use the personal medical history for human identification.In this article,medical indicators presented in abnormal changes of human appearances and behaviours caused by physiological or psychological diseases were introduced,and were applied in the field of forensic identification of human images,which we called medical forensic identification of human images(mFIHI).The proposed method analysed the people’s medical signs by studying the appearance and behaviour characteristics depicted in images or videos,and made a comparative examination between the medical indicators of the questioned human images and the corresponding signs or medical history of suspects.Through a conformity and difference analysis on medical indicators and their indicated diseases,it would provide an important information for human identification from images or videos.A case study was carried out to demonstrate and verify the feasibility of the proposed method of mFIHI,and our results showed that it would be important contents and angles for forensic expert manual examination in forensic human image identification.